Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, July 2015
Raegan L. Huffman
2016, Data Series 998
Previous investigations indicate that concentrations of chlorinated volatile organic compounds (CVOCs) are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant...
Preliminary investigation of groundwater flow and trichloroethene transport in the Surficial Aquifer System, Naval Industrial Reserve Ordnance Plant, Fridley, Minnesota
Jeffrey N. King, J. Hal Davis
2016, Open-File Report 2016-1066
Industrial practices at the Naval Industrial Reserve Ordnance Plant, in Fridley, Minnesota, caused soil and groundwater contamination. Some volatile organic compounds from the plant might have discharged to the Mississippi River, forced by the natural hydraulic gradient in the surficial aquifer system. The U.S. Environmental Protection Agency included the Naval...
Assessing atmospheric concentration of polychlorinated biphenyls (PCBs) by evergreen Rhododendron maximum next to a contaminated stream
Viet D. Dang, David Walters, Cindy M. Lee
2016, Environmental Toxicology and Chemistry (35) 2192-2198
Conifers are often used as an “air passive sampler”, but few studies have focused on the implication of broadleaf evergreens to monitor atmospheric semivolatile organic compounds such as polychlorinated biphenyls (PCBs). In this study, we used Rhododendron maximum (rhododendron) growing next to a contaminated stream to assess atmospheric PCB concentrations. The study...
Notes on the origin of copromacrinite based on nitrogen functionalities and δ13C and δ15N determined on samples from the Peach Orchard coal bed, southern Magoffin County, Kentucky
Bruno Valentim, Manuel Algarra, Alexandra Guedes, Leslie F. Ruppert, James C. Hower
2016, International Journal of Coal Geology (160-161) 63-72
This paper represents the first attempt to show, by means other than just petrographic ones, that one type of macrinite, herein designated copromacrinite, may result from macrofauna feces. For that purpose a combination of coal petrography, X-ray photoelectron spectroscopy, and elemental-analysis continuous-flow isotope ratio mass spectrometry methods were used...
Asthenosphere–lithosphere interactions in Western Saudi Arabia: Inferences from 3He/4He in xenoliths and lava flows from Harrat Hutaymah
Kevin Konrad, David W. Graham, Carl Thornber, Robert A. Duncan, Adam J. R. Kent, Abdulla Al-Amri
2016, LITHOS (248-251) 339-352
Extensive volcanic fields on the western Arabian Plate have erupted intermittently over the last 30 Ma following emplacement of the Afar flood basalts in Ethiopia. In an effort to better understand the origin of this volcanism in western Saudi Arabia, we analyzed3He/4He, and He, CO2 and trace element concentrations in minerals...
Potentiometric surfaces of the Arnold Engineering Development Complex Area, Arnold Air Force Base, Tennessee, May and September 2011
Connor J. Haugh, John A. Robinson
2016, Scientific Investigations Report 2015-5165
Arnold Air Force Base occupies about 40,000 acres in Coffee and Franklin Counties, Tennessee. The primary mission of Arnold Air Force Base is to provide risk-reduction information in the development of aerospace products through test and evaluation. This mission is achieved in part through test facilities at Arnold Engineering Development...
Volatile-organic molecular characterization of shale-oil produced water from the Permian Basin
Naima A. Khan, Mark A. Engle, Barry Dungan, F. Omar Holguin, Pei Xu, Kenneth C. Carroll
2016, Chemosphere (148) 126-136
Growth in unconventional oil and gas has spurred concerns on environmental impact and interest in beneficial uses of produced water (PW), especially in arid regions such as the Permian Basin, the largest U.S. tight-oil producer. To evaluate environmental impact, treatment, and reuse potential, there is a need to characterize the...
The conjunction of factors that lead to formation of giant gold provinces and deposits in non-arc settings
David I. Groves, Richard J. Goldfarb, M. Santosh
2016, Geoscience Frontiers (7) 303-314
It is quite evident that it is not anomalous metal transport, nor unique depositional conditions, nor any single factor at the deposit scale, that dictates whether a mineral deposit becomes a giant or not. A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales...
Chemical concentrations and instantaneous loads, Green River to the Lower Duwamish Waterway near Seattle, Washington, 2013–15
Kathleen E. Conn, Robert W. Black, Ann M. Vanderpool-Kimura, James R. Foreman, Norman T. Peterson, Craig A. Senter, Stephen K. Sissel
2015, Data Series 973
In November 2013, U.S. Geological Survey streamgaging equipment was installed at a historical water-quality station on the Duwamish River, Washington, within the tidal influence at river kilometer 16.7 (U.S. Geological Survey site 12113390; Duwamish River at Golf Course at Tukwila, WA). Publicly available, real-time continuous data includes river streamflow, stream...
Monitoring changes in seismic velocity related to an ongoing rapid inflation event at Okmok volcano, Alaska
Ninfa Bennington, Matthew M. Haney, Silvio De Angelis, Clifford Thurber, Jeff Freymueller
2015, Journal of Geophysical Research (120) 5664-5676
Okmok is one of the most active volcanoes in the Aleutian Arc. In an effort to improve our ability to detect precursory activity leading to eruption at Okmok, we monitor a recent, and possibly ongoing, GPS-inferred rapid inflation event at the volcano using ambient noise interferometry (ANI). Applying this method,...
Substantial contribution of biomethylation to aquifer arsenic cycling
Scott C. Maguffin, Matthew F. Kirk, Ashley R. Daigle, Stephen R. Hinkle, Qusheng Jin
2015, Nature Geoscience (8) 290-293
Microbes play a prominent role in transforming arsenic to and from immobile forms in aquifers1. Much of this cycling involves inorganic forms of arsenic2, but microbes can also generate organic forms through methylation3, although this process is often considered insignificant in aquifers4, 5, 6, 7. Here we identify the presence...
Groundwater quality in the Chemung River, Eastern Lake Ontario, and Lower Hudson River Basins, New York, 2013
Tia-Marie Scott, Elizabeth A. Nystrom, James E. Reddy
2015, Open-File Report 2015-1168
In a study conducted by the U.S. Geological Survey (USGS) in cooperation with the New York State Department of Environmental Conservation, water samples were collected from 4 production wells and 4 domestic wells in the Chemung River Basin, 8 production wells and 7 domestic wells in the Eastern Lake Ontario...
Limited role for thermal erosion by turbulent lava in proximal Athabasca Valles, Mars
Vincenzo Cataldo, David A. Williams, Colin M. Dundas, Laszlo P. Keszthelyi
2015, Journal of Geophysical Research E: Planets (120) 1800-1819
The Athabasca Valles flood lava is among the most recent (<50 Ma) and best preserved effusive lava flows on Mars and was probably emplaced turbulently. The Williams et al. (2005) model of thermal erosion by lava has been applied to what we term “proximal Athabasca,” the 75 km long upstream portion of...
Stable carbon isotope fractionation during bacterial acetylene fermentation: Potential for life detection in hydrocarbon-rich volatiles of icy planet(oid)s
Laurence Miller, Shaun Baesman, Ron Oremland
2015, Astrobiology (15) 977-986
We report the first study of stable carbon isotope fractionation during microbial fermentation of acetylene (C2H2) in sediments, sediment enrichments, and bacterial cultures. Kinetic isotope effects (KIEs) averaged 3.7 ± 0.5‰ for slurries prepared with sediment collected at an intertidal mudflat in San Francisco Bay and 2.7 ± 0.2‰ for a pure culture of Pelobacter sp....
Monitoring gas emissions can help forecast volcanic eruptions
Christoph Kern, J. Maarten de Moor, Bo Galle
2015, Eos, Earth and Space Science News (96) 6-6
As magma ascends in active volcanoes, dissolved volatiles partition from melt into a gas phase, rise, and are released into the atmosphere from volcanic vents. The major components of high-temperature volcanic gas are typically water vapor, carbon dioxide, and sulfur dioxide. Volcanologists have long recognized that measuring the chemical composition and emission rates...
Feasibility and potential effects of the proposed Amargosa Creek Recharge Project, Palmdale, California
Allen H. Christensen, Adam J. Siade, Peter Martin, Victoria E. Langenheim, Rufus D. Catchings, Matthew K. Burgess
2015, Scientific Investigations Report 2015-5054
Historically, the city of Palmdale and vicinity have relied on groundwater as the primary source of water, owing, in large part, to the scarcity of surface water in the region. Despite recent importing of surface water, groundwater withdrawal for municipal, industrial, and agricultural use has resulted in groundwater-level declines...
Tracing chlorine sources of thermal and mineral springs along and across the Cascade Range using halogen and chlorine isotope compositions
Jeffrey T. Cullen, Jaime D. Barnes, Shaul Hurwitz, William P. Leeman
2015, Earth and Planetary Science Letters (426) 225-234
In order to provide constraints on the sources of chlorine in spring waters associated with arc volcanism, the major/minor element concentrations and stable isotope compositions of chlorine, oxygen, and hydrogen were measured in 28 thermal and mineral springs along the Cascade Range in northwestern USA. Chloride concentrations in the springs...
Evaluation of the toxicity of sediments from the Anniston PCB Site to the mussel Lampsilis siliquoidea
Allison Schein, Jesse A. Sinclair, Donald D. MacDonald, Christopher G. Ingersoll, Nile E. Kemble, James L. Kunz
2015, Report
The Anniston Polychlorinated Biphenyl (PCB) Site is located in the vicinity of the municipality of Anniston in Calhoun County, in the north-eastern portion of Alabama. Although there are a variety of land-use activities within the Choccolocco Creek watershed, environmental concerns in the area have focused mainly on releases of PCBs...
Mineral Resource of the Month: Bromine
Emily Schnebele
2015, Earth (September 2015)
Bromine, along with mercury, is one of only two elements that are liquid at room temperature. Bromine is a highly volatile and corrosive reddish-brown liquid that evaporates easily and converts to a metal at extreme pressures — above about 540,000 times atmospheric pressure. Bromine occurs in seawater, evaporitic (salt) lakes...
Groundwater quality data in 15 GAMA study units: results from the 2006–10 Initial sampling and the 2009–13 resampling of wells, California GAMA Priority Basin Project
Robert Kent
2015, Data Series 919
The Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) program was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). From May...
Organic and inorganic composition and microbiology of produced waters from Pennsylvania shale gas wells
Denise M. Akob, Isabelle M. Cozzarelli, Darren S. Dunlap, Elisabeth L. Rowan, Michelle M. Lorah
2015, Applied Geochemistry (60) 116-125
Hydraulically fractured shales are becoming an increasingly important source of natural gas production in the United States. This process has been known to create up to 420 gallons of produced water (PW) per day, but the volume varies depending on the formation, and the characteristics of individual hydraulic fracture. PW...
An automated SO2 camera system for continuous, real-time monitoring of gas emissions from Kīlauea Volcano's summit Overlook Crater
Christoph Kern, Jeff Sutton, Tamar Elias, Robert Lopaka Lee, Kevan P. Kamibayashi, Loren Antolik, Cynthia A. Werner
2015, Journal of Volcanology and Geothermal Research (300) 81-94
SO2 camera systems allow rapid two-dimensional imaging of sulfur dioxide (SO2) emitted from volcanic vents. Here, we describe the development of an SO2 camera system specifically designed for semi-permanent field installation and continuous use. The integration of innovative but largely “off-the-shelf” components allowed us to assemble a robust and highly customizable instrument...
Mapping of coal quality using stochastic simulation and isometric logratio transformation with an application to a Texas lignite
Ricardo A. Olea, James A. Luppens
2015, International Journal of Coal Geology (152) 80-93
Coal is a chemically complex commodity that often contains most of the natural elements in the periodic table. Coal constituents are conventionally grouped into four components (proximate analysis): fixed carbon, ash, inherent moisture, and volatile matter. These four parts, customarily measured as weight losses and expressed as percentages, share all...
Groundwater quality in Geauga County, Ohio: status, including detection frequency of methane in water wells, 2009, and changes during 1978-2009
Martha L. Jagucki, Stephanie P. Kula, Brian E. Mailot
2015, Scientific Investigations Report 2015-5032
Domestic wells that are not safeguarded by regular water-quality testing provide drinking water for 79 percent of the residents of Geauga County, in northeastern Ohio. Since 1978, the U.S. Geological Survey (USGS) has worked cooperatively with the Board of Commissioners and Geauga County Planning Commission to monitor the quality of...
Organic contaminant transport and fate in the subsurface: evolution of knowledge and understanding
Hedeff I. Essaid, Barbara A. Bekins, Isabelle M. Cozzarelli
2015, Water Resources Research (51) 4861-4902
Toxic organic contaminants may enter the subsurface as slightly soluble and volatile nonaqueous phase liquids (NAPLs) or as dissolved solutes resulting in contaminant plumes emanating from the source zone. A large body of research published in Water Resources Research has been devoted to characterizing and understanding processes controlling the transport and fate...