Ecological factors decouple Great Lakes fish mercury concentrations trends decadal declines in mercury emissions

Environmental Science and Technology
By: , and 

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Abstract

Atmospheric mercury (Hg) deposition has been declining in North America but remains the dominant delivery mechanism to the Great Lakes. The Lakes are highly efficient at bioaccumulating methylmercury, making the fish excellent sentinels for tracking shifts in atmospheric Hg deposition. Invasive mussels have altered biogeochemical processes, prey populations and fish dietary strategies asynchronously and to varied extents across the lower four lakes, impacting fish Hg exposure. To test if fish are adapting to new biogeochemical conditions, we analyzed a 40 year fish archive for carbon and nitrogen isotope ratios and amino acid-specific nitrogen isotope ratios. To assess Hg sources, we measured Hg isotope ratios. We reconstructed and compared energetic pathways that impact fish Hg concentrations to Hg-source trends. We found fish-Hg concentrations are declining but not monotonically due to ecological disturbances. Fish-Hg isotope values, unimpacted by ecological disturbance, confirm that sources of bioaccumulated Hg shift contemporaneously with changes in atmospheric Hg concentrations. Across Lakes, the degree of responsiveness to changes in atmospheric Hg concentrations mirrors the proportion of atmospheric-delivered Hg we previously modeled. Changes in both fish concentrations and fish isotope values outpace paleolimnetic reconstructions suggesting declines in atmospheric Hg concentrations impact fish Hg more than sediment.

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Publication type Article
Publication Subtype Journal Article
Title Ecological factors decouple Great Lakes fish mercury concentrations trends decadal declines in mercury emissions
Series title Environmental Science and Technology
DOI 10.1021/acs.est.5c01359
Volume 59
Issue 23
Publication Date June 06, 2025
Year Published 2025
Language English
Publisher American Chemical Society
Contributing office(s) Upper Midwest Water Science Center
Description 10 p.
First page 11799
Last page 11808
Country Canada, United States
Other Geospatial Great Lakes
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