Chemical and textural controls on phosphorus mobility in drylands of southeastern Utah
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Abstract
We investigated several forms of phosphorus (P) in dryland soils to examine the chemical and textural controls on P stabilization on a diverse set of substrates. We examined three P fractions including labile, moderately labile, and occluded as determined by a modified Hedley fractionation technique. The P fractions were compared to texture measurements and total elemental concentrations determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Labile P related to the absence of materials involved in P sorption. Moderately labile P was most strongly associated with high total Al & Fe content that we interpret to represent oxides and 1:1 clay minerals. The occluded P fraction was strongly associated with low total Al & Fe environments and interpreted to represent 2:1 clay minerals where ligand exchange tightly sequesters P. The results indicate that the controls on P fraction distribution are initially closely tied to the chemical and physical properties of the bedrock units that contribute to soil formation. Further, these results suggest that the progression of stabilized P forms in dryland areas differs from the progression observed in mesic environments. Soil development in dryland settings, such as the formation of pedogenic carbonates, may lead to differing controls on P availability and the proportional size of the moderately labile fraction.
Study Area
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Chemical and textural controls on phosphorus mobility in drylands of southeastern Utah |
| Series title | Biogeochemistry |
| DOI | 10.1007/s10533-010-9408-7 |
| Volume | 100 |
| Publication Date | February 11, 2010 |
| Year Published | 2010 |
| Language | English |
| Publisher | Springer |
| Contributing office(s) | Geosciences and Environmental Change Science Center |
| Description | 16 p. |
| First page | 105 |
| Last page | 120 |
| Country | United States |
| State | Utah |
| Other Geospatial | Canyonlands National Park |