Enhanced petrogenic organic carbon oxidation during the Paleocene-Eocene thermal maximum

Geochemical Perspectives Letters
By: , and 

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Abstract

The Paleocene-Eocene thermal maximum (PETM; ∼56 Ma) is a hyperthermal event associated with the rapid input of carbon into the ocean-atmosphere system. The oxidation of petrogenic organic carbon (OCpetro) may have released additional carbon dioxide (CO2), thereby prolonging the PETM. However, proxy-based estimates of OCpetro oxidation are unavailable due to the lack of suitable techniques. Raman spectroscopy is used to evaluate OCpetro oxidation in modern settings. For the first time, we explore whether Raman spectroscopy can evaluate OCpetro oxidation during the PETM. In the mid-Atlantic Coastal Plain, there is a shift from disordered to graphitised carbon. This is consistent with enhanced oxidation of disordered OCpetro and intensified physical erosion. In the Arctic Ocean, the distribution of graphitised carbon vs. disordered carbon does not change, suggesting limited variability in weathering intensity. Overall, this study provides the first evidence of increased OCpetro oxidation during the PETM, although it was likely not globally uniform. Our work also highlights the utility of Raman spectroscopy as a novel tool to reconstruct OCpetro oxidation in the past.

Publication type Article
Publication Subtype Journal Article
Title Enhanced petrogenic organic carbon oxidation during the Paleocene-Eocene thermal maximum
Series title Geochemical Perspectives Letters
DOI 10.7185/geochemlet.2444
Volume 33
Year Published 2024
Language English
Publisher European Association of Geochemistry
Contributing office(s) Florence Bascom Geoscience Center
Description 6 p.
First page 1
Last page 6
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