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Hydrologic and biogeochemical controls of river subsurface solutes under agriculturally enhanced ground water flow
R.A. Wildman Jr., Joseph L. Domagalski, J. G. Hering
2009, Journal of Environmental Quality (38) 1830-1840
The relative influences of hydrologic processes and biogeochemistry on the transport and retention of minor solutes were compared in the riverbed of the lower Merced River (California, USA). The subsurface of this reach receives ground water discharge and surface water infiltration due to an altered hydraulic setting resulting from agricultural...
Estimating 3D variation in active-layer thickness beneath arctic streams using ground-penetrating radar
T.R. Brosten, J.H. Bradford, J. P. McNamara, M.N. Gooseff, J.P. Zarnetske, W.B. Bowden, M.E. Johnston
2009, Journal of Hydrology (373) 479-486
We acquired three-dimensional (3D) ground-penetrating radar (GPR) data across three stream sites on the North Slope, AK, in August 2005, to investigate the dependence of thaw depth on channel morphology. Data were migrated with mean velocities derived from multi-offset GPR profiles collected across a stream section within each of the...
Obtaining parsimonious hydraulic conductivity fields using head and transport observations: A Bayesian geostatistical parameter estimation approach
Michael N. Fienen, R. Hunt, D. Krabbenhoft, T. Clemo
2009, Water Resources Research (45)
Flow path delineation is a valuable tool for interpreting the subsurface hydrogeochemical environment. Different types of data, such as groundwater flow and transport, inform different aspects of hydrogeologic parameter values (hydraulic conductivity in this case) which, in turn, determine flow paths. This work combines flow and transport information to estimate...
High-quality unsaturated zone hydraulic property data for hydrologic applications
Kimberlie Perkins, John R. Nimmo
2009, Water Resources Research (45)
In hydrologic studies, especially those using dynamic unsaturated zone moisture modeling, calculations based on property transfer models informed by hydraulic property databases are often used in lieu of measured data from the site of interest. Reliance on database-informed predicted values has become increasingly common with the use of neural networks....
The changing global carbon cycle: Linking plant-soil carbon dynamics to global consequences
F. S. Chapin III, J. McFarland, David A. McGuire, E.S. Euskirchen, Roger W. Ruess, K. Kielland
2009, Journal of Ecology (97) 840-850
Most current climate-carbon cycle models that include the terrestrial carbon (C) cycle are based on a model developed 40 years ago by Woodwell & Whittaker (1968) and omit advances in biogeochemical understanding since that time. Their model treats net C emissions from ecosystems as the balance between net primary production...
Water uptake and nutrient concentrations under a floodplain oak savanna during a non-flood period, lower Cedar River, Iowa
K. E. Schilling, P. Jacobson
2009, Hydrological Processes (23) 3006-3016
Floodplains during non-flood periods are less well documented than when flooding occurs, but non-flood periods offer opportunities to investigate vegetation controls on water and nutrient cycling. In this study, we characterized water uptake and nutrient concentration patterns from 2005 to 2007 under an oak savanna located on the floodplain of...
Rapid changes in small fish mercury concentrations in estuarine wetlands: Implications for wildlife risk and monitoring programs
Collin A. Eagles-Smith, Joshua T. Ackerman
2009, Environmental Science & Technology (43) 8658-8664
Small fish are commonly used to assess mercury (Hg) risk to wildlife and monitor Hg in wetlands. However, limited research has evaluated short-term Hg variability in small fish, which can have important implications for monitoring programs and risk assessment. We conducted a time-series study of Hg concentrations in two small...
Is there evidence of adaptation to tidal flooding in saplings of baldcypress subjected to different salinity regimes?
K. W. Krauss, T.W. Doyle, R.J. Howard
2009, Environmental and Experimental Botany (67) 118-126
Plant populations may adapt to environmental conditions over time by developing genetically based morphological or physiological characteristics. For tidal freshwater forested wetlands, we hypothesized that the conditions under which trees developed led to ecotypic difference in response of progeny to hydroperiod. Specifically, we looked for evidence of ecotypic adaptation for...
Effects of introduced fish on macroinvertebrate communities in historically fishless headwater and kettle lakes
Emily Gaenzle Schilling, Cynthia S. Loftin, Alexander D. Huryn
2009, Biological Conservation (142) 3030-3038
Widespread fish introductions have led to a worldwide decline in the number of fishless lakes and their associated communities. Studies assessing effects of fish stocking on native communities in historically fishless lakes have been limited to high-elevation headwater lakes stocked with non-native trout. Little is known about the effect of...
Elevated naturally occurring arsenic in a semiarid oxidizing system, Southern High Plains aquifer, Texas, USA
Bridget R. Scanlon, J.-P. Nicot, R.C. Reedy, D. Kurtzman, A. Mukherjee, D. Kirk Nordstrom
2009, Applied Geochemistry (24) 2061-2071
High groundwater As concentrations in oxidizing systems are generally associated with As adsorption onto hydrous metal (Al, Fe or Mn) oxides and mobilization with increased pH. The objective of this study was to evaluate the distribution, sources and mobilization mechanisms of As in the Southern High Plains (SHP) aquifer, Texas,...
A comparison of pre- and post-remediation water quality, Mineral Creek, Colorado
R.L. Runkel, K.E. Bencala, B. A. Kimball, K. Walton-Day, P. L. Verplanck
2009, Hydrological Processes (23) 3319-3333
Pre- and post-remediation data sets are used herein to assess the effectiveness of remedial measures implemented in the headwaters of the Mineral Creek watershed, where contamination from hard rock mining has led to elevated metal concentrations and acidic pH. Collection of pre- and post-remediation data sets generally followed the synoptic...
Relationship between body condition of American alligators and water depth in the Everglades, Florida
Ikuko Fujisaki, Kenneth G. Rice, Leonard G. Pearlstine, Frank J. Mazzotti
2009, Hydrobiologia (635) 329-338
Feeding opportunities of American alligators (Alligator mississippiensis) in freshwater wetlands in south Florida are closely linked to hydrologic conditions. In the Everglades, seasonally and annually fluctuating surface water levels affect populations of aquatic organisms that alligators consume. Since prey becomes more concentrated when water depth decreases, we hypothesized an inverse...
Arsenic in the evolution of earth and extraterrestrial ecosystems
R.S. Oremland, C.W. Saltikov, Felisa Wolfe-Simon, J.F. Stolz
2009, Geomicrobiology Journal (26) 522-536
If you were asked to speculate about the form extra-terrestrial life on Mars might take, which geomicrobial phenomenon might you select as a model system, assuming that life on Mars would be ‘primitive’? Give your reasons.At the end of my senior year at Rensselaer Polytechnic Institute in 1968, I...
Hydrologic control of nitrogen removal, storage, and export in a mountain stream
R.O. Hall, M. A. Baker, C.D. Arp, B.J. Kocha
2009, Limnology and Oceanography (54) 2128-2142
Nutrient cycling and export in streams and rivers should vary with flow regime, yet most studies of stream nutrient transformation do not include hydrologic variability. We used a stable isotope tracer of nitrogen (15N) to measure nitrate (NO3−) uptake, storage, and export in a mountain stream, Spring Creek, Idaho, U.S.A....
Salinity tolerance and mycorrhizal responsiveness of native xeroriparian plants in semi-arid western USA
Vanessa B. Beauchamp, C. Walz, P.B. Shafroth
2009, Applied Soil Ecology (43) 175-184
Restoration of salt-affected soils is a global concern. In the western United States, restoration of salinized land, particularly in river valleys, often involves control of Tamarix, an introduced species with high salinity tolerance. Revegetation of hydrologically disconnected floodplains and terraces after Tamarix removal is often difficult because of limited knowledge...
Biodegradation of 17β-estradiol, estrone, and testosterone in stream sediments
P. M. Bradley, F. H. Chapelle, L. B. Barber, P.B. McMahon, J.L. Gray, D.W. Kolpin
2009, Conference Paper, In Situ and On-Site Bioremediation-2009: Proceedings of the 10th International In Situ and On-Site Bioremediation Symposium
The release of endocrine-disrupting chemicals (EDCs) in wastewater treatment plant (WWTP) effluent poses a significant threat to the ecology of surface water receptors, due to impacts on the hormonal control, sexual development, reproductive success and community structure of the indigenous aquatic organisms and associated wildlife. Among the EDCs commonly observed...
Relations between hydrology and velocity of a continuously moving landslide-evidence of pore-pressure feedback regulating landslide motion?
W.H. Schulz, J.P. McKenna, J.D. Kibler, G. Biavati
2009, Landslides (6) 181-190
We measured displacement, pore-water pressure, and climatic conditions for 3 years at the continuously moving Slumgullion landslide in Colorado, USA. The landslide accelerated when pore-water pressure increased within the landslide body, but this occurred as pore-water pressure decreased along the landslide margin. The decrease probably occurred in response to shear-induced...
Mercury and trace element contents of Donbas coals and associated mine water in the vicinity of Donetsk, Ukraine
A. Kolker, B.S. Panov, Y.B. Panov, E. R. Landa, K.M. Conko, V.A. Korchemagin, T. Shendrik, J.D. McCord
2009, International Journal of Coal Geology (79) 83-91
Mercury-rich coals in the Donets Basin (Donbas region) of Ukraine were sampled in active underground mines to assess the levels of potentially harmful elements and the potential for dispersion of metals through use of this coal. For 29 samples representing c11 to m3 Carboniferous coals, mercury contents range from 0.02...
In situ measurements of microbially-catalyzed nitrification and nitrate reduction rates in an ephemeral drainage channel receiving water from coalbed natural gas discharge, Powder River Basin, Wyoming, USA
S.H. Harris, R. L. Smith
2009, Chemical Geology (267) 77-84
Nitrification and nitrate reduction were examined in an ephemeral drainage channel receiving discharge from coalbed natural gas (CBNG) production wells in the Powder River Basin, Wyoming. CBNG co-produced water typically contains dissolved inorganic nitrogen (DIN), primarily as ammonium. In this study, a substantial...
Holocene climate on the Modoc Plateau, northern California, USA: The view from Medicine Lake
Scott W. Starratt
2009, Hydrobiologia (631) 197-211
Medicine Lake is a small (165 ha), relatively shallow (average 7.3 m), intermediate elevation (2,036 m) lake located within the summit caldera of Medicine Lake volcano, Siskiyou County, California, USA. Sediment cores and high-resolution bathymetric and seismic reflection data were collected from the lake during the fall of 1999 and 2000. Sediments were...
Processes affecting δ34S and δ18O values of dissolved sulfate in alluvium along the Canadian River, central Oklahoma, USA
Michele L. Tuttle, George N. Breit, Isabelle M. Cozzarelli
2009, Chemical Geology (265) 455-467
The δ34S and δ18O values for dissolved sulfate in groundwater are commonly used in aquifer studies to identify sulfate reservoirs and describe biogeochemical processes. The utility of these data, however, often is compromised by mixing of sulfate sources within reservoirs and isotope fractionation during sulfur redox cycling. Our study shows...
Gas chromatographic–mass spectrometric fragmentation study of phytoestrogens as their trimethylsilyl derivatives: Identification in soy milk and wastewater samples
Imma Ferrar, Larry B. Barber, E. Michael Thurman
2009, Journal of Chromatography A (1216) 6024-6032
An analytical method for the identification of eight plant phytoestrogens (biochanin A, coumestrol, daidzein, equol, formononetin, glycitein, genistein and prunetin) in soy products and wastewater samples was developed using gas chromatography coupled with ion trap mass spectrometry (GC/MS–MS). The phytoestrogens were derivatized as their trimethylsilyl ethers with trimethylchlorosilane (TMCS) and...
Arsenite and ferrous iron oxidation linked to chemolithotrophic denitrification for the immobilization of arsenic in anoxic environments
W. Sun, R. Sierra-Alvarez, L. Milner, R. Oremland, J.A. Field
2009, Environmental Science & Technology (43) 6585-6591
The objective of this study was to explore a bioremediation strategy based on injecting NO3− to support the anoxic oxidation of ferrous iron (Fe(II)) and arsenite (As(III)) in the subsurface as a means to immobilize As in the form of arsenate (As(V)) adsorbed onto biogenic ferric (Fe(III)) (hydr)oxides....
Application of iron and zinc isotopes to track the sources and mechanisms of metal loading in a mountain watershed
D.M. Borrok, R. B. Wanty, Ridley W. Ian, P. J. Lamothe, B. A. Kimball, P. L. Verplanck, R.L. Runkel
2009, Applied Geochemistry (24) 1270-1277
Here the hydrogeochemical constraints of a tracer dilution study are combined with Fe and Zn isotopic measurements to pinpoint metal loading sources and attenuation mechanisms in an alpine watershed impacted by acid mine drainage. In the tested mountain catchment, δ56Fe and δ66Zn isotopic signatures of filtered stream water samples varied by ∼3.5‰ and...