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Scientific Investigations Report 2009–5073

Geochemical Investigation of Source Water to Cave Springs, Great Basin National Park, White Pine County, Nevada

Table 5. Stable isotopes of hydrogen, oxygen, carbon, and strontium in water collected from Cave Springs, a permanent pool in Lehman Caves, and two nearby springs at Great Basin National Park, Nevada.

[Site locations are shown in figure 2. Analyses were done by laboratories listed in table 2. Sample dates and times for sites 1–4 are listed in tables 3 and 4. Cave Springs prior to reconstruction of water-collection system: Analyses of Cave Springs water prior to reconstruction of water-collection system in 1996 are from Acheampong (1992). Average of 15 analyses from samples collected between August 15, 1990, and September 15, 1991. Environmental Isotope Laboratory of the Water Resources Center at the Desert Research Institute in Las Vegas, Nevada, did the analysis. Symbol: –, not determined]

Stable isotope Site 1
Cave Springs
Site 2
Pool in Lehman Caves
Site 3
Spring near upper Lehman Creek campground
Site 4 
Marmot Spring Cave Springs prior to reconstruction of water system
Hydrogen-2/hydrogen-1 (2H/1H) as δD 
in permil1 -115 -94.2 -106 -113 -116
Oxygen-18/oxygen-16 (18O/16O) as δ18O 
in permil1 -15.5 -12.2 -14.7 -15.4 -15.7
Carbon-13/carbon-12 (13C/12C) as δ13C 
in permil2 -14.0 -10.0 -16.0 -15.0
Strontium-87/strontium-86 (87Sr/86Sr)3 0.71713 0.71121 0.71813 0.71271

1 Ratios reported in delta (δ) notation as parts per thousand (permil). Delta is the relative difference between the ratios of hydrogen-2 or deuterium to hydrogen-1 (2H/1H) or oxygen-18 to oxygen-16 (18O/16O) in water samples to the respective ratios in Vienna Standard Mean Ocean Water (VSMOW; Giofiantini, 1978). A negative value represents water with less 2H relative to 1H or 18O relative to 16O than VSMOW. Standard error at 95-percent confidence level is 2 permil for δD and 0.2 permil for δ18O.

2 Ratios reported in delta (δ) notation as parts per thousand (permil). Delta is the relative difference between the ratios of carbon-13 to carbon-12 (13C/12C) in water samples to that in a sample of belemnite from the Pee Dee Formation of South Carolina (PDB; Craig, 1957). A negative value represents a sample with less 13C relative to 12C than in the standard sample of PDB. Standard error at 95-percent confidence level is 0.5 permil.

3 Ratios are based on repetitive analyses on the seawater standard, EN-1. The error on the ratio of strontium-87 to strontium-86 (87Sr/86Sr) is ± 0.00005 at the 95-percent confidence level.

For additional information contact:
Director, Nevada Water Science Center
U.S. Geological Survey
2730 N. Deer Run Road
Carson City, Nevada 89701
http://nevada.usgs.gov/water/

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