Effect of copper salts on hydrothermal oxidative decarboxylation: A study of phenylacetic acid

Xuan Fu; Megan Jamison; Aaron M. Jubb; Yiju Liao; Alexandria Aspin; Kyle Hayes; Christopher R. Glein; Ziming Yang

doi:10.1039/C9CC09825A

Effect of copper salts on hydrothermal oxidative decarboxylation: A study of phenylacetic acid

Chemical Communications (London)

By: Xuan Fu, Megan Jamison, Aaron M. Jubb, Yiju Liao, Alexandria Aspin, Kyle Hayes, Christopher R. Glein, and Ziming Yang

https://doi.org/10.1039/C9CC09825A

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Abstract

Decarboxylation of carboxylic acids is favored under hydrothermal conditions, and can be influenced by dissolved metals. Here, we use phenylacetic acid as a model compound to study its hydrothermal decarboxylation in the presence of copper(II) salts but no O₂. Our results showed a strong oxidizing role of copper in facilitating oxidative decarboxylation.

Additional publication details
Publication type	Article
Publication Subtype	Journal Article
Title	Effect of copper salts on hydrothermal oxidative decarboxylation: A study of phenylacetic acid
Series title	Chemical Communications (London)
DOI	10.1039/C9CC09825A
Volume	56
Issue	18
Year Published	2020
Language	English
Publisher	Royal Society of Chemistry
Contributing office(s)	Eastern Energy Resources Science Center
Description	4 p.
First page	2791
Last page	2794