Diel cycling of trace elements in streams draining mineralized areas: a review
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Abstract
Many trace elements exhibit persistent diel, or 24-h, concentration cycles in streams draining mineralized areas. These cycles can be caused by various physical and biogeochemical mechanisms including streamflow variation, photosynthesis and respiration, as well as reactions involving photochemistry, adsorption and desorption, mineral precipitation and dissolution, and plant assimilation. Iron is the primary trace element that exhibits diel cycling in acidic streams. In contrast, many cationic and anionic trace elements exhibit diel cycling in near-neutral and alkaline streams. Maximum reported changes in concentration for these diel cycles have been as much as a factor of 10 (988% change in Zn concentration over a 24-h period). Thus, monitoring and scientific studies must account for diel trace-element cycling to ensure that water-quality data collected in streams appropriately represent the conditions intended to be studied.
Publication type | Article |
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Publication Subtype | Journal Article |
Title | Diel cycling of trace elements in streams draining mineralized areas: a review |
Series title | Applied Geochemistry |
DOI | 10.1016/j.apgeochem.2014.05.008 |
Volume | 57 |
Year Published | 2015 |
Language | English |
Publisher | Elsevier |
Contributing office(s) | Eastern Mineral and Environmental Resources Science Center, Toxic Substances Hydrology Program |
Description | 10 p. |
First page | 35 |
Last page | 44 |
Online Only (Y/N) | N |
Additional Online Files (Y/N) | N |
Google Analytic Metrics | Metrics page |