The U.S. Geological Survey maintains a quality-assurance program based on the analysis of reference samples for its two water-analysis laboratories located in Atlanta, Georgia, and Denver, Colorado. Reference samples containing inorganic constituents are prepared at the U.S. Geological Survey 's Ocala , Florida, office and disguised as routine samples, and sent daily to each laboratory through other U.S. Geological Survey offices. The results are permanently stored in the National Water Data Storage and Retrieval System (WATSTORE), the U.S. Geological Survey 's data base for all water data. These data are analyzed statistically for precision and bias. The results of these statistical analyses are presented for data collected during the 1982 water year. In addition, one sample containing known concentrations of trihalomethanes was analyzed in both laboratories, and these results also are presented. (USGS)