Atmospheric mercury speciation in Yellowstone National Park
B.D. Hall, M.L. Olson, A.P. Rutter, R.R. Frontiera, D. P. Krabbenhoft, D.S. Gross, M. Yuen, T.M. Rudolph, J.J. Schauer
2006, Science of the Total Environment (367) 354-366
Atmospheric concentrations of elemental mercury (Hg0), reactive gaseous Hg (RGM), and particulate Hg (pHg) concentrations were measured in Yellowstone National Park (YNP), U.S.A. using high resolution, real time atmospheric mercury analyzers (Tekran 2537A, 1130, and 1135). A survey of Hg0 concentrations at various locations within...
Steroid estrogens, nonylphenol ethoxylate metabolites, and other wastewater contaminants in groundwater affected by a residential septic system on Cape Cod, MA
C.H. Swartz, S. Reddy, M.J. Benotti, H. Yin, L. B. Barber, Bruce J. Brownawell, R.A. Rudel
2006, Environmental Science & Technology (40) 4894-4902
Septic systems serve approximately 25% of U.S. households and may be an important source of estrogenic and other organic wastewater contaminants (OWC) to groundwater. We monitored several estrogenic OWC, including nonylphenol (NP), nonylphenol mono- and diethoxycarboxylates (NP1EC and NP2EC), the steroid hormones 17β-estradiol (E2), estrone (E1) and...
Detection of water quality trends at high, median, and low flow in a Catskill Mountain stream, New York, through a new statistical method
Peter S. Murdoch, James B. Shanley
2006, Water Resources Research (42)
The effects of changes in acid deposition rates resulting from the Clean Air Act Amendments of 1990 should first appear in stream waters during rainstorms and snowmelt, when the surface of the watershed is most hydrologically connected to the stream. Early detection of improved stream water quality is possible if...
Investigation of mercury exchange between forest canopy vegetation and the atmosphere using a new dynamic chamber
J.A. Graydon, Louis, S.E. Lindberg, H. Hintelmann, D. P. Krabbenhoft
2006, Environmental Science & Technology (40) 4680-4688
This paper presents the design of a dynamic chamber system that allows full transmission of PAR and UV radiation and permits enclosed intact foliage to maintain normal physiological function while Hg(0) flux rates are quantified in the field. Black spruce and jack pine foliage both emitted and...
Effect of H2 and redox condition on biotic and abiotic MTBE transformation
P. M. Bradley, F. H. Chapelle, J. E. Landmeyer
2006, Ground Water Monitoring and Remediation (26) 74-81
Laboratory studies conducted with surface water sediment from a methyl tert-butyl ether (MTBE)-contaminated site in South Carolina demonstrated that, under methanogenic conditions, [U-14C] MTBE was transformed to 14C tert-butyl alcohol (TBA) with no measurable production of 14CO2. Production of TBA was not attributed to the activity of methanogenic microorganisms, however,...
Mountain hydrology of the western United States
Roger C. Bales, Noah P. Molotch, Thomas H. Painter, Michael D. Dettinger, Robert Rice, Jeff Dozier
2006, Water Resources Research (42)
Climate change and climate variability, population growth, and land use change drive the need for new hydrologic knowledge and understanding. In the mountainous West and other similar areas worldwide, three pressing hydrologic needs stand out: first, to better understand the processes controlling the partitioning of energy and water fluxes within...
Drainage effects on the transient, near-surface hydrologic response of a steep hillslope to rainfall: Implications for slope stability, Edmonds, Washington, USA
G. Biavati, J. W. Godt, J.P. McKenna
2006, Natural Hazards and Earth System Sciences (6) 343-355
Shallow landslides on steep (>25??) hillsides along Puget Sound have resulted in occasional loss of life and costly damage to property during intense or prolonged rainfall. As part of a larger project to assess landslide hazards in the Seattle area, the U.S. Geological Survey instrumented two coastal bluff sites in...
Potential effects of recurrent low oxygen conditions on the Illinois Cave amphipod
S.V. Panno, Keith C. Hackley, W.R. Kelly, H.-H. Hwang, F.M. Wilhelm, S.J. Taylor, B.J. Stiff
2006, Journal of Cave and Karst Studies (68) 55-63
The caves of Illinois' sinkhole plain are the sole habitat of the Illinois Cave amphipod (Gammarus acherondytes), a federally endangered species. The sinkhole plain is a hydrologically-connected sequence of karstified limestone that constitutes an extensive karst aquifer which serves as an important source of potable water for area residents. During...
Cokriging estimation of daily suspended sediment loads
Z. Li, Y.-K. Zhang, K. Schilling, M. Skopec
2006, Journal of Hydrology (327) 389-398
Daily suspended sediment loads (S) were estimated using cokriging (CK) of S with daily river discharge based on weekly, biweekly, or monthly sampled sediment data. They were also estimated with ordinary kriging (OK) and a rating curve method. The estimated daily loads were compared with the daily measured values over...
Adequacy of selected evapotranspiration approximations for hydrologic simulation
D. M. Sumner
2006, Journal of the American Water Resources Association (42) 699-711
Evapotranspiration (ET) approximations, usually based on computed potential ET (PET) and diverse PET-to-ET conceptualizations, are routinely used in hydrologic analyses. This study presents an approach to incorporate measured (actual) ET data, increasingly available using micrometeorological methods, to define the adequacy of ET approximations for hydrologic simulation. The approach is demonstrated...
Delineating a shallow fault zone and dipping bed rock strata using multichannal analysis of surface waves with a land streamer
J. Ivanov, R. D. Miller, P. Lacombe, C. D. Johnson, J.W. Lane Jr.
2006, Geophysics (71) A39-A42
The multichannel analysis of surface waves (MASW) seismic method was used to delineate a fault zone and gently dipping sedimentary bedrock at a site overlain by several meters of regolith. Seismic data were collected rapidly and inexpensively using a towed 30-channel land streamer and a rubberband-accelerated weight-drop seismic source. Data...
Modeling the probability of arsenic in groundwater in New England as a tool for exposure assessment
J. D. Ayotte, B. T. Nolan, J.R. Nuckols, K.P. Cantor, G.R. Robinson Jr., D. Baris, L. Hayes, M. Karagas, W. Bress, D.T. Silverman, J.H. Lubin
2006, Environmental Science & Technology (40) 3578-3585
We developed a process-based model to predict the probability of arsenic exceeding 5 ??g/L in drinking water wells in New England bedrock aquifers. The model is being used for exposure assessment in an epidemiologic study of bladder cancer. One important study hypothesis that may explain increased bladder cancer risk is...
The chemical quality of self-supplied domestic well water in the United States
Michael J. Focazio, D. Tipton, Stephanie Dunkle Shapiro, Linda H. Geiger
2006, Ground Water Monitoring and Remediation (26) 92-104
Existing water quality data collected from domestic wells were summarized to develop the first national‐scale retrospective of self‐supplied drinking water sources. The contaminants evaluated represent a range of inorganic and organic compounds, and although the data set was not originally designed to be a statistical representation...
Groundwater flow and velocity in a 500 ka pre-Illinoian till, eastern Iowa
K. E. Schilling, S. Tassier-Surine
2006, Environmental Geology (50) 1255-1264
Few hydrology studies have investigated glacial till older than Illinoian time (> 300,000 BP) despite these older tills overlying a large portion of North America. An 8- and 6-well monitoring well nest installed into a 31 m thick pre-Illinoian till sequence near Cedar Rapids, Iowa was characterized using traditional hydrologic...
A landscape-scale model of yellow-billed loon (Gavia adamsii) habitat preferences in northern alaska
Susan L. Earnst, Robert Platte, Laura Bond
2006, Hydrobiologia (567) 227-236
We modeled yellow-billed loon (Gavia adamsii) habitat preferences in a 23,500 km2 area of northern Alaska using intensive aerial surveys and landscape-scale habitat descriptors. Of the 757 lakes censused, yellow-billed loons occupied 15% and Pacific loons (G. pacifica) 42%. Lake area, depth, proportion of shoreline in aquatic vegetation,...
Can basin-scale recharge be estimated reasonably with water-balance models?
A.E. Faust, T.P.A. Ferre, M.G. Schaap, A.C. Hinnell, Gordon E. Brown Jr.
2006, Vadose Zone Journal (5) 850-855
We examine in-place recharge as an example of the complex, basin-scale hydrologic processes that are being represented with simplified numerical models. The rate and distribution of recharge depend on local meteorological conditions and hydrogeologic properties. The pattern of recharge is defined predominantly by the distribution of net precipitation (precipitation less...
Assimilation of snow covered area information into hydrologic and land-surface models
M.P. Clark, A.G. Slater, A.P. Barrett, L.E. Hay, G.J. McCabe, B. Rajagopalan, G.H. Leavesley
2006, Advances in Water Resources (29) 1209-1221
This paper describes a data assimilation method that uses observations of snow covered area (SCA) to update hydrologic model states in a mountainous catchment in Colorado. The assimilation method uses SCA information as part of an ensemble Kalman filter to alter the sub-basin distribution of snow as well as the...
Multiple injected and natural conservative tracers quantify mixing in a stream confluence affected by acid mine drainage near Silverton, Colorado
L. E. Schemel, M.H. Cox, R.L. Runkel, B. A. Kimball
2006, Hydrological Processes (20) 2727-2743
The acidic discharge from Cement Creek, containing elevated concentrations of dissolved metals and sulphate, mixed with the circumneutral-pH Animas River over a several hundred metre reach (mixing zone) near Silverton, CO, during this study. Differences in concentrations of Ca, Mg, Si, Sr, and SO42- between the creek and the river...
Recharge processes drive sulfate reduction in an alluvial aquifer contaminated with landfill leachate
M. A. Scholl, I.M. Cozzarelli, S. C. Christenson
2006, Journal of Contaminant Hydrology (86) 239-261
Natural attenuation of contaminants in groundwater depends on an adequate supply of electron acceptors to stimulate biodegradation. In an alluvial aquifer contaminated with leachate from an unlined municipal landfill, the mechanism of recharge infiltration was investigated as a source of electron acceptors. Water samples were collected monthly at closely spaced intervals...
Flow-specific trends in river-water quality resulting from the effects of the clean air act in three mesoscale, forested river basins in the northeastern United States through 2002
Peter S. Murdoch, J. B. Shanley
2006, Environmental Monitoring and Assessment (120) 1-25
Two new methods for assessing temporal trends in stream-solute concentrations at specific streamflow ranges were applied to long (40 to 50-year) but sparse (bi-weekly to quarterly sampling) stream-water quality data collected at three forested mesoscale basins along an atmospheric deposition gradient in the northeastern United States (one in north-central Pennsylvania,...
Multiphase, multicomponent parameter estimation for liquid and vapor fluxes in deep arid systems using hydrologic data and natural environmental tracers
Edward M. Kwicklis, Andrew V. Wolfsberg, Philip H. Stauffer, Michelle Ann Walvoord, Michael J. Sully
2006, Vadose Zone Journal (5) 934-950
Multiphase, multicomponent numerical models of long-term unsaturated-zone liquid and vapor movement were created for a thick alluvial basin at the Nevada Test Site to predict present-day liquid and vapor fluxes. The numerical models are based on recently developed conceptual models of unsaturated-zone moisture movement in thick alluvium that explain present-day...
Nitrogen sources and cycling in the San Francisco Bay estuary: A nitrate dual isotopic composition approach
Scott D. Wankel, C. Kendall, C.A. Francis, A. Paytan
2006, Limnology and Oceanography (51) 1654-1664
We used the dual isotopic composition of nitrate (δ15N and δ18O) within the estuarine system of San Francisco (SF) Bay, California, to explore the utility of this approach for tracing sources and cycling of nitrate (NO2−). Surface water samples from 49 sites within the estuary were sampled during July–August 2004....
Evaluating uncertainty in predicting spatially variable representative elementary scales in fractured aquifers, with application to Turkey Creek Basin, Colorado
Tristan P. Wellman, Eileen P. Poeter
2006, Water Resources Research (42)
Computational limitations and sparse field data often mandate use of continuum representation for modeling hydrologic processes in large‐scale fractured aquifers. Selecting appropriate element size is of primary importance because continuum approximation is not valid for all scales. The traditional approach is to select elements by identifying a single representative elementary...
Use of radars to monitor stream discharge by noncontact methods
J. E. Costa, R. T. Cheng, F.P. Haeni, N. Melcher, K.R. Spicer, E. Hayes, W. Plant, K. Hayes, C. Teague, D. Barrick
2006, Water Resources Research (42)
Conventional measurements of river flows are costly, time‐consuming, and frequently dangerous. This report evaluates the use of a continuous wave microwave radar, a monostatic UHF Doppler radar, a pulsed Doppler microwave radar, and a ground‐penetrating radar to measure river flows continuously over long periods and without touching the water with...
Pharmaceuticals and other organic chemicals in selected north-central and northwestern Arkansas streams
B. E. Haggard, J.M. Galloway, W. R. Green, M. T. Meyer
2006, Journal of Environmental Quality (35) 1078-1087
Recently, our attention has focused on the low level detection of many antibiotics, pharmaceuticals, and other organic chemicals in water resources. The limited studies available suggest that urban or rural streams receiving wastewater effluent are more susceptible to contamination. The purpose of this study was to evaluate the occurrence of...