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Principal component analysis (PCA) applied to hydrochemical data has been used with end-member mixing to characterize groundwater flow to a limited extent, but aspects of this approach are unresolved. Previous similar approaches typically have assumed that the extreme-value samples identified by PCA represent end members. The method presented herein is...

The geochemical model PHREEQC is capable of simulating a wide range of equilibrium reactions between water and minerals, ion exchangers, surface complexes, solid solutions, and gases. It also has a general kinetic formulation that allows modeling of nonequilibrium mineral dissolution and precipitation, microbial reactions, decomposition of organic compounds, and other...

We measured mercury (Hg) concentrations and calculated export and yield from the Yukon River Basin (YRB) to quantify Hg flux from a large, permafrost-dominated, high-latitude watershed. Exports of Hg averaged 4400 kg Hg yr-1. The average annual yield for the YRB during the study period was 5.17 μg m-2 yr-1,...

The formation of acid mine drainage from metals extraction or natural acid rock drainage and its mixing with surface waters is a complex process that depends on petrology and mineralogy, structural geology, geomorphology, surface-water hydrology, hydrogeology, climatology, microbiology, chemistry, and mining and mineral processing history. The concentrations of metals, metalloids,...

Understanding the effects of climate change on the vegetative growing season is key to quantifying future hydrologic water budget conditions. The U.S. Geological Survey modeled changes in future growing season length at 14 basins across 11 states. Simulations for each basin were generated using five general circulation models with three...

Direct determination of mercury (Hg) speciation in sulfide-containing environments is confounded by low mercury concentrations and poor analytical sensitivity. Here we report the results of experiments designed to assess mercury speciation at environmentally relevant ratios of mercury to dissolved organic matter (DOM) (i.e., <4 nmol Hg (mg DOM)−1) by combining...

Stream flow in urban aquatic ecosystems often is maintained by water-reclamation plant (WRP) effluents that contain mixtures of natural and anthropogenic chemicals that persist through the treatment processes. In effluent-impactedstreams, aquatic organisms such as fish are continuously exposed to biologically-activechemicals throughout their life cycles. The North Shore Channel of the...

Antidepressant pharmaceuticals have been reported in wastewater effluent at the nanogram to low microgram-per-liter range, and include bupropion (BUP), fluoxetine (FLX), sertraline (SER), and venlafaxine (VEN). To assess the effects of antidepressants on reproductive anatomy, physiology, and behavior, adult male fathead minnows (Pimeplwles promelas) were exposed for 21 days either...

This report summarizes the environmental settings of streams in New York and South Carolina, where the U.S. Geological Survey completed detailed investigations during 2005-09 into factors contributing to mercury bioaccumulation in top-predator fish and other stream organisms. Descriptions of location, land use/land cover, climate, precipitation, atmospheric deposition, hydrology, water temperature,...

Nonylphenolic compounds (NPs), coprostanol (COP), and cholestanol, major contaminants in industrial and domestic wastewaters, were analyzed in creek water, wastewater treatment plant (WWTP) effluent, and sediment samples from artificial Lake Shihwa and its vicinity, one of the most industrialized regions in Korea. We also determined mass discharge of NPs and...

Calcite crystallization rates are characterized using a constant solution composition at 25°C, pH=8.5, and calcite supersaturation (Ω) of 4.5 in the absence and presence of fulvic acids isolated from Big Soda Lake, Nevada (BSLFA), and a fulvic acid from the Suwannee River, Georgia (SRFA). Rates are also measured in the...

Concentrations of dissolved orthophosphate (ortho P) in the unsaturated zone, groundwater, tile drains, and groundwater/stream water interfaces were assessed in five agricultural watersheds to determine the potential for subsurface transport. Concentrations of iron oxides were measured in the aquifer material and adsorption of ortho P on oxide surfaces was assessed...

Highly resolved time series data are useful to accurately identify the timing, rate, and magnitude of solute transport in streams during hydrologically dynamic periods such as snowmelt. We used in situ optical sensors for nitrate (NO3-) and chromophoric dissolved organic matter fluorescence (FDOM) to measure surface water concentrations at 30...

A 3-year study was conducted by the U.S. Geological Survey and the University of Wisconsin-Green Bay to characterize water quality in agricultural streams in the Fox/Wolf watershed in northeastern Wisconsin and provide information to assist in the calibration of a watershed model for the area. Streamflow, phosphorus, and suspended solids...

Natural clays have been used in ancient and modern medicine, but the mechanism(s) that make certain clays lethal against bacterial pathogens has not been identified. We have compared the depositional environments, mineralogies, and chemistries of clays that exhibit antibacterial effects on a broad spectrum of human pathogens including antibiotic resistant...

Surface water samples were collected in 2006 from a lead mine-mill complex in Missouri to investigate possible organic compounds coming from the milling process. Water samples contained relatively high concentrations of dissolved organic carbon (DOC; greater than 20 mg/l) for surface waters but were colorless, implying a lack of naturally...

Cattle (Bos taurus) numbers on national forests are allocated based on allotment grazing capacity, but spatial patterns of timing and density at smaller scales are difficult to assess. However, it is often in meadows or riparian areas that grazing may affect hydrology, biodiversity, and other important ecosystem characteristics. To explore...

Water-resource managers in Onondaga County, New York, are faced with the challenge of improving the water quality of Onondaga Lake, which has the distinction of being one of the most contaminated lakes in the United States. To assist in this endeavor, during 2003-07 the U.S. Geological Survey (USGS), in cooperation...

In the 300 Area of a U(VI)-contaminated aquifer at Hanford, Washington, USA, inorganic carbon and major cations, which have large impacts on U(VI) transport, change on an hourly and seasonal basis near the Columbia River. Batch and column experiments were conducted to investigate the factors controlling U(VI) adsorption/desorption by changing...

Background This commentary evolved from a workshop sponsored by the National Institute of Environmental Health Sciences titled "Superfund Contaminants: The Next Generation" held in Tucson, Arizona, in August 2009. All the authors were workshop participants. Objectives Our aim was to initiate a dynamic, adaptable process for identifying contaminants of emerging concern...

The U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture Natural Resources Conservation Service, the Edwards Region Grazing Lands Conservation Initiative, the Texas State Soil and Water Conservation Board, the San Antonio River Authority, the Edwards Aquifer Authority, Texas Parks and Wildlife, the Guadalupe Blanco River Authority, and...

Water and emergent vegetation are key features influencing nest site selection and success for many marsh-nesting waterbirds. Wetland management practices such as grazing, burning, and water-level manipulations directly affect these features and can influence nest survival. We used model selection and before-after-control-impact approaches to evaluate the effects of water depth...

The City of Wilmington, Delaware, is in the downstream part of the Brandywine Creek Basin, on the main stem of Brandywine Creek. Wilmington uses this stream, which drains a mixed-land-use area upstream, for its main drinking-water supply. Because the stream is used for drinking water, Wilmington is in need of...

A water, energy, and biogeochemical model (WEBMOD) was constructed to simulate hydrology and pyrite oxidation for the period October 1992 through September 1997. The hydrologic model simulates processes in Loch Vale, a 6.6-km² granitic watershed that drains the east side of the Continental Divide. Parameters describing pyrite oxidation were derived...

Simplicity is the final achievement. After one has played a vast quantity of notes and more notes, it is simplicity that emerges as the crowning reward of art. (Frédéric Chopin, a musician and composer, quoted in If Not God, Then What? by Fost 2007)Despite the dubious developments...