A dataset of site conditions at 101 Italian ground motion stations with recorded motions has been compiled that includes geologic characteristics and seismic velocities. Geologic characterization is derived principally from local geologic investigations by ENEL that include detailed mapping and cross sections. For sites lacking such detailed geologic characterization, the geology maps of the by Servizio Geologico d'Italia are used. Seismic velocities are extracted from the literature and the files of consulting engineers, geologists and public agencies for 33 sites. Data sources utilized include post earthquake site investigations (Friuli and Irpinia events), microzonation studies, and miscellaneous investigations performed by researchers or consulting engineers/geologists. Additional seismic velocities are measured by the authors using the controlled source spectral analysis of surface waves (SASW) method for 18 sites that recorded the 1997–1998 Umbria Marche earthquake sequence. The compiled velocity measurements provide data for 51 of the 101 sites. For the remaining sites, the average seismic velocity in the upper 30 m (Vs30) is estimated using a hybrid approach. For young Quaternary alluvium, 𝑉s30 an existing empirical relationship for California sites by Wills and Clahan (2006) is used, which we justify by validating this relationship against Italian data. For Tertiary Limestone and Italian Mesozoic rocks, empirical estimates of 𝑉s30 are developed using the available data.