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The molecular weights of aquatic fulvic acids extracted from five rivers were determined by vapor pressure osmometry with water and tetrahydrofuran as solvents. The values obtained ranged from 500 to 950 dallons, indicating that the molecular weights of aquatic fulvic acids are not as great as has been suggested in...

Selected trace element analysis for cadmium, copper, lead, and zinc in precipitation samples by inductively coupled plasma atomic emission Spectrometry (ICP) and by atomic absorption spectrometry with graphite furnace atomization (AAGF) have been evaluated. This task was conducted in conjunction with a longterm study of precipitation chemistry at high altitude...

The amplitude and phase of 11 tidal constituents for the English Channel and southern North Sea are calculated using a frequency domain, finite element model. The governing equations - the shallow water equations - are modifed such that sea level is calculated using an elliptic equation of the Helmholz type...

A mathematical model is developed to describe the fate of hydrocarbon constituents of petroleum products introduced to soils as an immiscible liquid from sources such as leaking underground storage tanks and ruptured pipelines. The problem is one of multiphase transport (oil (immiscible), air, and water phases) of a reactive contaminant...

Kinetic and mass conservation equations are used to describe oxygen isotopic exchange between minerals and water in "closed" and open hydrothermal systems. In cases where n coexisting mineral phases having different reaction rates are present, the exchange process is described by a system of n + 1 simultaneous differential equations...

The water system that supplies the heavily populated Dalap-Uliga-Darrit (DUD) area of Majuro atoll, Marshall Island, relies almost entirely upon airstrip catchment of rain water. Droughts cause severe water supply problems and water rationing is required, even during periods of normal rainfall. The Laura area contains a substantial lens of...

Channel modifications from 1968 to 1969 on the South Fork Forked Deer River in western Tennessee have caused upstream degradation, downstream aggradation, and bank failures along the altered channels, adjacent reaches, and tributaries. The result of these adjustments is a general decrease in gradient as the channel attempts to absorb...

Secondary hydroeruptions occur in pyroclastic-flow deposits when water or ice is trapped beneath hot pyroclastic debris and rapidly heated to steam. These eruptions display various styles of activity including fumarolic degassing, tephra fountaining, and explosive cratering. The deposits, which occupy the layer 3 stratigraphic position on the top of pyroclastic-flow...

Pyrite is rapidly accumulating at the contact between the Cretaceous limestones of the Florida Platform and the hemipelagic sediments of the abyssal Gulf of Mexico. Sediments sampled with the submersible “Alvin” in 3266 m of water are associated with a dense...

The distribution of rare earth elements (REE) in ferromanganese nodules from DOMES Site A has been determined by instrumental neutron activation methods. The concentrations of the REE vary markedly. Low concentrations characterize samples from a depression (the valley), in which Quaternary sediments are thin or absent; high concentrations are found...

Salt-water upconing describes the phenomenon where salt water is transported vertically upward under a well in response to pumpage in a fresh-water aquifer underlain by salt water. Sharp interface methods have been used successfully to describe the physics of upconing. A finite-element model is developed...

A map shows generalized contours of the altitude of water levels for wells completed in the Sparta-Memphis aquifer in eastern Arkansas. Most water-level measurements used in constructing the map were from the spring of 1980, but supplemental measurements from other years indicated no long-term change in water levels. Hydrographs for...

This map shows the generalized contours of the altitude of water levels in wells completed in the Cockfield Formation in southeastern Arkansas for 1980. Most water levels used in constructing the map were made in the spring of 1980. However, in parts of the State water levels from the spring...

K-Ar ages of illite alteration associated with Middle Proterozoic Athabasca unconformity-type U deposits in Saskatchewan range from 414 to 1493 Ma. The K-Ar ages correlate with water contents and δD values such that illites with young K-Ar ages have δD values as low as −169 and water contents as high...

Selected radiocarbon data on surficial materials from the Lahontan basin, Nevada and California, provide a chronology of lake-level variation for the past 50,000 yr. A moderate-sized lake connected three western Lahontan subbasins (the Smoke Creek-Black Rock Desert subbasin, the Pyramid Lake subbasin, and the Winnemucca Dry Lake subbasin) from about...

Overall mass-transfer coefficients for the volatilization of ethylene dibromide from water were measured simultaneously with the oxygen absorption coefficient in a laboratory stirred tank. Coefficients were measured as a function of mixing conditions in the water for two windspeeds. The ethylene dibromide mass-transfer coefficient depended on windspeed; the ethylene dibromide...

13C NMR spectroscopy is used to examine the hydroxyl group functionality of a series of humic and fulvic acids from different aquatic environments. Samples first are methylated with13C-labeled diazomethane. The NMR spectra of the diazomethylated samples allow one to distinguish between methyl esters of carboxylic acids, methyl ethers of phenolic...

The US Geological Survey is utilizing a national network of more than 1000 satellite data-collection stations, four satellite-relay direct-readout ground stations, and more than 50 computers linked together in a private telecommunications network to acquire, process, and distribute hydrological data in near real-time. The four Survey offices operating a satellite...

This paper describes conceptual and mathematical modeling approaches to evaluate environmentally suitable waste management practices that prevent ground water pollution from landfill  disposal of solid wastes contaminated with organic solvents. Threshold values for disposal of solid wastes contaminated with acetone, nitrobenzene, chlorobenzene, and carbon tetrachloride were estimated using a disposal...

Deep bedrock aquifers are present in rocks of Cretaceous through Pennsylvanian age in eastern Colorado. These aquifers are the Laramie-Fox Hills (the uppermost aquifer studied), Fort Hays-Codell, Dakota-Cheyenne, Entrada-Dockum, Lyons, and Fountain. Structural mapping indicates the aquifers are 2,000 to 9,000 ft below land surface in most of eastern Colorado...

Ground-water samples from 41 wells penetrating basal Oakville sandstone (Miocene) in S Texas were chemically analysed to identify chemical changes related to nearby U orebodies. The coverage included a 240 km2 area which contains several fault-related U deposits. Factors affecting the hydrochemistry include: 1) relatively high permeabilities of buried fluvial-channel...

A two-component soil water flow model was used in conjunction with an equilibrium speciation model WATEQF to study aluminum mobility in soils of a forested watershed, White Oak Run, in the Shenandoah National Park, Virginia. Soil solution samples, taken from the O, E, B, C1, and C2horizons, were collected from...

The S isotope composition of pyrite in Cretaceous shales from the Western Interior of North America is related to organic C abundance, kerogen type and Fe availability. Both calcareous and noncalcareous rocks show a correlation between S and C, but noncalcareous...

An application is described of the branch-network flow model, BRANCH, to the upper Alabama River system in central Alabama. The model is used to simulate one-dimensional unsteady flows and water surface elevations in approximately 60 river miles of the Alabama River system. Preliminary calibration was made using 72 hours of...

Examples of the use of transient electromagnetic soundings for three ground-water exploration problems in sedimentary aquifers are given. The examples include: (1) estimating depths to water table and bedrock in an alluvium-filled basin, (2) mapping a confined fresh-water aquifer in bedrock sediments, and (3) locating...