Response of North American Great Basin Lakes to Dansgaard-Oeschger oscillations
L. Benson, S. Lund, R. Negrini, B. Linsley, M. Zic
2003, Quaternary Science Reviews (22) 2239-2251
We correlate oscillations in the hydrologic and/or cryologic balances of four Great Basin surface-water systems with Dansgaard-Oeschger (D-O) events 2-12. This correlation is relatively strong at the location of the magnetic signature used to link the lake records, but becomes less well constrained with distance/time from the signature. Comparison of...
The collaborative historical African rainfall model: description and evaluation
Christopher C. Funk, Joel C. Michaelsen, James P. Verdin, Guleid A. Artan, Gregory Husak, Gabriel B. Senay, Hussein Gadain, Tamuka Magadazire
2003, International Journal of Climatology (23) 47-66
In Africa the variability of rainfall in space and time is high, and the general availability of historical gauge data is low. This makes many food security and hydrologic preparedness activities difficult. In order to help overcome this limitation, we have created the Collaborative Historical African Rainfall Model (CHARM)....
A new cation-exchange method for accurate field speciation of hexavalent chromium
J.W. Ball, R. Blaine McCleskey
2003, Talanta (61) 305-313
A new method for field speciation of Cr(VI) has been developed to meet present stringent regulatory standards and to overcome the limitations of existing methods. The method consists of passing a water sample through strong acid cation-exchange resin at the field site, where Cr(III) is retained while Cr(VI) passes into...
Characterizing aquatic health using salmonid mortality, physiology, and biomass estimates in streams with elevated concentrations of arsenic, cadmium, copper, lead, and zinc in the Boulder River Watershed, Montana
Aida M. Farag, Don Skaar, David A. Nimick, Elizabeth MacConnell, Christer Hogstrand
2003, Transactions of the American Fisheries Society (132) 450-467
Abandoned tailings and mine adits are located throughout the Boulder River watershed in Montana. In this watershed, all species of fish are absent from some tributary reaches near mine sources; however, populations of brook trout Salvelinus fontitalis, rainbow trout Oncorhynchus mykiss, and cut-throat trout O. clarki are found further downstream....
A reservoir of nitrate beneath desert soils
Michelle Ann Walvoord, Fred M. Phillips, David A. Stonestrom, R. Dave Evans, Peter C. Hartsough, Brent D. Newman, Robert G. Striegl
2003, Science (302) 1021-1024
A large reservoir of bioavailable nitrogen (up to ∼104 kilograms of nitrogen per hectare, as nitrate) has been previously overlooked in studies of global nitrogen distribution. The reservoir has been accumulating in subsoil zones of arid regions throughout the Holocene. Consideration of the subsoil reservoir raises estimates of vadose-zone nitrogen...
Inhibition of acetoclastic methanogenesis in crude oil- and creosote-contaminated groundwater
E. Warren, B.A. Bekins, E.M. Godsy, V. K. Smith
2003, Bioremediation Journal (7) 139-149
The inhibition of acetoclastic methanogenesis in crude oil- and creosote-contaminated groundwater was studied. The crude oil and water-soluble components of creosote contributed to the inhibition of acetoclastic methanogens. Acetoclastic methanogenesis was much more susceptible to the toxic inhibition of crude oil and creosote than either hydrogen- or formate-utilizing methanogenesis. The...
Nitrogen limitation of growth and nutrient dynamics in a disturbed mangrove forest, Indian River Lagoon, Florida
Ilka C. Feller, D.F. Whigham, K.L. McKee, C. E. Lovelock
2003, Oecologia (134) 405-414
The objectives of this study were to determine effects of nutrient enrichment on plant growth, nutrient dynamics, and photosynthesis in a disturbed mangrove forest in an abandoned mosquito impoundment in Florida. Impounding altered the hydrology and soil chemistry of the site. In 1997, we established a factorial experiment along a...
Baseflow and stormflow metal fluxes from two small agricultural catchments in the Coastal Plain of the Chesapeake Bay Basin, United States
C.V. Miller, G.D. Foster, B.F. Majedi
2003, Applied Geochemistry (18) 483-501
Annual yields (fluxes per unit area) of Al, Mn, Fe, Ni, Cd, Pb, Zn, Cu, Cr, Co, As and Se were estimated for two small non-tidal stream catchments on the Eastern Shore of the Chesapeake Bay, United States - a poorly drained dissected-upland watershed in the Nanticoke River Basin, and...
Applicability of tetrazolium salts for the measurement of respiratory activity and viability of groundwater bacteria
P.B. Hatzinger, P. Palmer, R. L. Smith, C.T. Penarrieta, T. Yoshinari
2003, Journal of Microbiological Methods (52) 47-58
A study was undertaken to measure aerobic respiration by indigenous bacteria in a sand and gravel aquifer on western Cape Cod, MA using tetrazolium salts and by direct oxygen consumption using gas chromatography (GC). In groundwater and aquifer slurries, the rate of aerobic respiration...
Modeling flow and transport in unsaturated fractured rock: An evaluation of the continuum approach
H.-H. Liu, C.B. Haukwa, C.F. Ahlers, G.S. Bodvarsson, A. L. Flint, W.B. Guertal
2003, Journal of Contaminant Hydrology (62-63) 173-188
Because the continuum approach is relatively simple and straightforward to implement, it has been commonly used in modeling flow and transport in unsaturated fractured rock. However, the usefulness of this approach can be questioned in terms of its adequacy for representing fingering flow and transport in unsaturated fractured rock. The...
Temperature-pressure conditions in coalbed methane reservoirs of the Black Warrior basin: Implications for carbon sequestration and enhanced coalbed methane recovery
J.C. Pashin, M.R. McIntyre
2003, International Journal of Coal Geology (54) 167-183
Sorption of gas onto coal is sensitive to pressure and temperature, and carbon dioxide can be a potentially volatile supercritical fluid in coalbed methane reservoirs. More than 5000 wells have been drilled in the coalbed methane fields of the Black Warrior basin in west-central Alabama, and the hydrologic and geothermic...
History and ecology of chloroethene biodegradation: A review
Paul M. Bradley
2003, Bioremediation Journal (7) 81-109
No abstract available....
Chemical analyses of pore water from boreholes USW SD-6 and USW WT-24, Yucca Mountain, Nevada
I.C. Yang, Z. E. Peterman, K.M. Scofield
2003, Journal of Contaminant Hydrology (62-63) 361-380
Analyses of pore water extracted from cores of boreholes USW SD-6 in the central part and USW WT-24 in the northern part of Yucca Mountain, Nevada, show significant vertical and lateral variations in dissolved-ion concentrations. Analyses of samples of only a few milliliters of pore water extracted by uniaxial or...
Effects of stormwater infiltration on quality of groundwater beneath retention and detention basins
D. Fischer, Emmanuel G. Charles, Arthur L. Baehr
2003, Journal of Environmental Engineering (129) 464-471
Infiltration of storm water through detention and retention basins may increase the risk of groundwater contamination, especially in areas where the soil is sandy and the water table shallow, and contaminants may not have a chance to degrade or sorb onto soil particles before reaching the saturated zone. Groundwater from...
Chlorine-36 in groundwater of the United States: Empirical data
S.N. Davis, S. Moysey, L.D. Cecil, M. Zreda
2003, Hydrogeology Journal (11) 217-227
Natural production of the radionuclide chlorine-36 (36Cl) has provided a valuable tracer for groundwater studies. The nuclear industry, especially the testing of thermonuclear weapons, has also produced large amounts of 36Cl that can be detected in many samples of groundwater. In order to be most useful in hydrologic studies, the natural production prior to 1952 should be distinguished from more recent artificial...
Mass spectrometric identification of an azobenzene derivative produced by smectite-catalyzed conversion of 3-amino-4-hydroxyphenylarsonic acid
Robert L. Wershaw, David W. Rutherford, Colleen E. Rostad, John R. Garbarino, I. Ferrer, K. R. Kennedy, G.-M. Momplaisir, A. Grange
2003, Talanta (59) 1219-1226
The compound 3-amino-4-hydroxyphenylarsonic acid (3-amino-HPAA) reacts with smectite to form a soluble azobenzene arsonic acid compound. This reaction is of particular interest because it provides a possible mechanism for the formation of a new type of arsenic compound in natural water systems. 3-Amino-HPAA is a degradation product excreted by chickens...
Time‐lapse imaging of saline‐tracer transport in fractured rock using difference‐attenuation radar tomography
Frederick D. Day-Lewis, John W. Lane Jr., Jerry M. Harris, Steven M. Gorelick
2003, Water Resources Research (39)
Accurate characterization of fractured‐rock aquifer heterogeneity remains one of the most challenging and important problems in groundwater hydrology. We demonstrate a promising strategy to identify preferential flow paths in fractured rock using a combination of geophysical monitoring and conventional hydrogeologic tests. Cross‐well difference‐attenuation ground‐penetrating radar was used to monitor saline‐tracer...
Comment on “Isotopic fractionation between Fe(III) and Fe(II) in aqueous solutions” by Clark Johnson et al., [Earth Planet. Sci. Lett. 195 (2002) 141–153]
Thomas D. Bullen, Arthur F. White, Cyril W. Childs
2003, Earth and Planetary Science Letters (206) 229-232
In a recent contribution [1], Johnson et al. reported the equilibrium isotope fractionation factor between dissolved Fe(II) and Fe(III) in aqueous solutions at pH=2.5 and 5.5. They suggest that because the iron isotope fractionation observed in their experiments spans virtually the entire range observed in...
Determination of antibiotic residues in manure, soil, and surface waters
T. Christian, R.J. Schneider, H.A. Farber, D. Skutlarek, M. T. Meyer, H.E. Goldbach
2003, Acta Hydrochimica et Hydrobiologica (31) 36-44
In the last years more and more often detections of antimicrobially active compounds (“antibiotics”) in surface waters have been reported. As a possible input pathway in most cases municipal sewage has been discussed. But as an input from the realm of agriculture is conceivable as well,...
The geochemical evolution of riparian ground water in a forested piedmont catchment
Douglas A. Burns, Niel Plummer, Jeffrey J. McDonnell, Eurybiades Busenberg, Gerolamo C. Casile, Carol Kendall, Richard P. Hooper, James E. Freer, Norman E. Peters, Keith Beven, Peter Schlosser
2003, Groundwater (41) 913-925
The principal weathering reactions and their rates in riparian ground water were determined at the Panola Mountain Research Watershed (PMRW) near Atlanta, Georgia. Concentrations of major solutes were measured in ground water samples from 19 shallow wells completed in the riparian (saprolite) aquifer and in one borehole completed in granite,...
Selenium in San Francisco Bay zooplankton: Potential effects of hydrodynamics and food web interactions
D.G. Purkerson, M.A. Doblin, S.M. Bollens, S. N. Luoma, G.A. Cutter
2003, Estuaries (26) 956-969
The potential toxicity of elevated selenium (Se) concentrations in aquatic ecosystems has stimulated efforts to measure Se concentrations in benthos, nekton, and waterfowl in San Francisco Bay (SF Bay). In September 1998, we initiated a 14 mo field study to determine the concentration of Se in SF Bay zooplankton, which...
Analysis of aquifer mineralization by paleodrainage channels
H. Rubin, R. W. Buddemeier
2003, Journal of Hydrology (277) 280-304
Mineralization of groundwater resources is a problem in south-central Kansas, due to the penetration of saline water from Permian bedrock formations into the overlying alluvial aquifer. One of the mechanisms involved in the mineralization involves small bedrock features of high permeability located in places occupied by streams and rivers in...
Temperature-profile methods for estimating percolation rates in arid environments
Jim Constantz, Scott W. Tyler, Edward Kwicklis
2003, Vadose Zone Journal (2) 12-24
Percolation rates are estimated using vertical temperature profiles from sequentially deeper vadose environments, progressing from sediments beneath stream channels, to expansive basin-fill materials, and finally to deep fractured bedrock underlying mountainous terrain. Beneath stream channels, vertical temperature profiles vary over time in response to downward heat transport, which is generally...
Mechanisms underlying export of N from high-elevation catchments during seasonal transitions
J.O. Sickman, A.L. Leydecker, Cecily C.Y. Chang, C. Kendall, J.M. Melack, D.M. Lucero, J. Schimel
2003, Biogeochemistry (64) 1-24
Mechanisms underlying catchment export of nitrogen (N) during seasonal transitions (i.e., winter to spring and summer to autumn) were investigated in high-elevation catchments of the Sierra Nevada using stable isotopes of nitrate and water, intensive monitoring of stream chemistry and detailed catchment N-budgets. We had four objectives: (1) determine the...
An approach to understanding hydrologic connectivity on the hillslope and the implications for nutrient transport
M. Stieglitz, J. Shaman, J. McNamara, V. Engel, J. Shanley, G.W. Kling
2003, Global Biogeochemical Cycles (17)
Hydrologic processes control much of the export of organic matter and nutrients from the land surface. It is the variability of these hydrologic processes that produces variable patterns of nutrient transport in both space and time. In this paper, we explore how hydrologic “connectivity” potentially affects nutrient transport. Hydrologic connectivity...