Review of Trace Element Blank and Replicate Data Collected in Ground and Surface Water for the National Water-Quality Assessment Program, 1991–2002
By Lori E. Apodaca1, David K. Mueller2 and Michael T. Koterba3
Scientific Investigations Report 2006-5093, published 2006.
Table 7
Estimated sample variability and confidence intervals around U.S. Environmental Protection Agency drinking-water standards for select trace elements in ground water and surface water.
[pCi/L, picocuries per liter; RSD, relative standard deviation; USEPA, U.S. Environmental Protection Agency; µg/L, microgram per liter; —, no data]
AnalytesUSEPA drinking-water standard¹ (µg/L or pCi/L)Estimated sample variability (percent, µg/L or pCi/L)95-percent confidence interval for concentrations at the USEPA drinking-water standards (µg/L)
    Individual measurementsMean of 10 measurements 
  Ground waterSurface WaterGround waterSurface waterGround waterSurface water
Aluminum2350–20011.81.02 µg/L38.4–61.648.0–52.046.3–53.749.4–50.6
Antimony469.424.89–7.115.65–6.35
Arsenic4107.624.678.51–11.59.08–10.99.53–10.59.71–10.3
Barium42,0002.021.381,920–2,0801,950–2,0501,980–2,0301,980–2,020
Beryllium44
Boron256003.501.40559–641584–616587–613595–605
Cadmium4513.11.563.72–6.284.85–5.154.59–5.414.95–5.05
Chromium241009.6081.2–11999.1–106
Cobalt2
Copper261,30010.313.11,040–1,560966–1,6301,220–1,3801,190–1,410
Iron2²33002.625.53285–315267–333295–305290–310
Lead61512.511.3–18.713.8–16.2
Lithium
Manganese253003.280.58 µg/L281–319299–301294–306300
Molybdenum5403.511.7637.3–42.838.6–41.439.1–40.939.6–40.4
Nickel21000.08 µg/L8.1799.8–10084.0–11610095.0–105
Radon4300 pCi/L19.9 pCi/L261–449288–412
Radon74,000 pCi/L4.133,680–4,3203,900–4,100
Selenium45010.310.239.9–60.140.0–60.046.8–53.246.8–53.2
Silver5100
Strontium54,0002.351.204,820–4,1804,910–4,0903,940–4,0603,970–4,030
Thallium42
Uranium24300.981.5129.4–30.629.1–30.929.8–30.229.7–30.3
Vanadium2
Zinc52,00011.818.61,550–2,4501,270–2,7301,860–2,1401,770–2,230
1U.S. Environmental Protection Agency, 2004. 2See table 4 or 5 for variability of both low and high concentrations. For comparison with USEPA drinking-water standards the mean relative standard deviation (RSD) was used with the exceptions of nickel (Ni) and radon (Rn) in ground water and aluminum (Al) and manganese (Mn) in surface water where the standard deviation (SD) was used. 3Secondary Drinking Water Regulation (SDWR): is a non-enforceable Federal guideline to address cosmetic or aesthetic effects of drinking water. 4Maximum Contaminant Level (MCL): the highest level of contaminant that is allowed in drinking water. 5Health Advisory (HA): is an acceptable drinking-water level for a chemical substance that is based on health effects information. HAs are not legally enforceable, but is a standard that serves as a guidance to assist Federal, state, and local officials. 6Action Level (AL): concentration of a contaminant that triggers treatment or other requirements that a water system must follow. For lead and copper, the action level is the level where 10 percent of the homes tested exceed the standard. 7Alternative Maximum Contaminant Level (AMCL): Used for those states that create Multimedia Mitigation programs to address radon in indoor air.