Neutron powder diffraction studies as a function of temperature of structure II hydrate formed from propane
Canadian Journal of Physics
By: C.J. Rawn, A.J. Rondinone, B.C. Chakoumakos, S. Circone, L.A. Stern, S. H. Kirby, and Y. Ishii
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Abstract
Neutron powder diffraction data confirm that hydrate samples synthesized with propane crystallize as structure type II hydrate. The structure has been modeled using rigid-body constraints to describe C3H8 molecules located in the eight larger polyhedral cavities of a deuterated host lattice. Data were collected at 12, 40, 100, 130, 160, 190, 220, and 250 K and used to calculate the thermal expansivity from the temperature dependence of the lattice parameters. The data collected allowed for full structural refinement of atomic coordinates and the atomic-displacement parameters.
Suggested Citation
Rawn, C., Rondinone, A., Chakoumakos, B., Circone, S., Stern, L., Kirby, S.H., Ishii, Y., 2003, Neutron powder diffraction studies as a function of temperature of structure II hydrate formed from propane: Canadian Journal of Physics, v. 81, no. 1-2, p. 431-438, https://doi.org/10.1139/p03-022.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Neutron powder diffraction studies as a function of temperature of structure II hydrate formed from propane |
| Series title | Canadian Journal of Physics |
| DOI | 10.1139/p03-022 |
| Volume | 81 |
| Issue | 1-2 |
| Year Published | 2003 |
| Language | English |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Canadian Journal of Physics |
| First page | 431 |
| Last page | 438 |