Investigation of thallium fluxes from subaerial volcanism-Implications for the present and past mass balance of thallium in the oceans
R.G.A. Baker, M. Rehkamper, T. K. Hinkley, S.G. Nielsen, J.P. Toutain
2009, Geochimica et Cosmochimica Acta (73) 6340-6359
A suite of 34 volcanic gas condensates and particulates from Kilauea (Hawaii), Mt. Etna and Vulcano (Italy), Mt. Merapi (Indonesia), White Island and Mt. Nguaruhoe (New Zealand) were analysed for both Tl isotope compositions and Tl/Pb ratios. When considered together with published Tl–Pb abundance data, the measurements provide globally representative...
Organic geochemistry of resins from modern Agathis australis and Eocene resins from New Zealand: Diagenetic and taxonomic implications
P.C. Lyons, Maria Mastalerz, W. H. Orem
2009, International Journal of Coal Geology (80) 51-62
A maturation series of resins and fossil resins from New Zealand, ranging in age from Modern to Eocene and ranging from uncoalified to high volatile C bituminous coal, were analyzed by elemental, pyrolysis-gas chromatography (Py-GC), Fourier Transform infrared (FTir), and solid-state 13C nuclear magnetic resonance (13C NMR) techniques. For comparison,...
Learning to wait: A laboratory investigation
Ryan Oprea, Daniel Friedman, Steven T. Anderson
2009, Review of Economic Studies (76) 1103-1124
Human subjects decide when to sink a fixed cost C to seize an irreversible investment opportunity whose value V is governed by Brownian motion. The optimal policy is to invest when V first crosses a threshold V* = (1 + w*) C, where the wait option premium w* depends on...
Nitrogen losses from dairy manure estimated through nitrogen mass balance and chemical markers
Alexander N. Hristov, S. Zaman, M. Vander Pol, P. Ndegwa, L. Campbell, S. Silva
2009, Journal of Environmental Quality (38) 2438-2448
Ammonia is an important air and water pollutant, but the spatial variation in its concentrations presents technical difficulties in accurate determination of ammonia emissions from animal feeding operations. The objectives of this study were to investigate the relationship between ammonia volatilization and ??15N of dairy manure and the feasibility of...
Fractionation of the platinum-group elments and Re during crystallization of basalt in Kilauea Iki Lava Lake, Hawaii
L. Pitcher, Rosalind Tuthill Helz, R.J. Walker, P. Piccoli
2009, Chemical Geology (260) 196-210
Kilauea Iki lava lake formed during the 1959 summit eruption of Kilauea Volcano, then crystallized and differentiated over a period of 35??years. It offers an opportunity to evaluate the fractionation behavior of trace elements in a uniquely well-documented basaltic system. A suite of 14 core samples recovered from 1967 to...
Effects of coal storage in air on physical and chemical properties of coal and on gas adsorption
Maria Mastalerz, W. Solano-Acosta, A. Schimmelmann, A. Drobniak
2009, International Journal of Coal Geology (79) 167-174
This paper investigates changes in the high-volatile bituminous Lower Block Coal Member from Indiana owing to moisture availability and oxidation in air at ambient pressure and temperature over storage time. Specifically, it investigates changes in chemistry, in surface area, and pore structure, as well as changes in methane and carbon...
Biogeochemistry at a wetland sediment-alluvial aquifer interface in a landfill leachate plume
M.M. Lorah, I.M. Cozzarelli, J.K. Böhlke
2009, Journal of Contaminant Hydrology (105) 99-117
The biogeochemistry at the interface between sediments in a seasonally ponded wetland (slough) and an alluvial aquifer contaminated with landfill leachate was investigated to evaluate factors that can effect natural attenuation of landfill leachate contaminants in areas of groundwater/surface-water interaction. The biogeochemistry at the wetland-alluvial aquifer interface differed greatly between...
Changes in optical properties, chemistry, and micropore and mesopore characteristics of bituminous coal at the contact with dikes in the Illinois Basin
Maria Mastalerz, A. Drobniak, A. Schimmelmann
2009, International Journal of Coal Geology (77) 310-319
Changes in high-volatile bituminous coal (Pennsylvanian) near contacts with two volcanic intrusions in Illinois were investigated with respect to optical properties, coal chemistry, and coal pore structure. Vitrinite reflectance (Ro) increases from 0.62% to 5.03% within a distance of 5.5??m from the larger dike, and from 0.63% to 3.71% within...
Volatile selenium flux from the great Salt Lake, Utah
X. Diaz, W.P. Johnson, W.A. Oliver, D. L. Naftz
2009, Environmental Science & Technology (43) 53-59
The removal mechanisms that govern Se concentrations in the Great Salt Lake are unknown despite this terminal lake being an avian habitat of hemispheric importance. However, the volatilization flux of Se from the Great Salt Lake has not been previously measured due to challenges of analysis in this hypersaline environment...
Analytical modeling of gravity changes and crustal deformation at volcanoes: The Long Valley caldera, California, case study
Maurizio Battaglia, D.P. Hill
2009, Tectonophysics (471) 45-57
Joint measurements of ground deformation and micro-gravity changes are an indispensable component for any volcano monitoring strategy. A number of analytical mathematical models are available in the literature that can be used to fit geodetic data and infer source location, depth and density. Bootstrap statistical methods allow estimations of the...
Mesoscale raised rim depressions (MRRDs) on Earth: A review of the characteristics, processes, and spatial distributions of analogs for Mars
D.M. Burr, B.C. Bruno, P.D. Lanagan, L.S. Glaze, W.L. Jaeger, R.J. Soare, Bun Tseung J.-M. Wan, J.A. Skinner Jr., S.M. Baloga
2009, Planetary and Space Science (57) 579-596
Fields of mesoscale raised rim depressions (MRRDs) of various origins are found on Earth and Mars. Examples include rootless cones, mud volcanoes, collapsed pingos, rimmed kettle holes, and basaltic ring structures. Correct identification of MRRDs on Mars is valuable because different MRRD types have different geologic and/or climatic implications and...
Improved constraints on the estimated size and volatile content of the Mount St. Helens magma system from the 2004-2008 history of dome growth and deformation
L.G. Mastin, M. Lisowski, E. Roeloffs, N. Beeler
2009, Geophysical Research Letters (36)
The history of dome growth and geodetic deflation during the 2004-2008 Mount St. Helens eruption can be fit to theoretical curves with parameters such as reservoir volume, bubble content, initial overpressure, and magma rheology, here assumed to be Newtonian viscous, with or without a solid plug in the conduit center....
Selenium mass balance in the Great Salt Lake, Utah
X. Diaz, W.P. Johnson, D. L. Naftz
2009, Science of the Total Environment (407) 2333-2341
A mass balance for Se in the south arm of the Great Salt Lake was developed for September 2006 to August 2007 of monitoring for Se loads and removal flows. The combined removal flows (sedimentation and volatilization) totaled to a geometric mean value of 2079??kg Se/yr, with the estimated low...
A mass balance mercury budget for a mine-dominated lake: Clear Lake, California
T.H. Suchanek, J. Cooke, K. Keller, S. Jorgensen, P.J. Richerson, Collin A. Eagles-Smith, E.J. Harner, D.P. Adam
2009, Water, Air, & Soil Pollution (196) 51-73
The Sulphur Bank Mercury Mine (SBMM), active intermittently from 1873–1957 and now a USEPA Superfund site, was previously estimated to have contributed at least 100 metric tons (105 kg) of mercury (Hg) into the Clear Lake aquatic ecosystem. We have confirmed this minimum estimate. To better quantify the contribution of the...
Halogen degassing during ascent and eruption of water-poor basaltic magma
M. Edmonds, T.M. Gerlach, Richard A. Herd
2009, Chemical Geology (263) 122-130
A study of volcanic gas composition and matrix glass volatile concentrations has allowed a model for halogen degassing to be formulated for K??lauea Volcano, Hawai'i. Volcanic gases emitted during 2004-2005 were characterised by a molar SO2/HCl of 10-64, with a mean of 33; and a molar HF/HCl of 0-5, with...
Did the Middlesboro, Kentucky, bolide impact event influence coal rank?
J.C. Hower, S.F. Greb, K.W. Kuehn, C.F. Eble
2009, International Journal of Coal Geology (79) 92-96
The Middlesboro Basin, southeastern Kentucky, occurs on the Cumberland Overthrust Sheet and includes a ca. 5.5-km diameter impact structure. The Lower and Middle Pennsylvanian coal-bearing strata are faulted, with some evidence for shock metamorphism. The event post-dated the latest-Pennsylvanian-early-Permian thrusting and was likely prior to late-Mesozoic entrenchment of drainages. The...
Martian mud volcanism: Terrestrial analogs and implications for formational scenarios
James A. Skinner, A. Mazzini
2009, Marine and Petroleum Geology (26) 1866-1878
The geology of Mars and the stratigraphic characteristics of its uppermost crust (mega-regolith) suggest that some of the pervasively-occurring pitted cones, mounds, and flows may have formed through processes akin to terrestrial mud volcanism. A comparison of terrestrial mud volcanism suggests that equivalent Martian processes likely required discrete sedimentary depocenters,...
Effects of megascale eruptions on Earth and Mars
T. Thordarson, M. Rampino, L. P. Keszthelyi, S. Self
2009, Special Paper of the Geological Society of America 37-53
Volcanic features are common on geologically active earthlike planets. Megascale or "super" eruptions involving >1000 Gt of magma have occurred on both Earth and Mars in the geologically recent past, introducing prodigious volumes of ash and volcanic gases into the atmosphere. Here we discuss felsic (explosive) and mafi c (flood...
Uplift and magma intrusion at Long Valley caldera from InSAR and gravity measurements
Pietro Tizzani, Maurizio Battaglia, Giovanni Zeni, Simone Atzori, Paolo Berardino, Riccardo Lanari
2009, Geology (37) 63-66
The Long Valley caldera (California) formed ~760,000 yr ago following the massive eruption of the Bishop Tuff. Postcaldera volcanism in the Long Valley volcanic field includes lava domes as young as 650 yr. The recent geological unrest is characterized by uplift of the resurgent dome in the central section of...
Geomorphic controls on mercury accumulation in soils from a historically mined watershed, Central California Coast Range, USA
J.M. Holloway, M. B. Goldhaber, J.M. Morrison
2009, Applied Geochemistry (24) 1538-1548
Historic Hg mining in the Cache Creek watershed in the Central California Coast Range has contributed to the downstream transport of Hg to the San Francisco Bay-Delta. Different aspects of Hg mobilization in soils, including pedogenesis, fluvial redistribution of sediment, volatilization and eolian transport were considered. The greatest soil concentrations...
Assigning land use to supply wells for the statistical characterization of regional groundwater quality: Correlating urban land use and VOC occurrence
T.D. Johnson, K. Belitz
2009, Journal of Hydrology (370) 100-108
Many national and regional groundwater studies have correlated land use "near" a well, often using a 500 m radius circle, with water quality. However, the use of a 500 m circle may seem counterintuitive given that contributing areas are expected to extend up-gradient from wells, and not be circular in...
Dike intrusions into bituminous coal, Illinois Basin: H, C, N, O isotopic responses to rapid and brief heating
A. Schimmelmann, Maria Mastalerz, L. Gao, P.E. Sauer, K. Topalov
2009, Geochimica et Cosmochimica Acta (73) 6264-6281
Unlike long-term heating in subsiding sedimentary basins, the near-instantaneous thermal maturation of sedimentary organic matter near magmatic intrusions is comparable to artificial thermal maturation in the laboratory in terms of short duration and limited extent. This study investigates chemical and H, C, N, O isotopic changes in high volatile bituminous...
Mobility of icy sand packs, with application to Martian permafrost
W.B. Durham, A.V. Pathare, L.A. Stern, H.J. Lenferink
2009, Geophysical Research Letters (36)
[1] The physical state of water on Mars has fundamental ramifications for both climatology and astrobiology. The widespread presence of "softened" Martian landforms (such as impact craters) can be attributed to viscous creep of subsurface ground ice. We present laboratory experiments designed to determine the minimum amount of ice necessary...
Pre-1991 sulfur transfer between mafic injections and dacite magma in the Mt. Pinatubo reservoir
Muro A. Di, John S. Pallister, B. Villemant, Chris Newhall, M. Semet, M. Martinez, C. Mariet
2008, Journal of Volcanology and Geothermal Research (175) 517-540
Before the 1991–1992 activity, a large andesite lava dome belonging to the penultimate Pinatubo eruptive period (Buag ∼ 500 BP) formed the volcano summit. Buag porphyritic andesite contains abundant amphibole-bearing microgranular enclaves of basaltic–andesite composition. Buag enclaves have lower K2O and incompatible trace element (LREE,...
The roles of fractional crystallization, magma mixing, crystal mush remobilization and volatile-melt interactions in the genesis of a young basalt-peralkaline rhyolite suite, the greater Olkaria volcanic complex, Kenya Rift valley
R. Macdonald, H. E. Belkin, J.G. Fitton, N.W. Rogers, K. Nejbert, A.G. Tindle, A.S. Marshall
2008, Journal of Petrology (49) 1515-1547
The Greater Olkaria Volcanic Complex is a young (???20 ka) multi-centred lava and dome field dominated by the eruption of peralkaline rhyolites. Basaltic and trachytic magmas have been erupted peripherally to the complex and also form, with mugearites and benmoreites, an extensive suite of magmatic inclusions in the rhyolites. The...