This geologic map of the Kings Mountain and Grover 7.5-min quadrangles, N.C.-S.C., straddles a regional geological boundary between the Inner Piedmont and Carolina terranes. The Kings Mountain sequence (informal name) on the western flank of the Carolina terrane in this area includes the Neoproterozoic Battleground and Blacksburg Formations. The Battleground Formation has a lower part consisting of metavolcanic rocks and interlayered schist and an upper part consisting of quartz-sericite phyllite and schist interlayered with quartz-pebble metaconglomerate, aluminous quartzite, micaceous quartzite, manganiferous rock, and metavolcanic rocks. The Blacks-burg Formation consists of phyllitic metasiltstone interlayered with thinner units of marble, laminated micaceous quartzite, hornblende gneiss, and amphibolite. Layered metamorphic rocks of the Inner Piedmont terrane include muscovite-biotite gneiss, muscovite schist, and amphibolite. The Kings Mountain sequence has been intruded by metatonalite and metatrondhjemite (Neoproterozoic), metagabbro and metadiorite (Paleozoic?), and the High Shoals Granite (Pennsylvanian). Layered metamorphic rocks of the Inner Piedmont in this area have been intruded by the Toluca Granite (Ordovician?), the Cherryville Granite and associated pegmatite (Mississippian), and spodumene pegmatite (Mississippian). Diabase dikes (early Jurassic) are locally present throughout the area. Ductile fault zones of regional scale include the Kings Mountain and Kings Creek shear zones. In this area, the Kings Mountain shear zone forms the boundary between the Inner Piedmont and Carolina terranes, and the Kings Creek shear zone separates the Battleground Formation from the Blacksburg Formation. Structural styles change across the Kings Mountain shear zone from steeply dipping layers, foliations, and folds on the southeast to gently and moderately dipping layers, foliations, and recumbent folds on the northwest. Mineral assemblages in the Kings Mountain sequence show a westward decrease from upper amphibolite facies (sillimanite zone) near the High Shoals Granite in the eastern side of the map area to upper greenschist (epidote-amphibolite) facies in the south-central part of the area near the Kings Mountain shear zone. Amphibolite-facies mineral assemblages in the Inner Piedmont terrane increase in grade from the kyanite zone near the Kings Mountain shear zone to the sillimanite zone in the northwestern part of the map area. Surficial deposits include alluvium in the stream valleys and colluvium along ridges and steep slopes. These quadrangles are unusual in the richness and variety of the mineral deposits that they contain, which include spodumene (lithium), cassiterite (tin), mica, feldspar, silica, clay, marble, kyanite and sillimanite, barite, manganese, sand and gravel, gold, pyrite, and iron.