We measure peak ground velocities from fault‐zone guided waves (FZGWs), generated by on‐fault earthquakes associated with the 24 August 2014 M_w 6.0 South Napa earthquake. The data were recorded on three arrays deployed across north and south of the 2014 surface rupture. The observed FZGWs indicate that the West Napa fault zone (WNFZ) and the Franklin fault (FF) are continuous in the subsurface for at least 75 km. Previously published potential‐field data indicate that the WNFZ extends northward to the Maacama fault (MF), and previous geologic mapping indicates that the FF extends southward to the Calaveras fault (CF); this suggests a total length of at least 110 km for the WNFZ–FF. Because the WNFZ–FF appears contiguous with the MF and CF, these faults apparently form a continuous Calaveras–Franklin–WNFZ–Maacama (CFWM) fault that is second only in length (∼300  km) to the San Andreas fault in the San Francisco Bay area. The long distances over which we observe FZGWs, coupled with their high amplitudes (2–10 times the S waves) suggest that strong shaking from large earthquakes on any part of the CFWM fault may cause far‐field amplified fault‐zone shaking. We interpret guided waves and seismicity cross sections to indicate multiple upper crustal splays of the WNFZ–FF, including a northward extension of the Southhampton fault, which may cause strong shaking in the Napa Valley and the Vallejo area. Based on travel times from each earthquake to each recording array, we estimate average P‐, S‐, and guided‐wave velocities within the WNFZ–FF (4.8–5.7, 2.2–3.2, and 1.1–2.8  km/s, respectively), with FZGW velocities ranging from 58% to 93% of the average S‐wave velocities.