Colloid mobilization and seasonal variability in a semiarid headwater stream
Journal of Environmental Quality
Links
- More information: Publisher Index Page (via DOI)
- Download citation as: RIS | Dublin Core
Abstract
Colloids can be important vectors for the transport of contaminants in the environment, but little is known about colloid mobilization at the watershed scale. We present colloid concentration, composition, and flux data over a large range of hydrologic conditions from a small watershed (Gordon Gulch) in the foothills of the Colorado Front Range. Colloids, consisting predominantly of Si, Fe, and Al, were present in most stream samples but were not detected in groundwater samples. Mineralogical and morphological analysis indicated that the colloids were composed of kaolinite and illite clays with lesser amounts of amorphous Fe-hydroxides. Although colloid composition remained relatively constant over the sampled flow conditions, colloid concentrations varied considerably and increased as ionic strength of stream water decreased. The highest concentrations occurred during precipitation events after extended dry periods. These observations are consistent with laboratory studies that have shown colloids can be mobilized by decreases in pore-water ionic strength, which likely occurs during precipitation events. Colloidal particles constituted 30 to 35% of the Si mass flux and 93 to 97% of the Fe and Al mass fluxes in the <0.45-µm fraction in the stream. Colloids are therefore a significant and often overlooked component of mass fluxes whose temporal variations may yield insight into hydrologic flowpaths in this semiarid catchment.
Suggested Citation
Mills, T.J., Ancerson, S.P., Bern, C.R., Aguirre, A., Derry, L.A., 2017, Colloid mobilization and seasonal variability in a semiarid headwater stream: Journal of Environmental Quality, v. 46, p. 88-95, https://doi.org/10.2134/jeq2016.07.0268.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Colloid mobilization and seasonal variability in a semiarid headwater stream |
| Series title | Journal of Environmental Quality |
| DOI | 10.2134/jeq2016.07.0268 |
| Edition | 1 |
| Volume | 46 |
| Year Published | 2017 |
| Language | English |
| Publisher | Alliance of Crop, Soil, and Environmental Science Societies |
| Contributing office(s) | Colorado Water Science Center |
| Description | 9 p. |
| First page | 88 |
| Last page | 95 |
| Country | United States |
| State | Colorado |