Using bioavailability modeling to refine copper treatments for zebra mussel control and better understanding risks to non-target species

Scientific Reports
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Abstract

Copper can be toxic to aquatic organisms at high concentrations and has been previously used successfully to control zebra mussels (Dreissena polymorpha). Because copper’s toxicity changes with water chemistry, using the same copper concentration in different waterbodies could yield different outcomes. We demonstrate how measuring water chemistry parameters and using the Biotic Ligand Model (BLM) and multiple linear regression (MLR) models can predict a suitable, site-specific copper concentration for management. We exposed zebra mussel adults and non-target organisms to varying concentrations of copper over 10 d in a mobile laboratory. We found that one non-target species, Daphnia magna, had a 50% chance of survival at 9.50 µg Cu/L (i.e., the 50% lethal concentration, LC50), within our BLM-predicted range of 3.38–16.95 µg Cu/L LC50 values. In the future, managers could make similar predictions and tailor their copper concentrations to their management goals. We also measured zebra mussel larvae mortality at copper concentrations ranging from 0 to 191 µg Cu/L. While those results were inconclusive, we present the results of this work as a foundation for future projects. Our study underscores the importance of developing site-specific copper concentration recommendations and demonstrates the potential utility of the BLM and MLR approaches for informing those recommendations.

Suggested Citation

Dahlberg, A.D., Waller, D.L., Severson, T.J., Barbour, M.T., Meulemans, M., Wise, J.K., Bajcz, A.W., Jankowski, M., and Phelps, N.B., 2025, Using bioavailability modeling to refine copper treatments for zebra mussel control and better understanding risks to non-target species: Scientific Reports, v. 15, 29333, 16 p., https://doi.org/10.1038/s41598-025-09231-4.

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Publication type Article
Publication Subtype Journal Article
Title Using bioavailability modeling to refine copper treatments for zebra mussel control and better understanding risks to non-target species
Series title Scientific Reports
DOI 10.1038/s41598-025-09231-4
Volume 15
Publication Date August 11, 2025
Year Published 2025
Language English
Publisher Springer Nature
Contributing office(s) Upper Midwest Environmental Sciences Center
Description 29333, 16 p.
Country United States
State Minnesota
Other Geospatial Pelican Lake
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