Heat capacities of gibbsite, Al(OH)3, between 13 and 480 K and magnesite, MgCO3, between 13 and 380 K and their standard entropies at 289.15 K, and the heat capacities of Calorimetry Conference benzoic acid between 12 and 316 K
Journal of Research of the U.S. Geological Survey
By: Bruce S. Hemingway, Richard A. Robie, James R. Fisher, and William H. Wilson
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Abstract
The heat capacities of gibbsite and magnesite were measured between 13 and 380 K by means of an adiabatic calorimeter. The heat capacity of gibbsite was measured continuously between 340 and 480 K by means of a differential scanning calorimeter. Tables of the thermodynamic functions C°P, (H°T–H°O)/T,–(G°T–H°O)/T, and S°T–S°O are presented for these phases at integral temperatures. S°T–S°O are 68.44±0.14 J/(K•mol) and 65.09±0.13 J/(K•mol) at 298.15 K for gibbsite and magnesite, respectively. The heat capacities of Calorimetry Conference benzoic acid have been remeasured between 12 and 316 K.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Heat capacities of gibbsite, Al(OH)3, between 13 and 480 K and magnesite, MgCO3, between 13 and 380 K and their standard entropies at 289.15 K, and the heat capacities of Calorimetry Conference benzoic acid between 12 and 316 K |
| Series title | Journal of Research of the U.S. Geological Survey |
| Volume | 5 |
| Issue | 6 |
| Year Published | 1977 |
| Language | English |
| Publisher | U.S. Geological Survey |
| Description | 10 p. |
| First page | 797 |
| Last page | 806 |
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