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Uranium disequilibrium in groundwater: An isotope dilution approach in hydrologic investigations
J.K. Osmond, H.S. Rydell, M. I. Kaufman
1968, Science (162) 997-999
The distribution and environmental disequilibrium patterns of naturally occurring uranium isotopes (U234 and U238) in waters of the Floridan aquifer suggest that variations in the ratios of isotopic activity and concentrations can be used quantitatively to evaluate mixing proportions of waters from differing sources. Uranium is probably unique in its...
European cretaceous flints on the coast of North America
K.O. Emery, C. A. Kaye, D.H. Loring, D.J.G. Nota
1968, Science (160) 1225-1228
Flint pebbles and nodules from the Upper Cretaceous chalks of Europe occur offshore and at many seaports along the Atlantic coast of North America, where they were brought as ship's ballast. Isolated pieces imported from Europe as gunflints also are present....
Dissociation constants of KSO4- from 10°-50°C
A.H. Truesdell, P. B. Hostetler
1968, Geochimica et Cosmochimica Acta (32) 1019-1022
A cell without liquid junction was used to obtain dissociation constants for the reaction: KSO4− = K+ +SO42−. At 10°, 25°, 38° and 50°C, values for Kdiss KSO4− are, respectively, 0.195, 0.142, 0.117, and 0.095. At 25°C, , and <img class="imgLazyJSB inlineImage" title=""...
Variation of Nb-Ta, Zr-Hf, Th-U and K-Cs in two diabase-granophyre suites
D. Gottfried, L. P. Greenland, E.Y. Campbell
1968, Geochimica et Cosmochimica Acta (32) 925-947
Concentrations of Nb, Ta, Zr, Hf, Th, U and Cs have been determined in samples of igneous rocks representing the diabase-granophyre suites from Dillsburg, Pennsylvania, and Great Lake, Tasmania.Niobium and tantalum have a three to fourfold increase with differentiation in each of the suites. The chilled margin of the Great...
Mazama ash in the Northeastern Pacific
C.H. Nelson, L.D. Kulm, P.R. Carlson, J. R. Duncan
1968, Science (161) 47-49
Volcanic glass in marine sediments off Oregon and Washington correlates with continental deposits of Mount Mazama ash by stratigraphic position, refractive index, and radiocarbon dating. Ash deposited in the abyssal regions by turbidity currents is used for tracing of the dispersal routes of postglacial sediments and for evaluation of marine...
Nuclear magnetic resonance studies of the phosphorus(v) pesticides: A rapid determination of the isomer ratio of systox
H. Babad, T.N. Taylor, M. C. Goldberg
1968, Analytica Chimica Acta (40) 387-392
The integration circuit of the Varian A-60 nuclear magnetic resonance spectrometer is used in conjunction with vapor phase chromatography, to develop a rapid analysis technique for the determination of isomer ratios in technical Systox-Sulfotepp mixtures. The complete analysis requires less than 0.1 g of sample...
An investigation of the source of air Ar contamination in K-Ar dating
A. E. Mussett, G. Brent Dalrymple
1968, Earth and Planetary Science Letters (4) 422-426
Precision of young KAr ages is limited by air argon contamination. A series of experiments in which the exposure of basalt and sanidine samples to air argon was controlled, shows that most of the air contamination does not...
Lead isotopes and the origin of granulite and eclogite inclusions in deep-seated pipes
J.F. Lovering, M. Tatsumoto
1968, Earth and Planetary Science Letters (4) 350-356
The isotopic composition of lead and the concentrations of lead, uranium, and thorium in Delegate basic pipes from Australia and in South African kimberlite pipes have been determined. The observed238U/204Pb and observed232Th/238U of eclogite inclusions in the pipes range from 2.9 to 18.7 and from 3.5 to 5.9, respectively. This...
SrRbK and Sr isotopic relationships in ultramafic rocks, southeastern Alaska
M. A. Lanphere
1968, Earth and Planetary Science Letters (4) 185-190
Geologic evidence suggests that a series of ultramafic complexes of the ‘Duke Island type’ located along a 560 km-long belt in southeastern Alaska crystallized from magmas of ultramafic composition. Some geologists have proposed that these magmas were derived by fractional fusion of...
Spectrographic date on cores from the Pacific Ocean and the Gulf of Mexico
E. J. Young
1968, Geochimica et Cosmochimica Acta (32) 466-471
Average quantitative spectrographic data are presented for V, Ti, Zr, Ni, Co, Sc, Cr and La in the following Pacific deep-sea cores: siliceous ooze (3), red clay (6), volcanic mud (3), calcareous ooze (3) and one manganese nodule, and in 23 near-shore cores,...
The relationship of geophysical measurements to engineering and construction parameters in the Straight Creek Tunnel pilot bore, Colorado
J. H. Scott, F. T. Lee, R. D. Carroll, C. S. Robinson
1968, International Journal of Rock Mechanics and Mining Sciences & Geomechanics Abstracts (5) 1-30
Seismic-refraction and electrical-resistivity measurements made along the walls of the Straight Creek Tunnel pilot bore indicate that both a low-velocity and a high-resistivity layer exist in the disturbed rock surrounding the excavation. Seismic measurements were analyzed to obtain the thickness and seismic velocity...
Paleomagnetism and the compositions of highly-oxidised iron-titanium oxides in basalts
P.J. Smith
1968, Physics of the Earth and Planetary Interiors (1) 88-92
As a preliminary step towards determination of the source of the natural remanence in highly-oxidised basalt lava flows, electron probe microanalysis has been carried out on the two main phases in each of two types of highly-oxidised iron-titanium oxide. The discovery of the source of NRM in these basalts is...
Surface area of montmorillonite from the dynamic sorption of nitrogen and carbon dioxide
Josephus Thomas Jr., Bruce F. Bohor
1968, Clays and Clay Minerals (16) 83-91
Surface area determinations were made on a montmorillonite with various cations emplaced on the exchangeable sites, utilizing nitrogen and carbon dioxide as adsorbates at 77°K and 195°K, respectively, in a dynamic system. From the fraction of a Mississippi montmorillonite less than about 1 μ in size, samples were prepared by replacing...
Nuclear magnetic resonance studies of phosphorus(v) pesticides. Part I. Chemical shifts of protons as a means of identification of pesticides
H. Babad, W. Herbert, M. C. Goldberg
1968, Analytica Chimica Acta (41) 259-268
Correlations of structural and proton chemical-hift data for 40 commercial phosphorus(V) pesticides are reported. Correlations of structure with the phosphorus coupling constants are discussed, and general trends are noted which aid in the use of NMR as a tool for identification and analysis of phosphorus(V)...
Spreading of the ocean floor: Undeformed sediments in the peru-chile trench
D.W. Scholl, Roland E. von Huene, J.B. Ridlon
1968, Science (159) 869-871
None of the expected stratigraphic and structural effects of a spreading sea floor have been imposed on the sedimentary fill of the Peru-Chile Trench. During at least the last several million years, and perhaps during much of the Cenozoic, the trench has not been affected by an oceanic crust thrusting...
Studies in the system MgO-SiO2-CO2-H2O(I): The activity-product constant of chrysotile
P. B. Hostetler, C. L. Christ
1968, Geochimica et Cosmochimica Acta (32) 485-497
Chrysotile dissolves congruently in water according to the reaction: Mg3Si2O6(OH)4c + 5H2Ol = 3Mgaq2+ + 6OHaq− + 2H4SiO4aq. Experimental determination of the activity-product constant of chrysotile, Kchr = [Mg2+]3[OH−]6[H4SiO4aq]2, at 90°C, yields the value of Kchr = 10−49.2 ± 100.5. A synthetic sample and a natural sample from New Idria, California, were used in the determination.Values of Kchr were calculated for temperatures...
Structural charge site influence on the interlayer hydration of expandable three-sheet clay minerals
Raymond L. Kerns Jr., Charles J. Mankin
1968, Clays and Clay Minerals (16) 73-81
Previous investigations have demonstrated the influences of interlayer cation composition, relative humidity, temperature, and magnitude of interlayer surface charge on the interlayer hydration of montmorillonites and vermiculites. It has been suggested that the sites of layer charge deficiencies may also have an influence upon the amount of hydration that can...
Diatremes with kimberlitic affinities in North-Central Montana
B. C. Hearn Jr.
1968, Science (159) 622-625
Diatremes in the Missouri River Breaks demonstrate systematic subsidence-ring structure, contain inclusions derived from far above and far below, and have been produced by gas-rich eruptions of alkalic ultramafic magmas. Similar magmas have produced diatremes in many localities in the world and are known to be closely associated with and...
Infectious pancreatic necrosis: Selection of virus-free stock from a population of carrier trout
K. Wolf, M. C. Quimby, C. P. Carlson, G. L. Bullock
1968, Journal of the Fisheries Research Board of Canada (25) 383-391
Infectious pancreatic necrosis (IPN) is a virulent disease of young trouts and is easily transmitted from infected animals through water and with eggs. At present, the most effective control measure consists of propagation of specific pathogen-free stock. Methods are described for using fish cell cultures to detect IPN virus in...