Reduction of uranium by Desulfovibrio desulfuricans
Derek R. Lovley, Elizabeth J.P. Phillips
1992, Applied and Environmental Microbiology (58) 850-856
The possibility that sulfate-reducing microorganisms contribute to U(VI) reduction in sedimentary environments was investigated. U(VI) was reduced to U(IV) when washed cells of sulfate-grown Desulfovibrio desulfuricans were suspended in a bicarbonate buffer with lactate or H2 as the electron donor. There was no U(VI) reduction in the absence of an...
Analytical interferences of mercuric chloride preservative in environmental water samples: Determination of organic compounds isolated by continuous liquid-liquid extraction or closed-loop stripping
W.T. Foreman, S.D. Zaugg, L.M. Falres, M.G. Werner, T.J. Leiker, P.F. Rogerson
1992, Environmental Science & Technology (26) 1307-1312
Analytical interferences were observed during the determination of organic compounds in groundwater samples preserved with mercuric chloride. The nature of the interference was different depending on the analytical isolation technique employed. (1) Water samples extracted with dichloromethane by continuous liquid-liquid extraction (CLLE) and analyzed by gas chromatography/mass spectrometry revealed a...
Comparison of methods for the removal of organic carbon and extraction of chromium, iron and manganese from an estuarine sediment standard and sediment from the Calcasieu River estuary, Louisiana, U.S.A.
N.S. Simon, S.A. Hatcher, C. Demas
1992, Chemical Geology (100) 175-189
U.S. National Bureau of Standards (NBS) estuarine sediment 1646 from the Chesapeake Bay, Maryland, and surface sediment collected at two sites in the Calcasieu River estuary, Louisiana, were used to evaluate the dilute hydrochloric acid extraction of Cr, Fe and Mn from air-dried and freeze-dried samples that had been treated...
Use of geochemical biomarkers in bottom sediment to track oil from a spill, San Francisco Bay, California
F. D. Hostettler, J. B. Rapp, K.A. Kvenvolden
1992, Marine Pollution Bulletin (24) 15-20
In April 1988, approximately 1500 m3 of a San Joaquin Valley crude oil were accidentally released from a Shell Oil Co. refinery near Martinez, Californa. The oil flowed into Carquinez Strait and Suisun Bay in northern San Francisco Bay Sediment and oil samples were collected within a week and analysed...
Seasonal dynamics of groundwater-lake interactions at Doñana National Park, Spain
Laura A. Sacks, Janet S. Herman, Leonard F. Konikow, Antonio L. Vela
1992, Journal of Hydrology (136) 123-154
The hydrologic and solute budgets of a lake can be strongly influenced by transient groundwater flow. Several shallow interdunal lakes in southwest Spain are in close hydraulic connection with the shallow ground water. Two permanent lakes and one intermittent lake have chloride concentrations that differ by almost an order of...
Gravel-bed deposition and erosion by bedform migration observed ultrasonically during storm flow, North Fork Toutle River, Washington
R.L. Dinehart
1992, Journal of Hydrology (136) 51-71
Ultrasonic depth sounding provides useful and unexpected information about peak discharge and sediment transport when applied during storm flow in channels with erodible beds. Streambed elevation was measured with dual ultrasonic depth sounders during the rise, crest, and recession of a storm flow in the North Fork Toutle River,...
Importance of methane-oxidizing bacteria in the methane budget as revealed by the use of a specific inhibitor
Ronald S. Oremland, Charles W. Culbertson
1992, Nature (356) 421-423
METHANE is a greenhouse gas whose concentration in the atmosphere is increasing. Much of this methane is derived from the metabolism of methane-generating (methanogenic) bacteria and over the past two decades much has been learned about the ecology of methanogens; specific inhibitors of methanogenesis, such as 2-bromoethanesulphonic acid, have proved useful...
Electromagnetic methods for mapping freshwater lenses on Micronesian atoll islands
S. S. Anthony
1992, Journal of Hydrology (137) 99-111
The overall shape of freshwater lenses can be determined by applying electromagnetic methods and inverse layered-earth modeling to the mapping of atoll island freshwater lenses. Conductivity profiles were run across the width of the inhabited islands at Mwoakilloa, Pingelap, and Sapwuahfik atolls of the Pohnpei State, Federated States...
Floodplain storage of mine tailings in the Belle Fourche river system: a sediment budget approach
D. C. Marron
1992, Earth Surface Processes and Landforms (17) 675-685
Arsenic‐contaminated mine tailings that were discharged into Whitewood Creek at Lead, South Dakota, from 1876 to 1978, were deposited along the floodplains of Whitewood Creek and the Belle Fourche River. The resulting arsenic‐contaminated floodplain deposit consists mostly of overbank sediments and filled abandoned meanders along White‐wood Creek, and overbank and...
Effects of uranium mining discharges on water quality in the Puerco River basin, Arizona and New Mexico
P. C. Van Metre, J. R. Gray
1992, Hydrological Sciences Journal (37) 463-480
From 1967 until 1986, uranium mine dewatering increased dissolved gross alpha, gross beta, uranium and radium activities and dissolved selenium and molybdenum concentrations in the Puerco River as indicated by time trends, areal patterns involving distance from the mines and stream discharge. Additionally, increased dissolved uranium concentrations were identified in...
Herbicide transport in rivers: Importance of hydrology and geochemistry in nonpoint-source contamination
P. J. Squillace, E.M. Thurman
1992, Environmental Science & Technology (26) 538-545
Alachlor, atrazine, cyanazine, metolachlor, and metribuzin were measured at six sites during 1984 and 1985 in large subbasins within the Cedar River, IA. A computer model separated the Cedar River discharge hydrograph into groundwater and overland-flow components. The concentration of herbicides in the river when groundwater was the...
Determination of subsurface fluid contents at a crude-oil spill site
K.M. Hess, W.N. Herkelrath, H.I. Essaid
1992, Journal of Contaminant Hydrology (10) 75-96
Measurement of the fluid-content distribution at sites contaminated by immiscible fluids, including crude oil, is needed to better understand the movement of these fluids in the subsurface and to provide data to calibrate and verify numerical models and geophysical methods. A laboratory...
Isolation of hydrophilic organic acids from water using nonionic macroporous resins
G. R. Aiken, Diane M. McKnight, K. A. Thorn, E.M. Thurman
1992, Organic Geochemistry (18) 567-573
A method has been developed for the isolation of hydrophilic organic acids from aquatic environments using Amberlite∗ XAD-4 resin. The method uses a two column array of XAD-8 and XAD-4 resins in series. The hydrophobic organic acids, composed primarily of...
Evaluation of methyl fluoride and dimethyl ether as inhibitors of aerobic methane oxidation
Ronald S. Oremland, Charles W. Culbertson
1992, Applied and Environmental Microbiology (58) 2983-2992
Methyl fluoride (MF) and dimethyl ether (DME) were effective inhibitors of aerobic methanotrophy in a variety of soils. MF and DME blocked consumption of CH4 as well as the oxidation of 14CH4 to 14CO2, but neither MF nor DME affected the oxidation of [14C]methanol or [14C]formate to 14CO2. Cooxidation of ethane and propane by methane-oxidizing...
Comparison of purge and trap GC/MS and purgeable organic chloride analysis for monitoring volatile chlorinated hydrocarbons
Larry B. Barber, E. Michael Thurman, Yoshi Takahashi, Mary C. Noriega
1992, Ground Water (30) 836-842
A combined field and laboratory study was conducted to compare purge and trap gas chromatography/mass spectrometry (PT‐GC/MS) and purgeable organic chloride (POC1) analysis for measuring volatile chlorinated hydro‐carbons (VCH) in ground water. Distilled‐water spike and recovery experiments using 10 VCH indicate that at concentrations greater than...
D4Z: A new renumbering for iterative solution of ground-water flow and solute-transport equations
K.L. Kipp, T.F. Russell, J.S. Otto
1992, Conference Paper, Finite Elements in Water Resources, Proceedings of the International Conference
D4 zig-zag (D4Z) is a new renumbering scheme for producing a reduced matrix to be solved by an incomplete LU preconditioned, restarted conjugate-gradient iterative solver. By renumbering alternate diagonals in a zig-zag fashion, a very low sensitivity of convergence rate to renumbering direction is obtained. For two demonstration problems involving...
Bioremediation of uranium contamination with enzymatic uranium reduction
Derek R. Lovley, Elizabeth J.P. Phillips
1992, Environmental Science & Technology (26) 2228-2234
Enzymatic uranium reduction by Desulfovibrio desulfuricans readily removed uranium from solution in a batch system or when D. desulfuricans was separated from the bulk of the uranium-containing water by a semipermeable membrane. Uranium reduction continued at concentrations as high as 24 mM. Of a variety of potentially inhibiting anions and...
Improved apparatus for measuring hydraulic conductivity at low water content
J. R. Nimmo, K.C. Akstin, K.A. Mello
1992, Soil Science Society of America Journal (56) 1758-1761
A modification of the steady-state centrifuge method (SSCM) for unsaturated hydraulic conductivity (K) measurement improves the range and adjustability of this method. The modified apparatus allows mechanical adjustments to vary the measured K by a factor of 360. In addition, the use of different flow-regulating ceramic materials can give a total K range covering...
Determination of selenium bioavailability to a benthic bivalve from particulate and solute pathways
S. N. Luoma, C. Johns, N.S. Fisher, N.A. Steinberg, R.S. Oremland, J.R. Reinfelder
1992, Environmental Science & Technology (26) 485-491
No abstract available. ...
Semiempirical model of soil water hysteresis
J. R. Nimmo
1992, Soil Science Society of America Journal (56) 1723-1730
In order to represent hysteretic soil water retention curves accurately using as few measurements as possible, a new semiempirical model has been developed. It has two postulates related to physical characteristics of the medium, and two parameters, each with a definite physical interpretation, whose values are determined empirically for a...
Solution of the advection-dispersion equation by a finite-volume eulerian-lagrangian local adjoint method
R. W. Healy, T.F. Russell
1992, Conference Paper, Finite Elements in Water Resources, Proceedings of the International Conference
A finite-volume Eulerian-Lagrangian local adjoint method for solution of the advection-dispersion equation is developed and discussed. The method is mass conservative and can solve advection-dominated ground-water solute-transport problems accurately and efficiently. An integrated finite-difference approach is used in the method. A key component of the method is that the integral...
Riparian vegetation recovery patterns following stream channelization: A geomorphic perspective
Cliff R. Hupp
1992, Ecology (73) 1209-1226
Hundreds of kilometres of West Tennessee streams have been channelized since the turn of the century. After a stream is straightened, dredged, or cleared, basinwide ecologic, hydrologic, and geomorphic processes bring about an integrated, characteristic recovery sequence. The rapid pace of channel responses to channelization provides an opportunity to document...
Enzymatic uranium precipitation
Y.A. Gorby, Derek R. Lovley
1992, Environmental Science & Technology (26) 205-207
No abstract available....
Laboratory investigations on the role of sediment surface and ground water chemistry in transport of bacteria through a contaminated Sandy Aquifer
M. A. Scholl, R.W. Harvey
1992, Environmental Science & Technology (26) 1410-1417
No abstract available. ...
A systematic approach to modelling the dynamic linkage of climate, physical catchment descriptors and hydrologic response components
A.J. Jakeman, G.M. Hornberger, I.G. Littlewood, P.G. Whitehead, J. W. Harvey, K.E. Bencala
1992, Mathematics and Computers in Simulation (33) 359-366
No abstract available....