Streamflow, Water Quality, and Constituent Loads and Yields, Scituate Reservoir Drainage Area, Rhode Island, Water Year 2021

Data Report 1203
Prepared in cooperation with Providence Water
By:  and 

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Abstract

As part of a long-term cooperative program to monitor water quality within the Scituate Reservoir drainage area, the U.S. Geological Survey in cooperation with Providence Water (formerly Providence Water Supply Board) collected streamflow and water-quality data in tributaries to the Scituate Reservoir, Rhode Island. Streamflow and concentrations of chloride and sodium estimated from records of specific conductance for 16 tributaries were used to calculate loads of chloride and sodium during water year 2021 (October 1, 2020, through September 30, 2021). Water-quality samples were collected by Providence Water at 36 sampling stations on tributaries to the Scituate Reservoir during water year 2021. These water-quality data are summarized by using values of central tendency and are used, in combination with measured (or estimated) streamflows, to calculate loads and yields of selected water-quality constituents for water year 2021.

Annual mean streamflows for monitoring stations in this study ranged from 0.37 to 32.4 cubic feet per second during water year 2021. At the 16 continuous-record streamgages, tributaries transported about 2,900 metric tons (t) of chloride and 1,800 t of sodium to the Scituate Reservoir; annual chloride yields for the tributaries ranged from 15 to 110 metric tons per square mile (t/mi2), and annual sodium yields ranged from 10 to 68 t/mi2. At the stations where water-quality samples were collected by Providence Water, the medians of the median daily loads were 180 kilograms per day for chloride, 12 grams per day as nitrogen for nitrite, less than 700 grams per day as nitrogen for nitrate, 410 grams per day as orthophosphate for phosphate, 71,000 million colony forming units per day for coliform bacteria, and less than 2,000 million colony forming units per day for Escherichia coli. The medians of the median yields were 67 kilograms per day per square mile for chloride, 4.2 grams per day per square mile as nitrogen for nitrite, 400 grams per day per square mile as nitrogen for nitrate, 180 grams per day per square mile as orthophosphate as phosphate, 46,000 million colony forming units per day per square mile for coliform bacteria, and 1,000 million colony forming units per day per square mile for Escherichia coli.

Plain Language Summary

The U.S. Geological Survey, in cooperation with Providence Water (formerly Providence Water Supply Board), conducted a long-term program to monitor water quality in the Scituate Reservoir drainage area in Rhode Island to collect streamflow and water-quality data from 16 tributaries to the reservoir during the water year 2021. These data were used to estimate loads of chloride and sodium. Additionally, water-quality samples were collected at 36 sampling stations on the tributaries, and the data were summarized using central tendency values.

  • Annual mean streamflows for monitoring stations ranged from 0.37 to 32.4 cubic feet per second.

  • Tributaries transported about 2,900 metric tons of chloride and 1,800 metric tons of sodium to the reservoir.

  • Annual yields ranged from 15 to 110 metric tons per square mile for chloride and 10 to 68 metric tons per square mile for sodium.

  • The medians of the median daily loads were 180 kilograms per day for chloride, 12 grams per day as nitrogen for nitrite, less than 700 grams per day as nitrogen for nitrate, 410 grams per day as orthophosphate for phosphate, 71,000 million colony forming units per day for coliform bacteria, and less than 2,000 million colony forming units per day for Escherichia coli.

  • The medians of the median yields were 67 kilograms per day per square mile for chloride, 4.2 grams per day per square mile as nitrogen for nitrite, 400 grams per day per square mile as nitrogen for nitrate, 180 grams per day per square mile as orthophosphate for phosphate, 46,000 million colony forming units per day per square mile for coliform bacteria, and 1,000 million colony forming units per day per square mile for Escherichia coli.

Introduction

The Scituate Reservoir is the primary source of drinking water for more than 60 percent of the population of Rhode Island. The Scituate Reservoir drainage area consists of six subbasins and covers an area of about 94 square miles (mi2) in parts of the towns of Cranston, Foster, Glocester, Johnston, and Scituate, R.I. (fig. 1). The six subbasins are referred to in this report as the Barden Reservoir, “Direct Runoff,”, Moswansicut Pond reservoir, Ponaganset Reservoir, “Regulating reservoir,”, and Westconnaug Reservoir subbasins [“informal” names are used for subbasins that do not have official names]. Information about the water quality of the reservoir and its tributaries is important for management of the water supply and for the protection of human health. Providence Water (PW; formerly the Providence Water Supply Board) is the agency responsible for the management and distribution of the Scituate Reservoir water supply and has been monitoring and assessing water quality in the reservoir and reservoir drainage area for more than 60 years.

6 reservoir subbasins and an unsampled area draining directly to Scituate Reservoir;
                     northwestern Rhode Island
Figure 1.

Map showing locations of tributary-reservoir subbasins and stations in the Scituate Reservoir drainage area, Rhode Island, in water year 2021 (October 1, 2020, through September 30, 2021). Modified from Breault (2009). Data are from Smith and Spaetzel (2021).

Since 1993, the U.S. Geological Survey (USGS) has been cooperating with PW and the Rhode Island Department of Environmental Management to measure streamflow in tributaries to the Scituate Reservoir. Streamflow has been continuously measured at 10 streamgages in the drainage area (table 1) since 2009 by the USGS. Streamflow also was continuously measured at four streamgages from 2009 to 2014 and periodically measured at nine additional streamgages on tributaries in the drainage area. In October 2020, three streamgages began or resumed collection of continuous streamflow data (table 1). At 11 streamgages, daily mean streamflow was estimated for the period between October 1, 2020, and September 30, 2021, by using methods developed by the USGS (table 1; Hirsch, 1982). The USGS also has been continuously measuring specific conductance at 14 monitoring stations since 2009 and at 2 additional monitoring stations since 2020 (table 1). Equations that relate specific conductance to concentrations of chloride and sodium in stream water were developed as part of previous cooperative studies of the USGS and PW (Nimiroski and Waldron, 2002; Smith, 2015b, 2018a, 2022a, 2024; Spaetzel and Smith, 2022b). These equations, used together with measured (or estimated) streamflows, allow for nearly continuous estimation of chloride and sodium loads to the reservoir.

Table 1.    

Providence Water water-quality sampling stations and corresponding U.S. Geological Survey streamgages, in the Scituate Reservoir drainage area, Rhode Island, and data collection and monitoring statistics from October 1, 2020, to September 30, 2021.

[Data are from U.S. Geological Survey (2023). Alternate station names given in parenthesis for stations where different historical names were used for the same sampling location by Providence Water (PW). Locations of stations are shown on figure 1. USGS, U.S. Geological Survey; mi2, square mile; WQ, water quality; Cl, chloride; Na, sodium; M, monthly; Q, quarterly; Y, yes; N, no; --, not applicable]

PW station number USGS station number USGS station short name Alternate name Drainage area (mi2) Frequency of WQ sample collection by PW Number of samples collected by PW1 Daily estimated Na and Cl loads Streamflow data availability Specific conductance data availability
24 01115190 Dolly Cole Brook 4.9 M 11 Y Continuous Continuous
25 01115200 Shippee Brook 2.37 Q 4 N Estimated None
26 01115185 Winsor Brook 4.33 Q 4 Y Continuous2 Continuous2
27 011151845 Unnamed tributary to Ponaganset River Unnamed brook B; unnamed brook west of Winsor Brook 0.10 Q 3 N None None
28 01115265 Barden Reservoir Hemlock Brook 8.72 M 12 Y Continuous Continuous
29 01115271 Ponaganset River Barden Stream 33.0 M 11 N None None
35 01115187 Ponaganset River 14.0 M 11 Y Continuous Continuous
1 01115180 Brandy Brook 1.57 M 11 N Estimated None
2 01115181 Unnamed tributary 2 to Scituate Reservoir Unnamed brook north of Bullhead Brook 0.22 Q 2 N None None
3 01115280 Cork Brook 1.87 M 10 Y Continuous Continuous
4 01115400 Kent Brook Betty Pond Stream 0.85 M 11 N Estimated None
5 01115184 Spruce Brook 1.26 Q 3 Y Continuous2 Continuous
6 01115183 Quonopaug Brook 1.96 M 10 Y Continuous Continuous
7 01115297 Wilbur Hollow Brook 4.33 M 12 Y Estimated Continuous
8 01115276 Westconnaug Brook Westconnaug Reservoir 5.18 M 11 Y Continuous Continuous
9 01115275 Bear Tree Brook 0.62 Q 4 Y Estimated Continuous
30 01115350 Unnamed tributary 4 to Scituate Reservoir Coventry Brook, Knight Brook 0.79 Q 3 N None None
31 01115177 Toad Pond 0.03 Q 0 N None None
32 01115178 Unnamed tributary 1 to Scituate Reservoir Pine Swamp Brook 0.45 Q 4 N Estimated None
33 01115182 Unnamed tributary 3 to Scituate Reservoir Halls Estate Brook 0.28 Q 4 N Estimated None
36 Outflow from King Pond 0.76 Q 4 N None None
37 Fire tower stream 0.03 Q 3 N None None
38 01115278 Swamp Brook 1.92 0 Y Continuous2 Continuous2
19 01115170 Moswansicut Stream 3.25 M 10 Y Continuous Continuous
20 01115160 Unnamed tributary 1 to Moswansicut Pond reservoir Blanchard Brook 1.18 M 10 N None None
21 01115165 Unnamed tributary 2 to Moswansicut Pond reservoir Brook from Kimball Reservoir 0.30 Q 3 N Estimated None
22 01115167 Unnamed tributary 3 to Moswansicut Reservoir 0.10 M 8 N None None
34 01115164 Unnamed tributary from Kimball Reservoir Kimball Stream 0.27 Q 4 N None None
23 011151843 Ponaganset Reservoir 1.92 M 10 N None None
13 01115176 Unnamed waterbody at Horseshoe Dam Regulating reservoir 22.1 M 10 N None None
14 01115110 Huntinghouse Brook 6.29 M 11 Y Continuous Continuous
15 01115114 Rush Brook 4.70 M 11 Y Continuous Continuous
16 01115098 Peeptoad Brook Harrisdale Brook 4.97 M 11 Y Continuous Continuous
17 01115119 Dexter Pond Paine Pond 0.22 Q 2 N None None
18 01115120 Unnamed tributary to Regulating reservoir Unnamed brook A 0.28 Q 3 Y Estimated Continuous
10 01115274 Westconnaug Brook 1.48 M 11 N Estimated None
11 01115273 Unnamed tributary to Westconnaug Reservoir Unnamed brook south of Westconnaug Reservoir 0.72 Q 4 N Estimated None
12 011152745 Unnamed tributary to Westconnaug Brook Unnamed brook north of Westconnaug Reservoir 0.16 Q 2 N None None
Table 1.    Providence Water water-quality sampling stations and corresponding U.S. Geological Survey streamgages, in the Scituate Reservoir drainage area, Rhode Island, and data collection and monitoring statistics from October 1, 2020, to September 30, 2021.
1

Not all samples were analyzed for all water-quality properties or constituents.

2

Continuous monitoring began or resumed in October 2020.

In 2021, PW regularly, either monthly or quarterly, visited fixed sites on 37 tributaries within the Scituate Reservoir drainage area and collected water-quality samples; however, no samples were collected at the Toad Pond (USGS station 01115177; PW station 31) site because it was routinely dry. Although the Swamp Brook (USGS station 01115278; PW station 38) site began being monitored by USGS in October 2020 and is the 38th site to be monitored by PW, samples were first collected after September 30, 2021 (table 1). Therefore, a total of 36 sites were sampled by PW between October 1, 2020, and September 30, 2021, of which, three were sampled fewer than three times. Compiled and tabulated streamflow (measured or estimated by the USGS) and water-quality data (collected by PW) have been published in Breault and others (2000), Nimiroski and others (2008), Breault (2009), Breault and Campbell (2010a-d), Breault and Smith (2010), Smith and Breault (2011), Smith (2013, 2014, 2015a, b, 2016, 2018a-d, 2019a, b, 2021, 2022a, b, 2024)2021222324, Smith and Spaetzel (2021), and Spaetzel and Smith (2022a, b)37.

This report presents data on streamflow, water quality, and loads and yields of selected constituents for water year (WY) 2021 in the Scituate Reservoir drainage area. Data were collected in past studies by the USGS in cooperation with PW and the Rhode Island Department of Environmental Management and continuous measurements provided by PW (Smith and Spaetzel, 2021). This report summarizes measured and estimated streamflows presented for the 13 continuous-record and 11 partial-record streamgages (called “estimated” in table 1) in the drainage area. Estimated monthly and annual loads and yields of chloride and sodium are presented for the 16 streamgages at which specific conductance is continuously monitored by the USGS (table 1). Summary statistics for water-quality data collected by PW for 36 sampling stations during WY 2021 also are presented, and these data were used to calculate loads and yields of selected water-quality constituents where flow data were available. Water-quality data related to the Scituate Reservoir drainage area have been published serially by the USGS since 2000 (Breault and others, 2000). The presentation and content of this report has been replicated from Breault (2009), with annually updated methods, data, and interpretations (Breault and Campbell, 2010a–d; Breault and Smith, 2010; Smith and Breault, 2011; Smith 2013, 2014, 2015a, 2016, 2018a, b, 2019a, 2022a20212324252831).

Streamflow Data Collection and Estimation

Streamflow was measured or estimated by the USGS at 24 streamgages (table 1). Measured and estimated streamflows are necessary to estimate water volume and water-quality constituent loads and yields from tributary basins. Stream gage height was measured at 10- or 15-minute intervals at the continuous-record streamgages. Streamflow was computed with a gage height to discharge relation (known as a rating), which was developed on the basis of periodic manual measurements of streamflow. Daily mean streamflow at a streamgage was calculated by dividing the total volume of water that passed the streamgage each day by 86,400 (the number of seconds in a day). Periodic manual streamflow measurements at partial-record streamgages were used concurrently with continuous-record measurements from streamgages in nearby hydrologically similar drainage areas to estimate a continuous daily record at the partial-record streamgages. Specifically, daily streamflow records for the 11 partial-record sites in the Scituate Reservoir drainage area (table 1) were estimated by using the maintenance of variance extension type 1 (MOVE.1) method, as described by Ries and Friesz (2000), Smith (2015b), and Spaetzel and Smith (2022b); data needed to estimate streamflows at partial-record sites were retrieved from the USGS National Water Information System (NWIS; U.S. Geological Survey, 2023). The upper and lower 90-percent confidence limits for the estimated mean annual streamflows, as described by Tasker and Driver (1988), are listed in table 2. These USGS data indicate that there is a 90-percent chance that the estimated mean annual streamflow is between the upper and lower 90-percent confidence limits.

Table 2.    

Measured or estimated annual mean streamflow for tributary streams in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

[Data were collected by the U.S. Geological Survey (U.S. Geological Survey, 2023). Stations are shown on figure 1. PW, Providence Water; USGS, U.S. Geological Survey; ft3/s, cubic foot per second; (ft3/s)/mi2, cubic foot per second per square mile]

PW station number USGS station number Annual mean streamflow (ft3/s) Annual mean streamflow yield ([ft3/s]/mi2)
Streamflow Upper 90-percent confidence limit Lower 90-percent confidence limit
24 01115190 10.0 11.3 8.71 2.04
25 01115200 9.62 31.3 2.96 4.06
26 01115185 9.98 11.2 8.74 2.31
28 01115265 14.9 17.2 12.7 1.71
35 01115187 32.4 36.3 28.5 2.32
1 01115180 3.28 6.95 1.55 2.09
3 01115280 3.32 3.87 2.77 1.78
4 01115400 1.86 8.38 0.41 2.19
5 01115184 2.05 2.30 1.81 1.63
6 01115183 4.00 4.42 3.58 2.04
7 01115297 8.32 17.1 4.04 1.92
8 01115276 9.19 9.78 8.59 1.77
9 01115275 1.62 2.78 0.95 2.61
32 01115178 0.69 1.29 0.37 1.53
33 01115182 0.37 0.86 0.16 1.33
38 01115278 3.84 4.50 3.18 2.00
19 01115170 6.27 6.75 5.79 1.93
21 01115165 0.63 1.34 0.29 2.09
14 01115110 12.5 14.3 10.7 1.98
15 01115114 9.58 11.1 8.01 2.04
16 01115098 12.7 15.0 10.4 2.56
18 01115120 0.72 3.13 0.16 2.56
10 01115274 4.09 9.80 1.71 2.77
11 01115273 2.33 6.16 0.88 3.23
Table 2.    Measured or estimated annual mean streamflow for tributary streams in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

Continuous-record streamgages were operated and maintained by the USGS during WY 2021 (fig. 1; table 1). Streamflow data for these streamgages were collected at 10- or 15-minute intervals (near-real-time streamflow data) and were updated at 1-hour intervals through NWIS (U.S. Geological Survey, 2023). Error associated with measured streamflows was generally within about 15 percent as noted in the annual water year summary for each USGS streamgage (U.S. Geological Survey, 2023).

Water-Quality Data Collection and Analysis

Water-quality data were collected by the USGS and PW. Concentrations of sodium and chloride were estimated by the USGS from continuous records of specific conductance from 16 of the 24 streamgages. Water-quality samples were collected monthly or quarterly at 36 sampling stations in the Scituate Reservoir drainage area by PW during WY 2021 as part of a long-term sampling program (table 1).

Data Collected by the U.S. Geological Survey

Three or more water-quality samples were collected by the USGS at each of the 16 streamgages equipped with continuous specific conductance monitors in the Scituate Reservoir drainage area during WY 2021 (table 1), except from unnamed brook A (USGS station 01115120; PW station 18) and Peeptoad Brook (USGS station 01115098; PW station 16) sites where samples were not collected during the summer because the streambeds were dry. Samples were collected in the centroid of the streams during fall, winter, and summer. Water samples were processed in the USGS New England Water Science Center laboratory in Northborough, Massachusetts, at the conclusion of scheduled sampling. After the processing, the samples were packed in ice and shipped overnight to the USGS National Water Quality Laboratory in Lakewood, Colorado. Analytical results for the USGS water-quality samples are available through the NWIS web interface (U.S. Geological Survey, 2023); these include specific conductance and dissolved concentrations of calcium, chloride, magnesium, potassium, sodium, and sulfate.

The USGS collected and analyzed continuous-record specific conductance data at 16 streamgages (fig. 1; table 1). Measurements of specific conductance were recorded automatically at 10- or 15-minute intervals at each streamgage. Measurements were made by using an instream probe and standard USGS methods for continuous water-quality monitoring at streams (Wagner and others, 2006). The specific conductance measurement data are available through the NWIS web interface (U.S. Geological Survey, 2023). Concentrations of chloride and sodium were estimated from continuous measurements of specific conductance by using equations that were developed by the USGS to relate specific conductance to concentrations of chloride and sodium, as follows:

CCl=SPCm×b
and
(1)
CNa=SPCm×b
,
(2)
where

CCl

is the chloride concentration, in milligrams per liter;

CNa

is the sodium concentration, in milligrams per liter;

SPC

is the specific conductance, in microsiemens per centimeter;

m

is the slope from the MOVE.1 analysis (table 3); and

b

is the intercept from the MOVE.1 analysis (table 3).

These regression equations were developed by using the MOVE.1 method (also known as the line of organic correlation; Helsel and Hirsch, 2002) on the basis of concurrent measurements of specific conductance (USGS parameter code 90095, corresponding to the observed property “Specific conductance, water, unfiltered, normalized to 25 degrees Celsius, laboratory” with units of µS/cm) along with chloride (USGS parameter code 00940, corresponding to the observed property “Chloride, water filtered” with units of mg/L) and sodium (USGS parameter code 00930, corresponding to the observed property “Sodium, water filtered” with units of mg/L) concentrations measured in water-quality samples collected by the USGS from tributaries in the Scituate Reservoir drainage area during WY 2000, WY 2005, and WYs 2009–23 (table 3; U.S. Geological Survey, 2023).

Table 3.    

Regression equation coefficients used to estimate concentrations of chloride and sodium from values of specific conductance for U.S. Geological Survey streamgage stations in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

[Data were collected by the U.S. Geological Survey (U.S. Geological Survey, 2023). Constituent concentrations, continuous specific conductance, and parameter codes are available in National Water Information System (U.S. Geological Survey, 2023). Locations of stations are shown in figure 1. Chloride is “Chloride, water filtered” (U.S. Geological Survey [USGS] parameter code 00940); sodium is “Sodium, water filtered” (USGS parameter code 00930); specific conductance is “Specific conductance, water, unfiltered, normalized to 25 degrees Celsius, laboratory” (USGS parameter code 90095) measured in microsiemens per centimeter at 25 degrees Celsius. PW, Providence Water; mg/L, milligram per liter; ft3/s, cubic foot per second; ≥, greater than or equal to]

PW station number USGS station number Samples used in analyses Chloride (mg/L) Sodium (mg/L) Percentage of specific conductance record unavailable where streamflow is ≥0.01 ft3/s
Date range of samples Number of samples Slope Intercept Standard error of regressions (percent) Slope Intercept Standard error of regressions (percent)
24 01115190 03/08/2000; 03/29/2005; 01/22/2009 to 08/22/2023 44 1.1657 0.10659 3.2 1.1018 0.08995 5.0 6.1
26 01115185 01/22/2020 to 08/22/2023 12 1.1063 0.14054 6.3 0.9185 0.21066 2.9 4.6
28 01115265 03/28/2001; 03/30/2005; 01/22/2009 to 08/22/2023 45 1.1437 0.11781 3.8 1.0533 0.11041 5.3 4.9
35 01115187 03/28/2001; 03/29/2005; 01/22/2009 to 08/21/2023 44 1.1723 0.10101 4.0 1.0951 0.08976 5.2 0.35
3 01115280 03/08/2000; 03/30/2005; 01/22/2009 to 08/21/2023 42 1.2008 0.08650 3.1 1.0875 0.09106 4.8 5.2
5 01115184 03/05/2009 to 08/22/2023 41 1.2314 0.07031 3.8 1.0848 0.08551 4.8 0.038
6 01115183 03/08/2000; 03/30/2005; 01/22/2009 to 08/22/2023 55 1.1793 0.08437 4.6 1.1894 0.04825 6.2 2.0
7 01115297 03/28/2001; 03/30/2005; 01/22/2009 to 08/21/2023 44 1.0316 0.14569 4.4 0.8601 0.20013 5.3 5.1
8 01115276 01/22/2009 to 08/22/2023 41 1.0871 0.14598 2.6 1.0286 0.12185 3.5 0.53
9 01115275 03/08/2000; 03/30/2005; 01/22/2009 to 08/22/2023 43 1.0548 0.18169 2.2 1.0818 0.09317 3.0 0.22
38 01115278 01/22/2020 to 08/23/2023 12 1.4687 0.02243 11.2 1.2124 0.04999 7.6 0.14
19 01115170 03/08/2000; 03/29/2005; 01/22/2009 to 08/21/2023 50 1.2118 0.07599 2.3 1.2127 0.04507 2.6 4.0
14 01115110 01/22/2009 to 08/22/2023 50 0.9935 0.18278 7.2 0.9335 0.14700 7.6 1.4
15 01115114 01/22/2009 to 08/22/2023 56 1.1367 0.11580 3.7 1.0674 0.10164 5.3 18
16 01115098 03/28/2001; 03/29/2005; 01/22/2009 to 08/22/2023 44 1.2439 0.06412 4.0 1.06100 0.09808 6.0 0.31
18 01115120 01/22/2009 to 08/21/2023 34 1.1610 0.09934 2.6 1.1454 0.06242 3.2 6.7
Table 3.    Regression equation coefficients used to estimate concentrations of chloride and sodium from values of specific conductance for U.S. Geological Survey streamgage stations in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

MOVE.1 was chosen for regression analysis to maintain variance (Hirsch and Gilroy, 1984). Under some circumstances, specific conductance records were unavailable, possibly because of the following reasons: a sensor malfunctioned, was affected by debris, fouling, or ice, or was not submerged during low flow. In these cases, values of specific conductance were estimated by proportional distribution between recorded values. In general, the period of specific conductance record when streamflow occurred that was unavailable for each USGS station represents a small fraction of the record period for WY 2021 (table 3).

Data Collected by Providence Water

Water-quality samples were collected by PW at 36 fixed stations on tributaries draining to the Scituate Reservoir during WY 2021. Samples were scheduled to be collected monthly at 19 stations and quarterly at another 17 stations (table 1). A periodic water-quality sampling schedule was followed so that water-quality samples would be representative of various streamflow conditions. However, sometimes samples could not be collected because tributaries at the sampling stations were dry or frozen or because of inclement weather conditions. When possible, water-quality samples were collected by dipping the sample bottle into the tributary at the center of flow (Richard Blodgett, PW, written commun., 2005). Samples were transported on ice to PW water-quality laboratory at the P.J. Holton Water Purification Plant in Scituate. Water-quality properties and constituent concentrations were measured by using unfiltered water samples. These water-quality properties included pH, alkalinity, color, turbidity, and concentrations of chloride, nitrite, nitrate, orthophosphate, and Escherichia coli (E. coli) and total coliform bacteria; these data collected by PW are published in Smith and Spaetzel (2021). In this report, orthophosphate is the name for compounds with only one phosphate molecule, whereas phosphate is used to name any compound having one or more phosphate molecules. Analytical methods used for the determination of values or concentrations of pH, color, turbidity, alkalinity, and chloride are documented by Baird and others (2018). Concentrations of nitrite were determined by U.S. Environmental Protection Agency method 353.2 (U.S. Environmental Protection Agency, 1993). Concentrations of nitrate were determined by Standard Method 4500–NO3 (Holm and others, 2018). Concentrations of orthophosphate were determined by the Hach PhosVer Method (Hach Method 8048; Hach Company, 2000). Standard Method 9223 was used for the determination of concentrations of bacteria (Best and others, 2018).

Water-quality samples were collected by PW during a wide range of flow conditions. The WY 2021 measured or estimated daily mean flow-duration curves for the USGS streamgages at Westconnaug Brook (USGS station 01115276; PW station 8) and Shippee Brook (USGS station 01115200; PW station 25) are shown in figure 2. The curves represent the percentage of time that each flow was equaled or exceeded at the respective stations; the flows at each station on days when water-quality samples were collected are represented by the plotted points superimposed on the curves. At Westconnaug Brook, 11 samples were collected at flow rates that are exceeded between 16 and 95 percent of the time; this range indicates that the water-quality samples collected in WY 2021 represent a large range of the flow conditions but do not represent flows less than 1.7 ft3/s and greater than 14 ft3/s. At Shippee Brook, samples were collected only on a quarterly schedule at flow rates that are exceeded between 13 and 80 percent of the time; this range of flow rates excludes the flow conditions for both the lower (less than 0.74 ft3/s) and upper (greater than 15 ft3/s) flow range at Shippee Brook during WY 2021 (fig. 2).

11 samples were collected from Westconnaug Brook, and 4 samples, from Shippee Brook.
Figure 2.

Graph showing flow-duration curves and streamflow on the dates (represented by points) when water-quality samples were collected by Providence Water at the Westconnaug Brook (station 01115276) and Shippee Brook (station 01115200) U.S. Geological Survey streamgages in Foster, Rhode Island, for water year 2021 (October 1, 2020, through September 30, 2021). Locations of stations are shown on figure 1. Modified from Breault (2009). Data are from Smith and Spaetzel (2021).

Estimating Daily, Monthly, and Annual Loads and Yields

Daily, monthly, and annual chloride and sodium loads (in kilograms) were estimated for all streamgages for which continuous-streamflow and specific-conductance data were available for WY 2021. Daily flow-weighted concentrations of chloride and sodium were calculated by multiplying instantaneous flows by concurrent concentrations of chloride and sodium (estimated from measurements of specific conductance) for each day and dividing the sum by the total flow for that day. At the three instrumented monitoring stations, where continuous flow was unavailable (table 1), daily mean concentrations of chloride and sodium were calculated from the daily mean value of specific conductance for each day. The latter method may result in less accurate concentrations because instantaneous measurements of specific conductance may change (decrease or increase) with surface-water runoff; however, the variability of instantaneous measurements of specific conductance at these streamgages was generally small and daily mean values did not differ substantially from daily flow-weighted values estimated during prior water years when instantaneous flow data were available. Daily loads of chloride and sodium were estimated by multiplying daily flow-weighted concentrations of chloride and sodium (in milligrams per liter) by daily discharge (in liters per day). Daily data were summed to estimate monthly or annual loads (converted to metric tons).

Daily loads of water-quality constituents (in samples collected by PW) were calculated for all sampling dates during WY 2021 (table 4) for which periodic- or continuous-streamflow data were available (table 1). These loads were calculated by multiplying constituent concentrations (in milligrams or colony forming units per liter) in single samples by the daily discharge (in liters per day) for the day on which each sample was collected. The flows, which in some cases were estimates, were assumed to be representative of the flow at the time of the sample collection. Loads (in million colony forming units per day, kilograms per day, or grams per day) and yields (in million colony forming units per day per square mile, kilograms per day per square mile, or grams per day per square mile) were calculated for bacteria, chloride, nitrite, nitrate, and orthophosphate. Censored data (concentrations reported as less than method detection limits) were replaced with concentrations equal to one half the method detection limit.

Table 4.    

Daily loads of bacteria, chloride, nitrite, nitrate, and orthophosphate in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

[Data from Spaetzel and Smith (2021). Water-quality data are from samples collected and analyzed by Providence Water (PW). Locations of stations shown on figure 1. USGS, U.S. Geological Survey; ft3/s, cubic foot per second; CFU×106/d; millions of colony forming units per day; E. coli, Escherichia coli; kg/d, kilogram per day; g/d, gram per day as N, gram per day as nitrogen; g/d as P, gram per day as phosphate; <, less than; >, greater than]

PW station number USGS station number Date Daily mean streamflow (ft3/s) Total coliform bacteria ([CFU×106]/d) E. coli ([CFU×106]/d) Chloride (kg/d) Nitrite (g/d as N) Nitrate (g/d as N) Orthophosphate (g/d as P)
24 01115190 11/19/20 1.08 18,000 1,400 90 2.6 <130 160
12/21/20 7.68 55,000 <1,900 410 19 1,600 190
01/29/21 5.57 57,000 2,700 310 14 900 270
02/18/21 9.57 40,000 <2,300 580 23 3,000 700
03/15/21 5.38 26,000 <1,300 310 13 1,100 530
04/15/21 5.29 400,000 2,600 350 13 <650 780
05/25/21 2.15 130,000 2,700 140 11 <260 370
06/22/21 4.04 230,000 11,000 250 20 680 590
07/14/21 17.1 1,300,000 13,000 870 84 4,600 2,100
08/20/21 2.25 180,000 17,000 150 11 350 280
09/21/21 2.77 69,000 <680 130 14 520 540
25 01115200 11/24/20 14.7 5,100,000 540,000 530 72 3,800 3,600
03/25/21 2.95 25,000 <720 89 7.2 460 290
06/25/21 0.73 25,000 1,800 17 3.6 <89 71
07/26/21 2.42 150,000 3,000 66 12 <300 240
26 01115185 11/24/20 14.5 6,100,000 220,000 1,200 71 5,300 2,100
03/25/21 6.67 48,000 <1,600 440 16 1,300 820
06/25/21 1.63 330,000 1,600 130 8 <200 240
07/26/21 2.49 74,000 <610 150 6.1 450 300
28 01115265 10/14/20 0.20 7,700 470 20 0.49 <24 20
11/16/20 5.28 530,000 47,000 580 26 <650 390
12/16/20 9.15 140,000 9,200 470 22 <1,100 1,300
01/14/21 7.82 76,000 23,000 570 19 1,400 570
02/11/21 7.84 41,000 5,900 770 19 2,600 3,100
03/10/21 9.89 34,000 <2,400 640 24 1,400 1,500
04/23/21 27.1 550,000 13,000 1,500 130 <3,300 2,700
05/11/21 46.3 2,100,000 35,000 2,100 230 <5,700 3,400
06/09/21 4.70 210,000 13,000 300 46 <570 1,100
07/12/21 54.3 9,100,000 290,000 210 530 7,000 4,000
08/10/21 2.50 46,000 3,900 210 18 410 550
09/08/21 13.0 480,000 9,900 750 95 2,100 1,300
35 01115187 11/19/20 6.17 170,000 3,000 460 30 <750 1,500
12/21/20 18.0 150,000 4,400 870 220 5,500 1,800
01/29/21 18.4 210,000 4,500 970 45 6,900 1,400
02/18/21 35.7 220,000 8,700 1,800 87 13,000 1,700
03/15/21 16.2 130,000 <4,000 910 40 4,600 2,000
04/15/21 17.5 1,600,000 8,600 1,000 43 <2,100 1,300
05/25/21 4.38 370,000 4,400 250 21 <540 540
06/22/21 8.39 890,000 30,000 440 41 1,300 1,000
07/14/21 69.5 5,500,000 17,000 2,700 340 12,000 6,800
08/20/21 13.5 1,800,000 89,000 720 66 <1,700 2,000
09/21/21 7.69 340,000 24,000 370 38 1,700 940
1 01115180 10/06/20 0.04 1,200 <9.8 2 0.098 22 4.9
11/10/20 0.60 31,000 440 22 2.9 520 120
12/08/20 4.73 530,000 72,000 170 46 1,300 1,000
01/04/21 4.49 38,000 <1,100 140 22 2,000 330
03/02/21 6.85 130,000 99,000 230 50 3,800 670
04/01/21 8.32 280,000 <2,000 260 41 1,800 200
05/04/21 7.77 1,100,000 73,000 230 76 2,100 2,100
06/01/21 6.61 380,000 12,000 230 65 1,500 1,300
07/01/21 2.16 120,000 <530 68 21 1,300 480
08/11/21 1.00 33,000 240 30 4.9 440 370
09/02/21 24.9 >15,000,000 350,000 780 300 4,200 4,900
3 01115280 11/12/20 0.19 9,000 230 30 0.46 <23 28
12/10/20 2.20 26,000 540 200 5.4 960 220
01/12/21 1.92 14,000 470 170 4.7 1,600 280
03/04/21 3.96 25,000 3,000 430 9.7 2,600 290
04/02/21 7.70 82,000 18,000 730 19 1,200 570
05/06/21 5.52 130,000 5,500 540 14 <680 540
06/03/21 2.72 130,000 1,300 230 6.7 710 270
07/06/21 1.57 75,000 1,500 160 3.8 460 270
08/06/21 1.65 75,000 13,000 150 8.1 400 200
09/13/21 1.72 33,000 840 150 4.2 650 460
4 01115400 11/10/20 0.07 1,800 <17 1.4 0.17 <8.6 10
12/08/20 2.42 62,000 3,700 32 5.9 <300 120
01/04/21 2.12 8,900 <520 41 5.2 680 160
02/02/21 0.74 5,100 <180 18 1.8 <91 91
03/02/21 4.61 51,000 <1,100 73 11 <560 230
04/01/21 6.47 220,000 1,600 110 16 1,500 <160
05/04/21 5.75 87,000 <1,400 110 14 <700 280
06/01/21 4.33 290,000 2,100 77 11 <530 320
07/01/21 0.62 160,000 150 14 1.5 <76 61
08/11/21 0.16 17,000 <39 6.5 0.39 <20 20
09/02/21 43.8 3,700,000 32,000 880 110 7,300 3,200
5 01115184 02/25/21 3.26 52,000 800 150 8 3,000 400
06/24/21 0.84 41,000 840 44 4.1 470 82
08/30/21 0.34 26,000 83 27 1.7 190 100
6 01115183 11/10/20 0.66 27,000 1,800 91 1.6 310 210
12/08/20 7.57 220,000 7,600 450 37 4,200 370
01/04/21 5.33 53,000 6,800 350 13 3,700 390
03/02/21 7.37 37,000 3,600 610 36 6,900 720
04/01/21 14.5 790,000 43,000 1,200 110 4,000 350
05/04/21 9.66 1,700,000 170,000 730 95 <1,200 1,200
06/01/21 6.24 400,000 15,000 460 61 1,400 610
07/01/21 1.24 130,000 2,400 120 27 <150 270
08/11/21 1.35 96,000 3,200 130 20 <170 430
09/02/21 33.7 >20,000,000 680,000 2,000 490 5,100 4,900
7 01115297 10/01/20 <0.01 950 4.9 0.36 0.049 4.9 0.73
11/12/20 2.15 100,000 5,300 82 11 <260 420
12/10/20 10.2 160,000 7,700 230 50 1,800 1,200
01/12/21 6.02 93,000 <1,500 210 15 1,900 880
02/04/21 9.60 80,000 4,700 310 23 4,600 1,200
03/04/21 10.8 110,000 5,300 290 26 3,500 1,600
04/02/21 19.6 730,000 30,000 420 96 3,300 960
05/06/21 11.4 690,000 18,000 300 56 <1,400 2,200
06/03/21 9.69 340,000 17,000 210 47 <1,200 1,200
07/06/21 6.61 560,000 24,000 210 49 <810 810
08/06/21 10.9 4,100,000 550,000 330 53 <1,300 1,100
09/13/21 4.45 140,000 5,400 110 22 680 760
8 01115276 10/15/20 1.74 83,000 <430 66 4.3 <210 85
12/15/20 13.7 28,000 <3,400 380 34 2,700 2,700
01/13/21 8.78 8,600 <2,100 280 21 <1,100 640
02/05/21 7.98 5,900 <2,000 270 20 <980 590
03/09/21 9.90 2,400 <2,400 300 24 <1,200 2,900
04/08/21 11.4 17,000 <2,800 350 28 <1,400 1,400
05/07/21 14.2 56,000 <3,500 450 35 <1,700 2,100
06/08/21 7.12 130,000 3,500 240 17 <870 2,100
07/20/21 8.03 180,000 <2,000 260 20 <980 980
08/12/21 5.10 130,000 1,200 170 12 <620 1,100
09/24/21 4.97 110,000 1,200 180 12 <610 240
9 01115275 12/22/20 1.62 99,000 <400 230 4 2,100 280
02/25/21 2.19 36,000 <540 250 11 2,400 54
06/24/21 0.75 42,000 370 110 3.7 980 73
08/30/21 0.62 27,000 150 97 1.5 910 76
32 01115178 10/30/20 0.82 400,000 52,000 27 6 <100 160
03/18/21 0.59 8,100 <140 20 1.4 830 120
06/28/21 0.31 29,000 530 9.7 3.8 230 99
07/23/21 0.44 26,000 750 15 3.2 260 75
33 01115182 12/30/20 0.87 7,400 <210 21 2.1 460 130
03/26/21 0.34 4,500 <83 11 0.83 190 33
06/29/21 0.07 5,000 17 4.7 0.17 21 15
08/27/21 0.01 1,500 4.9 0.58 0.049 3 2
19 01115170 11/23/20 2.02 1,200,000 2,600 220 9.9 270 1,700
12/11/20 7.29 20,000 <1,800 980 18 1,500 180
01/19/21 14.7 65,000 18,000 1,200 36 3,700 1,100
03/05/21 7.91 1,900 <1,900 980 19 2,500 1,200
04/20/21 10.0 21,000 <2,400 1,200 24 3,100 730
05/12/21 13.1 19,000 <3,200 1,700 64 3,400 2,200
06/10/21 3.57 130,000 870 500 17 <440 700
07/19/21 10.9 140,000 <2,700 1,400 27 <1,300 530
08/17/21 0.24 19,000 59 30 0.59 <29 53
09/20/21 1.25 89,000 <310 150 3.1 210 180
21 01115165 03/23/21 0.57 13,000 570 54 2.8 790 84
06/25/21 0.32 38,000 860 33 3.9 310 63
07/22/21 0.51 130,000 2,000 48 5 430 62
14 01115110 11/25/20 7.50 1,800,000 110,000 280 18 <920 1,500
12/09/20 13.7 170,000 10,000 1,300 34 3,500 2,000
01/21/21 11.3 80,000 <2,800 410 28 3,400 1,700
02/10/21 5.71 24,000 <1,400 240 42 2,700 1,300
03/11/21 10.0 15,000 2,400 370 24 2,500 1,700
04/27/21 11.8 210,000 2,900 410 29 <1,400 1,700
05/20/21 4.01 320,000 4,900 140 9.8 <490 98
06/15/21 12.2 3,100,000 130,000 460 60 2,100 1,500
07/08/21 15.5 >9,200,000 3,100,000 690 110 3,800 1,500
08/23/21 13.5 2,700,000 130,000 560 66 1,900 3,600
09/10/21 17.2 10,000,000 210,000 590 84 3,600 2,100
15 01115114 11/25/20 5.42 1,000,000 41,000 560 13 940 530
12/09/20 8.34 150,000 11,000 260 20 2,900 1,000
01/21/21 7.19 19,000 <1,800 570 18 3,300 700
02/10/21 3.92 14,000 <960 470 9.6 2,400 860
03/11/21 7.24 7,100 1,800 750 18 2,800 2,100
04/27/21 7.99 240,000 5,900 760 20 <980 590
05/20/21 2.07 94,000 <510 260 10 <250 100
06/15/21 9.12 3,900,000 270,000 880 67 1,400 670
07/08/21 10.6 >6,300,000 640,000 830 100 2,200 1,800
08/23/21 8.13 1,800,000 68,000 780 60 2,300 1,200
09/10/21 12.3 >7,200,000 140,000 910 60 2,000 1,500
16 01115098 11/25/20 15.1 1,200,000 79,000 1,500 37 3,200 1,500
12/09/20 11.3 150,000 2,800 870 28 4,100 1,900
01/21/21 8.65 55,000 4,200 730 21 5,600 850
02/10/21 7.69 11,000 <1,900 730 110 6,500 1,500
03/11/21 8.36 240,000 <2,000 730 20 4,900 2,000
04/27/21 11.1 170,000 5,400 1,100 27 2,300 810
05/20/21 8.88 270,000 <2,200 890 43 <1,100 <220
06/15/21 10.8 1,800,000 67,000 970 79 2,200 530
07/08/21 10.5 940,000 5,100 1,100 51 1,900 1,500
08/23/21 6.75 600,000 9,900 560 50 1,000 1,200
09/10/21 12.9 1,100,000 6,300 1,000 63 3,300 1,600
18 01115120 12/23/20 0.18 8,500 180 30 0.44 130 8.8
03/23/21 0.20 1,500 98 32 0.49 160 29
07/22/21 0.19 72,000 1,100 30 1.4 93 56
10 01115274 11/16/20 1.29 87,000 8,200 75 6.3 <160 95
12/16/20 2.62 27,000 <640 140 6.4 <320 130
01/14/21 1.69 29,000 <410 110 4.1 260 120
02/11/21 1.22 13,000 <300 81 <3 190 120
03/10/21 2.18 17,000 <530 130 5.3 <270 590
04/23/21 4.30 71,000 <1,100 260 11 <530 530
05/11/21 8.27 440,000 <2,000 490 20 <1,000 2,400
06/09/21 0.92 110,000 450 52 2.3 <110 290
07/12/21 15.7 1,300,000 33,000 830 38 <2,200 1,500
08/10/21 0.45 12,000 220 30 1.1 <55 110
09/08/21 1.91 87,000 2,900 120 4.7 <230 190
11 01115273 10/27/20 0.04 2,200 <9.8 0.69 0.2 <4.9 2.9
03/22/21 1.33 30,000 <330 26 6.5 440 200
04/30/21 2.62 310,000 6,200 46 13 <320 320
08/24/21 6.51 870,000 8,300 89 64 <800 1,100
Table 4.    Daily loads of bacteria, chloride, nitrite, nitrate, and orthophosphate in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

Streamflow

Monitoring streamflow is a necessary step to measure the volume of water and estimate constituent loads to the Scituate Reservoir. The Ponaganset River is the largest monitored tributary to the Scituate Reservoir. Mean annual streamflow at the streamgage on the Ponaganset River (USGS station 01115187, PW station 35) for the entire period of its operation (mean of the annual mean streamflows for the period of record, WYs 1995–2020) before WY 2021 was 28.9 cubic feet per second (ft3/s; U.S. Geological Survey, 2023). During WY 2021, the annual mean streamflow of 32.4 ft3/s was just below the 75th percentile (33.2 ft3/s) for the period of record (fig. 3). Daily mean streamflows were commonly within the 10th and 90th percentile of all mean daily streamflows for WYs 1995–2020 and were similar to the median daily streamflows from December through June. Daily mean streamflows in WY 2021 were lower than the median long-term streamflows and 10th percentile values in October and November and were higher than the median daily streamflows and 90th percentile values from July through September (fig. 3). The other long-term continuous-record streamgage in the Scituate Reservoir drainage area is the Peeptoad Brook streamgage (USGS station 01115098; PW station 16). The mean annual streamflow at the Peeptoad Brook streamgage for the period of record (WYs 1995–2020) before WY 2021 was 10.4 ft3/s (U.S. Geological Survey, 2023). The annual mean streamflow at the Peeptoad Brook streamgage during WY 2021 also was higher than the mean annual streamflow for its period of record at 12.7 ft3/s. The annual mean measured or estimated streamflows for the other monitoring stations in this study ranged from 0.37 to 14.9 ft3/s (table 2).

From October to May, there was average or high flow; after, it was low. The annual
                     mean streamflow for 2021 was near the 75th percentile
Figure 3.

Hydrologic data taken at the U.S. Geological Survey streamgage on the Ponaganset River in Foster, Rhode Island (station 01115187). A, Graph showing measured daily mean streamflow for water year 2021 (October 1, 2020, through September 30, 2021) and the 10th percentile, median, and 90th percentile values of daily streamflow for water years 1995–2020 (October 1, 1994, through September 30, 2020). B, Boxplot showing annual mean streamflow during water year 2021 and the distribution of mean annual streamflows for water years 1995–2020. Location of station is shown on figure 1. Modified from Breault (2009). Data are from Smith and Spaetzel (2021).

Water Quality and Constituent Loads and Yields

Water-quality conditions in the Scituate Reservoir drainage area are described by summary statistics for water-quality properties, constituent concentrations, and estimated constituent loads and yields. Loads and yields measure the rates at which masses of constituents are transferred to the reservoir by tributaries. Tributaries with high flows tend to have high loads because the greater volume of water can carry more of the constituent to the reservoir per unit time than tributaries with low flows. Yield represents the constituent load per unit of drainage area and is calculated by dividing the load estimated for a streamgage by the drainage area for the monitoring station. Yields are useful for comparison among streamgages that have different drainage areas because each basin size and therefore total streamflow volume is normalized. Yields also are useful for examining potential differences among basin properties that may contribute to water quality in the reservoir.

Summary statistics include means and medians. For some purposes, median values are more appropriate because they are less likely to be affected by high or low concentrations (or outliers). Medians are especially important to use for summarizing a relatively limited number of values. In contrast, datasets that include a large number of values, such as continuously monitored streamflow and loads of chloride and sodium (estimated from measurements of specific conductance), are better summarized in terms of means because large datasets are more resistant to the effects of outliers than small datasets. Mean values also are particularly appropriate for measuring loads because outlier values, which typically represent large flows, are important to include in estimates of constituent masses delivered to receiving waters.

Uncertainties associated with measuring streamflow and specific conductance and with chloride and sodium sample collection, preservation, and analysis produce uncertainties in load and yield estimates. The load and yield estimates presented in the text and tables are the most likely values for chloride and sodium inputs from tributaries or their drainage basins, based on the available data and analysis methods. It may be best to discuss loads and yields in terms of a range within which the true values lie; however, the most likely values of loads and yields are presented for ease of discussion and presentation. The range within which the true values lie depends on the uncertainties in individual measurements of streamflow and concentration, which are difficult to quantify with the available information. The uncertainties associated with streamflow are commonly assumed to affect load and yield calculations more than the errors associated with measuring specific conductance or chemical analysis, and the uncertainties associated with estimated streamflow are greater than those associated with measured streamflow. The most likely values of loads and yields presented in the tables and text are sufficient for planning-level analysis of water quality in tributaries and their drainage basins.

Chloride and Sodium Loads and Yields Estimated From Specific-Conductance Monitoring Data

Chloride and sodium are constituents of special concern in the Scituate Reservoir drainage area. Chloride is difficult to remove from finished drinking water and can affect the taste and sodium is a constituent of potential concern for human health because some people on restricted diets might need to limit their sodium intake. Chloride and sodium are major constituents of road salt used for deicing, and several major roadways cross the Scituate Reservoir drainage area. State Routes 12 and 14 cut across the main body of the reservoir, and Route 116 parallels the eastern limb of the reservoir (fig. 1). Nimiroski and Waldron (2002) indicated that tributaries in basins with State-maintained roads had substantially higher concentrations of chloride and sodium than tributaries in basins with low road density, presumably because of deicing activities. Smith (2015b) indicated relations between concentrations of chloride collected from the tributaries to the Scituate Reservoir and total impervious area of the respective subbasins were significant; and Spaetzel and Smith (2022b) found 32 significant upward trends in tributary chloride concentrations at the 37 stations during WYs 1983–2019.

Monthly mean concentrations were calculated by dividing the total monthly load by the total discharge for the month. Estimated monthly mean chloride concentrations in tributaries of the Scituate Reservoir drainage area ranged from 7.9 to 100 milligrams per liter (mg/L) and estimated monthly mean sodium concentrations ranged from 5.6 to 58 mg/L (table 5). The highest monthly mean concentrations of chloride and sodium were estimated to be 100 and 58 mg/L, respectively, in the Rush Brook tributary to Regulating reservoir (USGS station 01115114; PW station 15) in October 2020. The estimated monthly mean concentrations for 13 of the 16 stations were highest or tied for highest during October 2020 compared with the estimated mean concentrations during the winter months. Monthly estimated mean concentrations were highest in November 2020 for Ponaganset River (USGS station 01115187; PW station 35), and highest in February 2021 for the unnamed tributary to Regulating reservoir (USGS station 01115120; PW station 18) and Swamp Brook (USGS station 01115187; PW station 38). The estimated monthly mean concentrations of chloride and sodium in Moswansicut stream (USGS station 01115170; PW station 19) remained consistent throughout the water year, ranging only by a maximum of 3 mg/L.

Table 5.    

Monthly mean concentrations of chloride and sodium estimated from continuous measurements of specific conductance in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

[Data were collected by the U.S. Geological Survey (2023). Locations of stations are shown on figure 1. Monthly mean concentrations were calculated by dividing the monthly load by the total discharge for the month. PW, Providence Water; USGS, U.S. Geological Survey; Cl, chloride; Na, sodium; mg/L, milligram per liter; —, not applicable]

PW station number USGS station number October 2020 November 2020 December 2020 January 2021 February 2021March 2021April 2021May 2021June 2021July 2021August 2021September 2021
Cl (mg/L) Na (mg/L) Cl (mg/L) Na (mg/L) Cl (mg/L) Na (mg/L) Cl (mg/L) Na (mg/L) Cl (mg/L) Na (mg/L)Cl (mg/L)Na (mg/L)Cl (mg/L)Na (mg/L)Cl (mg/L)Na (mg/L)Cl (mg/L)Na (mg/L)Cl (mg/L)Na (mg/L)Cl (mg/L)Na (mg/L)Cl (mg/L)Na (mg/L)
24 01115190 46 28 31 19 19 12 20 13 24 152516251623152315181123141711
26 01115185 45 25 34 20 19 12 21 13 25 162515231522142817231425151812
28 01115265 52 30 46 27 19 12 22 14 26 16221420131912221316102616159.4
35 01115187 27 16 28 17 16 10 17 11 20 122012191218111812159.31912148.7
3 01115280 69 39 46 27 27 16 25 15 38 224024332028173018261635211812
5 01115184 48 27 25 15 20 12 17 11 27 161711169.91610171117112314148.7
6 01115183 94 57 55 33 25 15 26 15 34 213219301828173018261536212616
7 01115297 17 10 12 8.1 7.9 5.6 8.6 6.0 9.1 6.38.86.18.45.98.76.19.06.28.25.8117.37.95.6
8 01115276 27 17 27 17 17 11 18 12 20 132013181219122214191224151812
9 01115275 69 41 55 33 43 25 47 28 48 294929482849295734492962374929
38 01115278 18 12 35 22 23 15 21 14 60 334728352227182516211428181511
19 01115170 52 31 52 31 51 31 50 30 52 315130523151315231503050304929
14 01115110 23 14 18 11 10 6.5 11 7.0 14 8.7138.0127.4117.1127.8106.4148.79.15.8
15 01115114 100 58 60 35 17 11 27 17 42 263723322025162415191216102113
16 01115098 41 24 40 24 34 21 34 21 38 233722372236223823301934213019
18 01115120 33 19 54 31 39 22 47 27 63 365834492845266236402361352615
Mean 47 28 39 23 24 15 26 16 34 203119291727162918241530182213
Table 5.    Monthly mean concentrations of chloride and sodium estimated from continuous measurements of specific conductance in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

Annual mean concentrations were calculated by dividing the total annual load by the total discharge for the year. The highest annual mean concentrations of chloride and sodium were estimated to be 51 and 30 mg/L, respectively, in Moswansicut stream (USGS station 01115170; PW station 19; table 6). The stations on the Moswansicut Pond reservoir and the unnamed tributary to Regulating reservoir are in the more developed, northeastern part of the Scituate Reservoir drainage area (fig. 1.) The similarly high annual mean concentrations of 49 mg/L of chloride and 29 mg/L of sodium in Bear Tree Brook (USGS station 01115275; PW station 9) are the result of residual chloride and sodium leaching to groundwater from a formerly uncovered salt storage pile (Nimiroski and Waldron, 2002).

Table 6.    

Estimated annual mean chloride and sodium concentrations, loads, and yields for streamgage stations in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

[Data were collected by the U.S. Geological Survey (2023). Locations of stations are shown on figure 1. Annual mean concentrations were calculated by dividing the annual load by the total discharge for the year; annual mean yields were calculated by dividing the sum of individual loads by the sum of the drainage area. PW, Providence Water; USGS, U.S. Geological Survey; Cl, chloride; mg/L, milligram per liter; Na, sodium; t/yr, metric ton per year; (t/yr)/mi2, metric ton per year per square mile; —, not applicable]

PW station number USGS station number Concentration Load Yield
Cl (mg/L) Na (mg/L) Cl (t/yr) Na (t/yr) Cl ([t/yr]/mi2) Na ([t/yr]/mi2)
24 01115190 22 14 190 120 39 25
26 01115185 22 14 200 120 46 29
28 01115265 20 13 270 170 31 19
35 01115187 17 11 500 320 36 23
3 01115280 30 18 88 53 47 28
5 01115184 18 11 33 21 26 16
6 01115183 30 18 110 65 55 33
7 01115297 8.8 6.1 66 45 15 10
8 01115276 19 12 160 100 30 20
9 01115275 49 29 71 42 110 68
38 01115278 30 19 100 65 54 34
19 01115170 51 30 290 170 88 52
14 01115110 12 7.2 130 80 20 13
15 01115114 28 17 240 150 50 31
16 01115098 34 21 390 240 79 48
18 01115120 43 25 27 16 98 57
Mean 27 17 52 32
Total 2,900 1,800
Table 6.    Estimated annual mean chloride and sodium concentrations, loads, and yields for streamgage stations in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

During WY 2021, the Scituate Reservoir received about 2,900 t of chloride and 1,800 t of sodium from tributaries that are equipped with instrumentation capable of continuously monitoring specific conductance (table 6). The highest annual chloride and sodium loads in the Scituate Reservoir drainage area during WY 2021 were estimated to be 500 and 320 t, respectively, at the Ponaganset River station (USGS station 01115187; PW station 35; table 6). Monthly estimated chloride and sodium loads tended to be lowest in October at each station (fig. 4). Monthly estimated chloride and sodium loads were both highest or tied for highest in December for 13 of the 16 stations. Monthly estimated chloride loads for Rush Brook (USGS station 01115114; PW station 15) were highest in March and April (31 t) but were similar to the December load of 30 t; monthly estimated sodium loads for Rush Brook were tied in December, March, and April (19 t). Hemlock Brook (USGS station 01115265; PW station 28) had the highest loads for chloride (37 t) and sodium (23 t) in April, and Swamp Brook (USGS station 01115278; PW station 38) had the highest loads for chloride (20 t) and sodium (12 t) in March (fig. 4). Monthly estimated chloride and sodium loads for Winsor Brook (USGS station 01115185; PW station 26) were highest in September (28 and 19 t, respectively) but similar to July (26 and 17 t, respectively; fig. 4).

Chloride and sodium loads generally peaked in September, July, and September, and
                        dipped in January-February, June, and August.
Figure 4.

Graphs showing monthly loads of chloride and sodium estimated from streamflow and specific conductance data for water year 2021 (October 1, 2020, through September 30, 2021) at 16 Providence Water sampling stations with continuous-record U.S. Geological Survey (USGS) water-quality data in the Scituate Reservoir drainage area, Rhode Island. Locations of stations are shown on figure 1; station information is listed in table 1. Data are from Smith and Spaetzel (2021).

During WY 2021, estimated annual loads of chloride and sodium at the continuous streamgage stations were greater than the median estimated annual loads for WYs 2009–20 for 8 of the 16 USGS stations (fig. 5; note that two stations do not have estimates for WYs 2009–20). From December through April, the sum of the monthly estimated loads of chloride and sodium for the respective drainage areas upstream of each streamgage accounted for about 50 to 70 percent of the annual load of chloride and sodium (fig. 4). The Ponaganset River (USGS station 01115187; PW station 35), which accounts for 20 percent of the combined drainage area upstream from the 16 USGS streamgage stations, accounted for 17 percent of the combined annual load of chloride and sodium for the 16 USGS streamgage stations. Peeptoad Brook (USGS station 01115098; PW station 16) drains an area that is 7 percent of the combined drainage area upstream from the 16 USGS streamgage stations and had the second highest percentage (13 percent) of the combined annual load of chloride and sodium (table 6).

Chloride and sodium loads in 2021 varied near the median for 2009-2020 loads.
Figure 5.

Graph showing annual loads of chloride and sodium estimated from streamflow and specific conductance data for water year 2021 (October 1, 2020, through September 30, 2021) and associated minimum, maximum, and median annual loads for water years 2009–20 (October 1, 2008, through September 30, 2020) at 16 Providence Water sampling stations with continuous-record U.S. Geological Survey water quality data in the Scituate Reservoir drainage area, Rhode Island. Locations of stations are shown on figure 1; station information is shown in table 1. Modified from Smith (2016). Data are from Smith and Spaetzel (2021).

Chloride and sodium loads fluctuate in similar patterns, whereas annual discharge
                        fluctuates in a wave pattern.
Figure 6.

Bar chart showing estimated annual loads of chloride and sodium estimated from continuous measurements of streamflow and specific conductance and the annual mean discharge yield for water years 2009–21 (October 1, 2009, through September 30, 2021) for the area upstream from 16 Providence Water sampling stations in the Scituate Reservoir drainage area, Rhode Island. Locations of stations are shown on figure 1; station information is listed in table 1. Modified from Smith (2019a). Data are from Smith and Spaetzel (2021).

The sum of annual loads during WY 2021 for 14 stations with continuous monitoring in WYs 2009–20 was 17 percent greater than the sum of annual loads estimated during the previous water year and approximately equal to the average of WYs 2009–20 (fig. 6). The two additional stations (Swamp Brook [USGS station 01115187; PW station 38] and Winsor Brook [USGS station 01115185; PW station 26]) represent about 11 percent of the sum of annual loads of chloride and sodium (fig. 6). The annual mean discharge yield in cubic feet per second per square mile for WY 2021 was marginally greater (by 0.13 cubic foot per second per square mile) than the WY 2009–20 average.

The highest annual chloride and sodium yields were 110 and 68 metric tons per year per square mile ([t/yr]/mi2; table 6), respectively, measured at Bear Tree Brook (USGS station 01115275; PW station 9) in a small subbasin (0.62 mi2). These high yields were the result, in part, from chloride and sodium groundwater contamination (Nimiroski and others, 2008). Chloride and sodium yields for Ponaganset River (USGS station 01115187; PW station 35), the largest subbasin in the Scituate Reservoir watershed, were approximately three times lower at 36 and 23 (t/yr)/mi2, respectively, than the yields for Bear Tree Brook (USGS station 01115275; PW station 9). The estimated annual mean yields of chloride and sodium for the drainage area upstream from the 16 USGS streamgage stations were 52 and 32 (t/yr)/mi2 (table 6), respectively. These estimated annual mean yields of chloride and sodium for WY 2021 were greater than the estimated annual mean yields of chloride and sodium in the prior water year by about 49 and 45 percent, respectively (Smith, 2024).

Physical and Chemical Properties and Daily Loads and Yields Estimated From Data Collected by Providence Water

PW routinely measured four water-quality properties (pH, color, turbidity, and alkalinity), and concentrations of chloride, nitrite, nitrate, orthophosphate, total coliform bacteria, and E. coli bacteria in monthly or quarterly samples of tributary water. These data are general indicators of water-quality conditions in the Scituate Reservoir drainage area.

Physical and Chemical Properties

Physical and chemical properties including pH, turbidity, alkalinity, and color were routinely measured to determine water quality in each of the six subbasins in the Scituate Reservoir drainage area (table 7) by PW. Specifically, pH is a measure of the effective hydrogen-ion concentration (U.S. Geological Survey, 2021) representing the negative base-10 logarithm of hydrogen-ion activity of a solution, in moles per liter; color can be an indirect measure of the amount of organic carbon dissolved in the water column; turbidity is an indirect measure of suspended particles; and alkalinity is a measure of the buffer capacity of water.

Table 7.    

Median values for water-quality data collected at Providence Water stations in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

[Data from Spaetzel and Smith (2021). Water-quality data are from samples collected and analyzed by Providence Water (PW). Locations of stations are shown on figure 1. If fewer than three samples were collected, the sample values are reported instead of a median. Minimum, median, and maximum values of all stations are based on station with more than two samples. USGS, U.S. Geological Survey; PCU, platinum-cobalt unit; NTU, nephelometric turbidity unit; CFU/100 mL, colony forming unit per 100 milliliters; E.coli., Escherichia coli; mg/L, milligram per liter; CaCO3, calcium carbonate; N, nitrogen; PO4, phosphate; <, less than; —, no data]

PW station number USGS station number Properties Constituents
pH Color (PCU) Turbidity (NTU) Total coliform bacteria (CFU/100 mL) E. coli (CFU/100 mL) Alkalinity (mg/L as CaCO3) Chloride (mg/L) Nitrite (mg/L as N) Nitrate (mg/L as N) Orthophosphate (mg/L as PO4)
24 01115190 6.4 33 0.47 1,000 20 6.5 24.9 0.001 0.07 0.05
25 01115200 6.1 58 0.57 2,000 75 5.4 11.8 0.002 <0.06 0.04
26 01115185 6.3 42 0.70 4,700 <25 6.4 29.3 0.002 0.08 0.055
27 011151845 5.7 17 0.32 340 41 3.8 12.9 <0.001 0.24 0.03
28 01115265 5.9 70 0.52 1,200 52 5.1 26.4 0.002 <0.05 0.04
29 01115271 6.3 40 0.61 290 <10 5.7 21.2 0.002 <0.05 0.04
35 01115187 6.4 40 0.57 1,800 20 6.4 21.6 0.002 0.07 0.05
1 01115180 6.8 100 1.4 2,100 30 11 12.9 0.003 0.18 0.08
2 01115181 6.2; 6.0 15; 10 0.18; 0.22 370; 75 <10; 10 6.7; 5.4 54.1, 63.9 0.001; 0.001 0.88; 0.69 0.11; 0.05
3 01115280 6.5 35 0.31 870 36 6.3 37.8 0.001 0.11 0.045
4 01115400 6.2 30 0.54 1,100 <10 8.1 8.0 0.001 <0.05 0.03
5 01115184 6.3 50 0.35 2,000 10 6 21.3 0.002 0.23 0.05
6 01115183 6.2 190 1.1 2,400 97 10 32.1 0.004 0.10 0.045
7 01115297 6.2 80 0.66 1,500 56 7.6 11.6 0.002 0.06 0.05
8 01115276 6.3 25 0.41 160 <10 5.5 13.2 0.001 <0.05 0.05
9 01115275 6.6 45 0.42 2,000 <10 8.8 58.6 0.002 0.53 0.045
30 01115350 5.9 55 0.35 880 10 5.8 23.7 0.001 0.14 0.04
31 01115177
32 01115178 6.5 210 1.2 3,100 70 13.8 14.0 0.003 0.28 0.08
33 01115182 6.2 26 0.5 1,700 <10 18.5 18.0 0.001 0.17 0.07
36 6.6 25 0.38 1,100 25 7.4 7.4 0.001 <0.06 0.095
37 5.7 23 0.22 910 <10 7.1 7.1 0.001 0.05 0.13
19 01115170 7.0 22 0.57 360 <10 12 51.1 0.001 0.08 0.06
20 01115160 6.3 250 0.86 2,300 52 13 71.4 0.006 0.07 0.11
21 01115165 6.7 37 1.5 4,900 110 18 38.7 0.004 0.40 0.06
22 01115167 6.7 32 1.1 1,200 42 20 49.8 0.014 1.10 0.05
34 01115164 6.2 55 1.1 2,200 60 15 29.6 0.002 <0.09 0.07
23 011151843 6.2 22 0.56 650 <10 5.4 19.4 0.001 0.06 0.03
13 01115176 6.7 38 0.62 830 30 9.6 33.0 0.001 <0.05 0.05
14 01115110 6.5 65 0.59 3,300 50 8.1 15.1 0.001 0.08 0.06
15 01115114 6.7 70 0.75 1,900 52 10 39.1 0.001 0.08 0.05
16 01115098 6.5 45 0.95 1,200 20 11 36.7 0.002 0.09 0.05
17 01115119 5.6; 6.2 40; 45 0.28; 0.38 1,100; 470 20; <10 8.5; 7.6 32.7; 37.4 0.001; 0.001 <0.05; 0.09 0.03; 0.02
18 01115120 6.4 55 0.37 1,900 40 9.3 65.6 0.001 0.30 0.06
10 01115274 5.8 25 0.17 1,100 <10 4.8 24.9 0.001 <0.05 0.04
11 01115273 5.7 170 0.63 3,600 <31 7.6 7.2 0.002 <0.05 0.055
12 011152745 6.2; 6.1 25; 30 0.72; 0.67 320; 560 <10; 63 5.6; 5.4 13.1; 13.1 0.001; 0.001 0.14; <0.05 0.07; 0.03
Minimum 5.7 17 0.17 160 <10 3.8 7.1 <0.001 <0.05 0.03
Median 6.3 42 0.57 1,500 30 7.6 23.7 0.002 0.08 0.05
Maximum 7.0 250 1.5 4,900 110 20 71.4 0.014 1.10 0.13
Table 7.    Median values for water-quality data collected at Providence Water stations in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

The median pH in tributaries in the Scituate Reservoir drainage area ranged from 5.7 to 7.0; the median of the medians for all stations with more than two samples was 6.3. Median values of color ranged from 17 to 250 platinum-cobalt units; the median for all stations was 42 platinum-cobalt units. Median values of turbidity ranged from 0.17 to 1.5 nephelometric turbidity units; the median for all stations was 0.57 nephelometric turbidity unit. Median alkalinity values in tributaries were low, ranging from 3.8 to 20 mg/L as calcium carbonate; the median for all stations was 7.6 mg/L alkalinity as calcium carbonate (table 7).

Constituent Concentrations and Daily Loads and Yields

Fecal indicator bacteria, chloride, and nutrients such as nitrogen and phosphorus are commonly detected in natural water; at elevated concentrations, these constituents can cause or contribute to water-quality impairments. Fecal indicator bacteria, which are found in the intestines of warm-blooded animals, may indicate impairment from sewage contamination or from livestock or wildlife that defecate in or near the stream margin. Chloride originates in tributary stream water from precipitation, weathering, or human activities such as waste disposal, use of septic systems, and road deicing. Sources of nutrients in tributary stream water include atmospheric deposition, leaching of naturally occurring organic material, discharge of groundwater that is enriched with nutrients from septic-system leachate, and runoff contaminated with fertilizer or animal waste. The ultimate intended use of water in the tributaries is drinking water, which must meet specific water-quality standards. For this reason, PW closely monitors concentrations of these constituents in tributaries. Median concentrations, loads, and yields of water-quality constituents are listed in tables 7, 8, and 9.

Table 8.    

Median daily loads of bacteria, chloride, nitrite, nitrate, and orthophosphate in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

[Concentration data from Spaetzel and Smith (2021)]. Water-quality data are from samples collected and analyzed by Providence Water (PW). Locations of stations are shown on figure 1. USGS, U.S. Geological Survey; (CFU×106)/d; million colony forming units per day; E. coli, Escherichia coli; kg/d, kilogram per day; g/d, gram per day; N, nitrogen; PO4, phosphate; <, less than; —, not applicable]

PW station number USGS station number Total coliform bacteria ([CFU×106]/d) E. coli ([CFU×106]/d) Chloride (kg/d) Nitrite (as N; g/d) Nitrate (as N; g/d) Orthophosphate (as PO4; g/d)
24 01115190 69,000 2,600 310 14 680 530
25 01115200 88,000 2,400 78 10 <380 260
26 01115185 200,000 <1,600 300 12 880 560
28 01115265 180,000 11,000 580 25 1,400 1,300
35 01115187 340,000 8,600 870 43 <2,100 1,500
1 01115180 130,000 <2,000 170 41 1,500 480
3 01115280 54,000 1,400 180 6.0 <700 280
4 01115400 62,000 <1,100 41 5.9 <530 <160
5 01115184 41,000 800 44 4.1 470 100
6 01115183 180,000 7,200 460 36 2,600 410
7 01115297 150,000 6,600 220 36 <1,400 1,000
8 01115276 56,000 <2,100 270 20 <980 1,100
9 01115275 39,000 <380 170 3.8 1500 74
32 01115178 28,000 640 18 3.5 240 110
33 01115182 4,800 <50 7.8 0.48 110 24
19 01115170 43,000 <1,600 980 18 <1,400 710
21 01115165 38,000 860 48 3.9 430 63
14 01115110 320,000 10,000 410 34 2,500 1,700
15 01115114 240,000 11,000 750 20 2,200 860
16 01115098 270,000 5,100 890 43 3,200 1,500
18 01115120 8,500 180 30 0.49 130 29
10 01115274 71,000 <640 120 5.3 260 190
11 01115273 170,000 <3,300 36 9.8 <380 260
Minimum 4,800 180 7.8 0.48 110 24
Median 71,000 <2,000 180 12 <700 410
Maximum 340,000 11,000 980 43 3,200 1,700
Table 8.    Median daily loads of bacteria, chloride, nitrite, nitrate, and orthophosphate in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

Table 9.    

Median daily yields of bacteria, chloride, nitrite, nitrate, and orthophosphate in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.

[Concentration data from Spaetzel and Smith (2021). Water-quality data are from samples collected and analyzed by Providence Water (PW). Locations of stations shown on figure 1. USGS, U.S. Geological Survey; ([CFU×106]/d)/mi2; millions of colony forming units per day per square mile; E. coli, Escherichia coli; N, nitrogen; PO4, phosphate; (kg/d)/mi2, kilogram per day per square mile; (g/d)/mi2, gram per day per square mile; <, less than; —, not applicable]

PW station number USGS station number Total coliform bacteria ([CFU×106]/mi2) E. coli ([CFU×106]/mi2) Chloride ([kg/d]/mi2) Nitrite (as N; [g/d]/mi2) Nitrate (as N; [g/d]/mi2) Orthophosphate (as PO4; [g/d]/mi2)
24 01115190 14,000 530 63 2.9 140 110
25 01115200 37,000 1,000 33 4.2 <160 110
26 01115185 46,000 <370 69 2.8 200 130
28 01115265 21,000 1,300 67 2.9 160 150
35 01115187 24,000 610 62 3.1 <150 110
1 01115180 83,000 <1,300 110 26 960 310
3 01115280 29,000 750 96 3.2 <370 150
4 01115400 73,000 <1,300 48 6.9 <620 <190
5 01115184 33,000 630 35 3.3 370 79
6 01115183 92,000 3,700 230 18 1,300 210
7 01115297 35,000 1,500 51 8.3 <320 230
8 01115276 11,000 <410 52 3.9 <190 210
9 01115275 63,000 <610 270 6.1 2,400 120
32 01115178 62,000 1,400 40 7.8 530 240
33 01115182 17,000 <180 28 1.8 390 86
19 01115170 13,000 <490 300 5.5 <430 220
21 01115165 130,000 2,900 160 13 1,400 210
14 01115110 51,000 1,600 65 5.4 400 270
15 01115114 51,000 2,300 160 4.2 470 180
16 01115098 54,000 1,000 180 8.7 640 300
18 01115120 30,000 640 110 1.8 460 100
10 01115274 48,000 <430 81 3.6 180 130
11 01115273 240,000 <4,600 50 14 <530 360
Minimum 11,000 530 28 1.8 140 79
Median 46,000 1,000 67 4.2 400 180
Maximum 240,000 3,700* 300 26 2,400 360
Table 9.    Median daily yields of bacteria, chloride, nitrite, nitrate, and orthophosphate in the Scituate Reservoir drainage area, Rhode Island, from October 1, 2020, through September 30, 2021.
*

The maximum uncensored yield was 3,700 [CFU×106]/mi2, but the maximum value may have been up to 4,600 [CFU×106]/mi2.

Bacteria

Median concentrations of total coliform bacteria were above the detection limit (1 colony forming unit per 100 milliliters [CFU/100 mL]) at all sites (table 7). Median concentrations of E. coli were censored below detection limits of either 10, 25, or 31 CFU/100 mL at 11 of the 33 stations that had more than 2 samples collected in WY 2021. Median concentrations of E. coli were uncensored for 22 stations, and these concentrations ranged from 10 to 110 CFU/100 mL. For three stations, medians were not determined because fewer than three samples were collected, and these concentrations ranged from less than 10 to 63 CFU/100 mL. Total coliform bacteria concentrations were greater than E. coli concentrations (as expected because total coliform is a more inclusive measure than E. coli); the medians of median concentrations for all sites in the drainage area were 1,500 CFU/100 mL for total coliform bacteria and 30 CFU/100 mL for E. coli (table 7). The highest median concentration of total coliform bacteria, 4,900 CFU/100 mL, was at unnamed tributary 2 to Moswansicut Reservoir (USGS station 01115165; PW station 21) which drains a 0.30 mi2 area in the Moswansicut Pond reservoir subbasin (table 1). Median concentrations of total coliform bacteria exceeded 2,000 CFU/100 mL at eight other stations including Winsor Brook (USGS station 01115185; PW station 26), Brandy Brook (USGS station 01115180; PW station 1), Quonopaug Brook (USGS station 01115183; PW station 6), unnamed tributary 1 to Scituate Reservoir (USGS station 01115178; PW station 32), unnamed tributary 1 to Moswansicut Pond reservoir (USGS station 01115160; PW station 20), unnamed tributary from Kimball Reservoir (USGS station 01115164; PW station 34), Huntinghouse Brook (USGS station 01115110; PW station 14), and unnamed tributary to Westconnaug Reservoir (USGS station 01115273; PW station 11). Median concentrations of total coliform bacteria were lowest at Westconnaug Brook (USGS station 01115276; PW station 8). The highest median concentration of E. coli, 110 CFU/100 mL (table 7), also was at unnamed tributary 2 to Moswansicut Reservoir.

Median daily loads and yields of total coliform bacteria and E. coli varied by two orders of magnitude or more (tables 8 and 9). The median daily loads of total coliform bacteria for all subbasins in the Scituate Reservoir drainage area ranged from 4,800 to 340,000 million colony forming units per day ([CFU×106]/d), and yields ranged from 11,000 to 240,000 million colony forming units per day per square mile ([(CFU×106)/d]/mi2); E. coli loads ranged from less than 180 to 11,000 (CFU×106)/d, and yields ranged from 530 to 3,700 ([CFU×106]/d)/mi2 (table 8 and 9). The highest median daily yield of total coliform bacteria at 240,000 ([CFU×106]/d)/mi2 was at unnamed tributary to Westconnaug Reservoir (USGS station 01115273; PW station 11), and the E. coli median yield at this station may have been up to 4,600 ([CFU×106]/d)/mi2. The highest (uncensored) median daily yield of E. coli of 3,700 ([CFU×106]/d)/mi2 occurred at Quonopaug Brook (USGS station 01115183; PW station 6; table 9). Although relatively high for sampling stations in the Scituate Reservoir subbasin, median daily bacteria yields at these stations were low to moderate for yields of indicator bacteria in sewage-contaminated stream water or stream water affected by stormwater runoff in an urban environment (Breault and others, 2002).

Chloride

Median chloride concentrations among PW stations ranged from 7.1 to 71.4 mg/L. The highest median concentration was collected at unnamed tributary 1 to Moswansicut Pond reservoir (USGS station 01115160; PW station 20; table 7). The median of median concentrations for all sites in the drainage area was 23.7 mg/L (table 7), which is very similar to the median of median concentrations in WY 2020 (24.8 mg/L; Smith, 2024). Median daily chloride loads and yields estimated from samples collected by PW varied among monitoring stations in the drainage area (tables 8 and 9). Moswansicut Stream (USGS station 01115170; PW station 19) had the largest median daily chloride load at 980 kilograms per day, followed by Peeptoad Brook (USGS station 01115098; PW station 16) and Ponaganset River (USGS station 01115187; PW station 35) at 890 and 870 kilograms per day, respectively (table 8). The median daily chloride yield at Moswansicut stream was about five times greater than the median yield at Ponaganset River and was the maximum among all stations at 300 kilograms per day per square mile (table 9). The median daily chloride yield for monitored areas within the drainage area was 67 kilograms per day per square mile.

Nutrients

Median concentrations of nitrite and nitrate (table 7) were 0.002 and 0.08 mg/L as nitrogen, respectively. The highest median concentrations of nitrite (0.014 mg/L as nitrogen) and nitrate (1.10 mg/L as nitrogen) were at unnamed tributary 3 to Moswansicut Reservoir (USGS station 01115167; PW station 22). The median concentration of orthophosphate for the entire study area (table 7) was 0.05 mg/L as phosphate. The maximum median concentration of orthophosphate was 0.13 mg/L as phosphate measured in a sample collected at Fire Tower Stream (PW station 37). Median daily loads of nitrite were largest at Ponaganset River (USGS station 01115187; PW station 35) and Peeptoad Brook (USGS station 01115098; PW station 16) at 43 grams per day as nitrogen (g/d; table 8). Median daily loads of nitrate were largest at Peeptoad Brook (USGS station 01115098; PW station 16) at 3,200 g/d as nitrogen. Median daily orthophosphate loads were largest (1,700 g/d as phosphate) at Huntinghouse Brook (USGS station 01115110; PW station 14; table 8). The maximum median daily yield for nitrite was 26 grams per day per square mile ([g/d]/mi2) as nitrogen at Brandy Brook (USGS station 01115180; PW station 1), and the maximum median daily yield for nitrate was 2,400 (g/d)/mi2 as nitrogen at Bear Tree Brook (USGS station 01115275; PW station 9). The maximum yields for nitrite and nitrate were six times greater than the median yields among all stations which were equal to 4.2 and 400 [g/d]/mi2 as nitrogen, respectively. For orthophosphate, the maximum median daily yield was 360 (g/d)/mi2 as phosphate at unnamed tributary to Westconnaug Reservoir (USGS station 01115273; PW station 11), which also had the highest total coliform bacteria median yield. The maximum median daily yield of orthophosphate was two times greater than the median among all station medians (180 [g/d]/mi2 as phosphate). The medians of median daily loads were 12 g/d for nitrite as nitrogen, less than 700 g/d for nitrate as nitrogen, and 410 g/d for orthophosphate as phosphate (table 8), respectively.

Summary

Since 1993, the U.S. Geological Survey (USGS), in cooperation with Providence Water (PW), has maintained a long-term cooperative water-quality monitoring program within the Scituate Reservoir drainage area. PW also has been independently monitoring and assessing water quality in the reservoir and reservoir drainage area for more than 60 years. Together, the data collected by the USGS and PW are used to calculate concentrations, loads, and yields of chloride, sodium, nutrients, and bacteria for tributaries within Scituate Reservoir drainage area on an annual basis.

During water year (WY) 2021, the U.S. Geological Survey measured or estimated streamflow at 24 streamgages; 16 of these streamgages are equipped with instrumentation capable of continuously monitoring water level, specific conductance, and water temperature. Before WY 2021, 14 streamgages were equipped with continuous-monitoring instrumentation; therefore, for annual comparisons of total chloride and sodium loads measured in the drainage area over the WY 2009–20 period, loads from the two streamgages added in WY 2021 are omitted. Water-quality samples, that are analyzed for dissolved concentrations of major ions (including chloride and sodium), were periodically collected by the USGS at each of the 16 streamgages. Concentrations of chloride and sodium, collected during WY 2021 and in previous water years, were used to support and refine relations between each ion and specific conductance. Using equations to relate specific conductance to concentrations of chloride and sodium, and combined with measured or estimated streamflow data, monthly and annual concentrations, loads, and yields were estimated for the 16 streamgages.

At 16 of the 24 USGS streamgages, where both streamflow and continuous specific conductance data were available, estimated monthly mean chloride concentrations ranged from 7.9 to 100 milligrams per liter (mg/L) and estimated monthly mean sodium concentrations ranged from 5.6 to 58 mg/L in tributaries of the Scituate Reservoir drainage area. The highest annual mean concentrations of chloride and sodium were estimated to be 51 and 30 mg/L, respectively, in Moswansicut stream (USGS station 01115170; PW station 19) in the more developed, northeastern part of the Scituate Reservoir drainage area. An estimated 2,900 metric tons (t) of chloride and 1,800 t of sodium were transported to the Scituate Reservoir during WY 2021 from tributaries equipped with instrumentation; annual chloride yields for tributaries in the drainage area ranged from 15 to 110 metric tons per square mile (t/mi2), and annual sodium yields ranged from 10 to 68 t/mi2. The sum of annual loads during WY 2021 for 14 stations with continuous monitoring in WYs 2009–20 was 17 percent greater than the sum of annual loads estimated during the previous water year and approximately equal to the average of WYs 2009–20.

PW collected at least one water-quality sample at 36 of 38 sampling stations in WY 2021, including at 15 of the 16 USGS continuous-record streamgages, as part of their long-term sampling program in the Scituate Reservoir drainage area. In WY 2021, Toad Pond (USGS station 01115177; PW station 31) and Swamp Brook (USGS station 01115278; PW station 38) were not sampled. Water-quality samples are analyzed by PW for pH, color, turbidity, alkalinity, and concentrations of chloride, nutrients, and bacteria. Water-quality data collected by PW are summarized by using values of central tendency and are used in combination with periodic- or continuous-streamflow data available at 23 of the 36 stations sampled in WY 2021 to calculate loads and yields of chloride, nutrients, and bacteria.

For water samples collected by PW, the median of the median pH values for samples from all stations on tributaries in the Scituate Reservoir drainage area was 6.3; the median value for color was 42 platinum-cobalt units; the median value for turbidity was 0.57 nephelometric turbidity unit; and the median concentration for alkalinity was 7.6 mg/L as calcium carbonate. The medians of the median concentrations for water samples from all stations were 23.7 milligrams per liter for chloride, 0.002 milligram per liter as nitrogen for nitrite, 0.08 milligram per liter as nitrogen for nitrate, 0.05 milligram per liter as phosphate for orthophosphate, 1,500 colony forming units per 100 milliliters for total coliform bacteria and 30 colony forming units per 100 milliliters for Escherichia coli. The medians of the median daily loads were 180 kilograms per day for chloride, 12 grams per day as nitrogen for nitrite, less than 700 grams per day as nitrogen for nitrate, 410 grams per day as orthophosphate for phosphate, 71,000 million colony forming units per day for coliform bacteria, and less than 2,000 million colony forming units per day for Escherichia coli. The medians of the median yields were 67 kilograms per day per square mile for chloride, 4.2 grams as nitrogen per day per square mile for nitrite, 400 grams as nitrogen per day per square mile for nitrate, 180 grams as orthophosphate per day per square mile for phosphate, 46,000 million colony forming units per day per square mile for coliform bacteria, and 1,000 million colony forming units per day per square mile for Escherichia coli.

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Conversion Factors

Multiply By To obtain
mile (mi) 1.609 kilometer (km)
square mile (mi2) 2.590 square kilometer (km2)
liter (L) 0.03531 cubic foot (ft3)
cubic foot per second (ft3/s) 0.02832 cubic meter per second (m3/s)
liter per day (L/d) 0.03531 cubic foot per day (ft3/d)
kilogram (kg) 2.205 pound avoirdupois (lb)
metric ton (t) 1.102 ton, short [2,000 lb]
gram per day (g/d) 0.0022 pound per day (lb/d)
kilogram per day (kg/d) 2.205 pound per day (lb/d)
metric ton per year (t/yr) 2205 pound per year (lb/yr)
kilogram per day per square mile ([kg/d]/mi2) 2.590 kilogram per day per square kilometer ([kg/d]/km2)
kilogram per day per square mile ([kg/d]/mi2) 2.205 pound per day per square mile ([lb/d]/mi2)
metric ton per year per square mile ([t/yr]/mi2) 2.590 metric ton per year per square kilometer ([t/yr]/mi2)
metric ton per year per square mile ([t/yr]/mi2) 2205 pound per year per square mile ([lb/yr]/mi2)

Datums

Vertical coordinate information is referenced to the North American Vertical Datum of 1988 (NAVD 88).

Horizontal coordinate information is referenced to the North American Datum of 1983 (NAD 83).

Supplemental Information

Concentrations of constituents in water are given in either milligrams per liter (mg/L) or colony forming units per 100 milliliters (CFU/100 mL).

Loads of bacteria in water are given in million colony forming units per day).

Yields of bacteria are given in million colony forming units per day per square mile ([(CFU×106)/d]/mi2).

Specific conductance is given in microsiemens per centimeter at 25 degrees Celsius (µS/cm at 25 °C).

Color is given in platinum-cobalt units (PCU).

A water year is the period from October 1 to September 30 and is designated by the year in which it ends; for example, water year 2020 was from October 1, 2019, to September 30, 2020.

Abbreviations

MOVE.1

Maintenance of Variance Extension type 1

NWIS

National Water Information System

PW

Providence Water (formerly Providence Water Supply Board)

USGS

U.S. Geological Survey

WY

water year

For more information, contact

Director, New England Water Science Center

U.S. Geological Survey

10 Bearfoot Road

Northborough, MA 01532

dc_nweng@usgs.gov

or visit our website at

https://www.usgs.gov/centers/new-england-water

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Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.

Although this information product, for the most part, is in the public domain, it also may contain copyrighted materials as noted in the text. Permission to reproduce copyrighted items must be secured from the copyright owner.

Suggested Citation

Smith, K.P., and Spaetzel, A.B., 2024, Streamflow, water quality, and constituent loads and yields, Scituate Reservoir drainage area, Rhode Island, water year 2021: U.S. Geological Survey Data Report 1203, 34 p., https://doi.org/10.3133/dr1203.

ISSN: 2771-9448 (online)

Study Area

Publication type Report
Publication Subtype USGS Numbered Series
Title Streamflow, water quality, and constituent loads and yields, Scituate Reservoir drainage area, Rhode Island, water year 2021
Series title Data Report
Series number 1203
DOI 10.3133/dr1203
Publication Date December 09, 2024
Year Published 2024
Language English
Publisher U.S. Geological Survey
Publisher location Reston, VA
Contributing office(s) New England Water Science Center
Description Report: vi, 34 p.; Data Release
Country United States
State Rhode Island
Other Geospatial Scituate Reservoir Drainage Area
Online Only (Y/N) Y
Additional Online Files (Y/N) N
Additional publication details