Mercury in water and biomass of microbial communities in hot springs of Yellowstone National Park, USA
S.A. King, S. Behnke, K. Slack, D. P. Krabbenhoft, D. Kirk Nordstrom, M.D. Burr, Robert G. Striegl
2006, Applied Geochemistry (21) 1868-1879
Ultra-clean sampling methods and approaches typically used in pristine environments were applied to quantify concentrations of Hg species in water and microbial biomass from hot springs of Yellowstone National Park, features that are geologically enriched with Hg. Microbial populations of chemically-diverse hot springs were also characterized using modern methods in...
Alternate corrections for estimating actual wetland evapotranspiration from potential evapotranspiration
W. Barclay Shoemaker, D. M. Sumner
2006, Wetlands (26) 528-543
Corrections can be used to estimate actual wetland evapotranspiration (AET) from potential evapotranspiration (PET) as a means to define the hydrology of wetland areas. Many alternate parameterizations for correction coefficients for three PET equations are presented, covering a wide range of possible data-availability scenarios. At nine sites in the wetland...
Estimating recharge using relations between precipitation and yield in a mountainous area with large variability in precipitation
Janet M. Carter, D.G. Driscoll
2006, Journal of Hydrology (316) 71-83
Estimates of recharge to bedrock aquifers from infiltration of precipitation can be difficult to obtain, especially in areas with large spatial and temporal variability in precipitation. In the Black Hills area of western South Dakota and eastern Wyoming, streamflow yield is highly influenced by annual precipitation, with yield efficiency (annual...
Hyporheic exchange and fulvic acid redox reactions in an alpine stream/wetland ecosystem, Colorado front range
Matthew P. Miller, Diane M. McKnight, R.M. Cory, Mark W. Williams, Robert L. Runkel
2006, Environmental Science & Technology (40) 5943-5949
The influence of hyporheic zone interactions on the redox state of fulvic acids and other redox active species was investigated in an alpine stream and adjacent wetland, which is a more reducing environment. A tracer injection experiment using bromide (Br-) was conducted in the stream system. Simulations...
Trophic transfer of trace metals: Subcellular compartmentalization in a polychaete and assimilation by a decapod crustacean
P.S. Rainbow, L. Poirier, B. D. Smith, K.V. Brix, S. N. Luoma
2006, Marine Ecology Progress Series (308) 91-100
The chemical form of accumulated trace metal in prey is important in controlling the bioavailability of dietary metal to a predator. This study investigated the trophic transfer of radiolabelled Ag, Cd and Zn from the polychaete worm Nereis diversicolor to the decapod crustacean Palaemonetes varians. We used 2 populations of worms with different...
Accumulation of contaminants in fish from wastewater treatment wetlands
L. B. Barber, S.H. Keefe, Ronald C. Antweiler, Howard E. Taylor, R.D. Wass
2006, Environmental Science & Technology (40) 603-611
Increasing demands on water resources in arid environments make reclamation and reuse of municipal wastewater an important component of the water budget. Treatment wetlands can be an integral part of the water-reuse cycle providing both water-quality enhancement and habitat functions. When used for habitat, the bioaccumulation potential...
Modeling the influence of river rehabilitation scenarios on bed material sediment flux in a large river over decadal timescales
Michael B. Singer, Thomas Dunne
2006, Water Resources Research (42)
A stochastic flood generator and calibrated sediment transport formulae were used to assess the decadal impact of major river rehabilitation strategies on two fraction bed material sediment flux and net storage, first‐order indicators of aquatic riverine habitat, in a large river system. Model boundary conditions were modified to reflect the...
Location and timing of river-aquifer exchanges in six tributaries to the Columbia River in the Pacific Northwest of the United States
C.P. Konrad
2006, Journal of Hydrology (329) 444-470
The flow of water between rivers and contiguous aquifers influences the quantity and quality of water resources, particularly in regions where precipitation and runoff are unevenly distributed through the year, such as the Columbia Basin (CB) in northwestern United States. Investigations of basin hydrogeology and gains and losses of streamflow...
Use of borehole radar tomography to monitor steam injection in fractured limestone
C. Gregoire, P. K. Joesten
2006, Near Surface Geophysics (4) 355-365
Borehole radar tomography was used as part of a pilot study to monitor steam‐enhanced remediation of a fractured limestone contaminated with volatile organic compounds at the former Loring Air Force Base, Maine, USA. Radar tomography data were collected using 100‐MHz electric‐dipole antennae before and during steam injection to evaluate whether...
Relations between climatic variability and hydrologic time series from four alluvial basins across the southwestern United States
R. T. Hanson, M. D. Dettinger, M.W. Newhouse
2006, Hydrogeology Journal (14) 1122-1146
Hydrologic time series of groundwater levels, streamflow, precipitation, and tree-ring indices from four alluvial basins in the southwestern United States were spectrally analyzed, and then frequency components were reconstructed to isolate variability due to climatic variations on four time scales. Reconstructed components (RCs), from each time series, were compared to...
Assessment of factors limiting Klamath River fall Chinook salmon production potential using historical flows and temperatures
John M. Bartholow, James A. Henriksen
2006, Open-File Report 2006-1249
We parameterized and applied a deterministic salmon production model to infer the degree to which river flows and temperatures may limit freshwater production potential of the Klamath River in California. Specific parameter requirements, data sources, and significant assumptions are discussed in detail. Model simulations covered a wide variety of historical...
Modeling wetland plant community response to assess water-level regulation scenarios in the Lake Ontario-St. Lawrence River basin
Christiane Hudon, Douglas Wilcox, Joel Ingram
2006, Environmental Monitoring and Assessment (113) 303-328
The International Joint Commission has recently completed a five-year study (2000-2005) to review the operation of structures controlling the flows and levels of the Lake Ontario - St. Lawrence River system. In addition to addressing the multitude of stakeholder interests, the regulation plan review also considers environmental sustainability and integrity...
Users' manual for the Hydroecological Integrity Assessment Process software (including the New Jersey Assessment Tools)
James A. Henriksen, John Heasley, Jonathan G. Kennen, Steven Nieswand
2006, Open-File Report 2006-1093
This manual is a user’s guide to four computer software tools that have been developed for the Hydroecological Integrity Assessment Process. The Hydroecological Integrity Assessment Process recognizes that streamflow is strongly related to many critical physiochemical components of rivers, such as dissolved oxygen, channel geomorphology, and water temperature, and can...
Predicting crappie recruitment in Ohio reservoirs with spawning stock size, larval density, and chlorophyll concentrations
David B. Bunnell, R. Scott Hale, Michael J. Vanni, Roy A. Stein
2006, North American Journal of Fisheries Management (26) 1-12
Stock-recruit models typically use only spawning stock size as a predictor of recruitment to a fishery. In this paper, however, we used spawning stock size as well as larval density and key environmental variables to predict recruitment of white crappies Pomoxis annularis and black crappies P. nigromaculatus, a genus notorious...
Inverse modeling for seawater intrusion in coastal aquifers: Insights about parameter sensitivities, variances, correlations and estimation procedures derived from the Henry problem
E. Sanz, C.I. Voss
2006, Advances in Water Resources (29) 439-457
Inverse modeling studies employing data collected from the classic Henry seawater intrusion problem give insight into several important aspects of inverse modeling of seawater intrusion problems and effective measurement strategies for estimation of parameters for seawater intrusion. Despite the simplicity of the Henry problem, it embodies the behavior of a...
Ge/Si and 87Sr/86Sr tracers of weathering reactions and hydrologic pathways in a tropical granitoid system
L.A. Derry, J. C. Pett-Ridge, A.C. Kurtz, J.W. Troester
2006, Journal of Geochemical Exploration (88) 271-274
Ge/Si and 87Sr/86Sr data from primary and secondary minerals, soil waters, and stream waters in a tropical granitoid catchment quantitatively reflect mineral alteration reactions that occur at different levels within the bedrock-saprolite-soil zone. Near the bedrock-saprolite interface, plagioclase to kaolinite reaction yields low Ge/Si and 87Sr/86Sr. Higher in the regolith...
Low-temperature MTBE biodegradation in aquifer sediments with a history of low, seasonal ground water temperatures
P. M. Bradley, J. E. Landmeyer
2006, Ground Water Monitoring and Remediation (26) 101-105
Sediments from two shallow, methyl tert‐butyl ether (MTBE)–contaminated aquifers, with mean ground water temperatures ∼10°C, demonstrated significant mineralization of [U‐14C] MTBE to 14CO2 at incubation temperatures as low as 4°C. These results indicate that microbial degradation can continue to contribute to the attenuation of MTBE in ground water under...
Geologic, hydrologic, and geochemical interpretations of mineral deposits as analogs for understanding transport of environmental contaminants
R. B. Wanty, B. R. Berger
2006, Journal of Geochemical Exploration (88) 162-165
Base- and precious-metal mineral deposits comprise anomalous concentrations of metals and associated elements, which may be useful subjects for study as analogs for migration of environmental contaminants. In the geologic past, hydrothermal mineral deposits formed at the intersection of favorable geologic, hydrologic and geochemical gradients. In the present, weathering of...
Future trends in transport and fate of diffuse contaminants in catchments, with special emphasis on stable isotope applications
J. Turner, H.-J. Albrechtsen, M. Bonell, J.-P. Duguet, B. Harris, R. Meckenstock, K. McGuire, R. Moussa, N. Peters, H.H. Richnow, B. Sherwood-Lollar, S. Uhlenbrook, Lanen H. van
2006, Hydrological Processes (20) 205-213
A summary is provided of the first of a series of proposed Integrated Science Initiative workshops supported by the UNESCO International Hydrological Programme. The workshop brought together hydrologists, environmental chemists, microbiologists, stable isotope specialists and natural resource managers with the purpose of communicating new ideas on ways to assess microbial...
Controls on soil pore water solutes: An approach for distinguishing between biogenic and lithogenic processes
A. F. White, M. S. Schulz, D.V. Vivit, A.E. Blum, David A. Stonestrom
2006, Journal of Geochemical Exploration (88) 363-366
Spatial and temporal variations in pore water compositions are characterized for a deep regolith profile developed on a marine terrace chronosequence near Santa Cruz California. Variations are resolved in terms of the dominance of either a lithogenic process, i.e. chemical weathering, or a biogenic process, i.e. plant nutrient cycling. The concept of elemental fractionation is introduced describing...
Kinetics of sorption and abiotic oxidation of arsenic(III) by aquifer materials
A. Amirbahman, D.B. Kent, G.P. Curtis, J.A. Davis
2006, Geochimica et Cosmochimica Acta (70) 533-547
The fate of arsenic in groundwater depends largely on its interaction with mineral surfaces. We investigated the kinetics of As(III) oxidation by aquifer materials collected from the USGS research site at Cape Cod, MA, USA, by conducting laboratory experiments. Five different solid samples with similar specific surface areas (0.6–0.9 m2 g−1) and...
Denitrification potential in stream sediments impacted by acid mine drainage: Effects of pH, various electron donors, and iron
J.L. Baeseman, R. L. Smith, J. Silverstein
2006, Microbial Ecology (51) 232-241
Acid mine drainage (AMD) contaminates thousands of kilometers of stream in the western United States. At the same time, nitrogen loading to many mountain watersheds is increasing because of atmospheric deposition of nitrate and increased human use. Relatively little is known about nitrogen cycling in acidic, heavy-metal-laden streams; however,...
Enantiomeric separation of metolachlor and its metabolites using LC-MS and CZE
C. John Klein, R.J. Schneider, M. T. Meyer, D.S. Aga
2006, Chemosphere (62) 1591-1599
The stereoisomers of metolachlor and its two polar metabolites [ethane sulfonic acid (ESA) and oxanilic acid (OXA)] were separated using liquid chromatography–mass spectrometry (LC–MS) and capillary zone electrophoresis (CZE), respectively. The separation of metolachlor enantiomers was achieved using a LC–MS equipped with a...
Long-term natural attenuation of carbon and nitrogen within a groundwater plume after removal of the treated wastewater source
D.A. Repert, L. B. Barber, K.M. Hess, S.H. Keefe, D.B. Kent, D.R. LeBlanc, R. L. Smith
2006, Environmental Science & Technology (40) 1154-1162
Disposal of treated wastewater for more than 60 years onto infiltration beds on Cape Cod, Massachusetts produced a groundwater contaminant plume greater than 6 km long in a surficial sand and gravel aquifer. In December 1995 the wastewater disposal ceased. A long-term, continuous study was conducted to characterize the post-cessation...
Sulfates on Mars: A systematic Raman spectroscopic study of hydration states of magnesium sulfates
A. Wang, J.J. Freeman, B.L. Jolliff, I.-M. Chou
2006, Geochimica et Cosmochimica Acta (70) 6118-6135
The martian orbital and landed surface missions, OMEGA on Mar Express and the two Mars Explorations Rovers, respectively, have yielded evidence pointing to the presence of magnesium sulfates on the martian surface. In situ identification of the hydration states of magnesium sulfates, as well as the hydration states of other...