Origin of the Pd/Pt ratio of the J-M Reef, Stillwater Complex, Montana, USA

Economic Geology
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Abstract

The J-M reef of the Stillwater Complex is characterized by a high Pd/Pt ratio (mean ~3.8 with a standard error of 0.03) with a homogeneous geospatial distribution at the deposit scale. In this contribution, we demonstrate that the Pd/Pt ratio of the reef is the product of equilibration of an immiscible sulfide liquid with a silicate melt rich in Pd relative to Pt. Despite the high tenors of the J-M reef sulfides (avg 2,700 ppm Pt and 770 ppm Pt), numerical modeling shows that the parental melts did not have extraordinary Pd and Pt concentrations. Instead, the initial composition of a plausible parental silicate melt can have Pd and Pt contents well within the expected range of a normal, mantle-derived partial melt (i.e., ~10–20 ppb for both Pd and Pt with Pd/Pt of ~1). The relative differences in the partitioning behavior of Pt and Pd between sulfide liquid and silicate melt are unlikely to produce a consistent Pd/Pt ratio across a wide range of silicate melt to sulfide liquid mass ratios (i.e., R factors). Instead, the pre-emplacement fractionation of Pt alloy from S-undersaturated silicate magma accounts for the homogeneous and high Pd/Pt ratio of the J-M reef. We show that batch equilibration of sulfide liquid with silicate melt can produce the high Pd/Pt ratios of the reef if the partition coefficients between sulfide liquid and silicate melt for Pd and Pt are extremely high (>106). In an alternative model, Pd enrichment could be achieved by sulfide upgrading in resident footwall mush even if the partition coefficients between sulfide liquid and silicate melt are relatively small (between 104 and 106) because the instantaneous mass ratio of silicate melt to sulfide liquid is small (R ≈ 100–700), so the partitioning behavior of Pt and Pd has little impact on the composition of sulfide liquid.

Suggested Citation

Jenkins, M., and Smith, W.D., 2026, Origin of the Pd/Pt ratio of the J-M Reef, Stillwater Complex, Montana, USA: Economic Geology, v. 121, no. 2, p. 414-427, https://doi.org/10.5382/econgeo.5217.

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Publication type Article
Publication Subtype Journal Article
Title Origin of the Pd/Pt ratio of the J-M Reef, Stillwater Complex, Montana, USA
Series title Economic Geology
DOI 10.5382/econgeo.5217
Volume 121
Issue 2
Publication Date February 01, 2026
Year Published 2026
Language English
Publisher Society of Economic Geologists
Contributing office(s) Geology, Minerals, Energy, and Geophysics Science Center
Description 14 p.
First page 414
Last page 427
Country United States
State Montana
Other Geospatial Stillwater Complex
Additional publication details