The impact of burial diagenesis on soil-formed minerals in paleosols using stable isotopes of phyllosilicates and carbonate clumped isotopes
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Abstract
To understand the effects of burial diagenesis on the stable isotope geochemistry of soil-formed clay and carbonate minerals in paleosols, samples were collected from seven cores, spanning middle- to upper-Pennsylvanian strata of the Illinois Basin, with varied maximum burial depths of 1–3 km. Mixed-layer illite-smectite and kaolinite mixtures give δ2H and δ18O values of −83 ‰ to −36 ‰ and 11.9 ‰ to 21.1 ‰ (VSMOW), respectively. After carbonates were screened petrographically for diagenetic textures using transmitted light and cathodoluminescence, measured clumped isotope Δ47 values range from 0.504 to 0.563 ‰ (I-CDES). Resulting mineral formation temperatures for phyllosilicate mineral mixtures are 28 to 66 °C (mean = 47 °C), whereas T(Δ47) estimates for calcites are 36 to 61 °C (mean = 45 °C). Calculated δ18Owater values from which phyllosilicate minerals and calcites precipitated under isotopic equilibrium ranges from −7.1 to −1.2 ‰ and − 1.4 to +4.9 ‰, respectively. Closed and open-system phyllosilicate-fluid exchange modeling indicates that phyllosilicate alteration occurred in the presence of a low temperature brine or meteoric water and is interpreted to occur in a layer-by-layer illitization transformation. Due to the lack of diagenetic textures and positively correlated T(Δ47) and δ18Owater, calcites are interpreted to have undergone solid-state bond reordering. Despite low to moderate temperatures (<125 °C) and varying depths of shallow burial (1–3 km), solid-state transformation of phyllosilicates and calcites indicates paleosols had prolonged exposure to burial conditions which has implications for the use of paleosol minerals for paleoenvironmental reconstructions.
Study Area
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | The impact of burial diagenesis on soil-formed minerals in paleosols using stable isotopes of phyllosilicates and carbonate clumped isotopes |
| Series title | Chemical Geology |
| DOI | 10.1016/j.chemgeo.2025.122941 |
| Volume | 692 |
| Year Published | 2025 |
| Language | English |
| Publisher | Elsevier |
| Contributing office(s) | Geology, Geophysics, and Geochemistry Science Center |
| Description | 122941, 17 p. |
| Country | United States |
| State | Illinois, Indiana, Kentucky |
| Other Geospatial | Illinois Basin |