Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test, Texas, USA
Yousif K. Kharaka, James J. Thordsen, Susan D. Hovorka, H. Seay Nance, David R. Cole, Tommy J. Phelps, Kevin G. Knauss
2009, Applied Geochemistry (24) 1106-1112
Sedimentary basins in general, and deep saline aquifers in particular, are being investigated as possible repositories for large volumes of anthropogenic CO2 that must be sequestered to mitigate global warming and related climate changes. To investigate the potential for the long-term storage of CO2 in such aquifers, 1600 t of...
Evaluation of a moderate resolution, satellite-based impervious surface map using an independent, high-resolution validation data set
J. W. Jones, T. Jarnagin
2009, Journal of Hydrologic Engineering (14) 369-376
Given the relatively high cost of mapping impervious surfaces at regional scales, substantial effort is being expended in the development of moderate-resolution, satellite-based methods for estimating impervious surface area (ISA). To rigorously assess the accuracy of these data products high quality, independently derived validation data are needed. High-resolution data were...
Investigating local variation in groundwater recharge along a topographic gradient, Walnut Creek, Iowa, USA
K. E. Schilling
2009, Hydrogeology Journal (17) 397-407
Groundwater recharge is an important component to hydrologic studies but is known to vary considerably across the landscape. The purpose of this study was to examine 4 years of water-level behavior in a transect of four water-table wells installed at Walnut Creek, Iowa, USA to evaluate how groundwater recharge varied...
Stimulating a Great Lakes coastal wetland seed bank using portable cofferdams: implications for habitat rehabilitation
K.P. Kowalski, D.A. Wilcox, M.J. Wiley
2009, Journal of Great Lakes Research (35) 206-214
Coastal wetland seed banks exposed by low lake levels or through management actions fuel the reestablishment of emergent plant assemblages (i.e., wetland habitat) critical to Great Lakes aquatic biota. This project explored the effectiveness of using portable, water-filled cofferdams as a management tool to promote the natural growth of emergent...
Respiratory arsenate reductase as a bidirectional enzyme
C. Richey, P. Chovanec, S.E. Hoeft, R.S. Oremland, P. Basu, J.F. Stolz
2009, Biochemical and Biophysical Research Communications (382) 298-302
The haloalkaliphilic bacterium Alkalilimnicola ehrlichii is capable of anaerobic chemolithoautotrophic growth by coupling the oxidation of arsenite (As(III)) to the reduction of nitrate and carbon dioxide. Analysis of its complete genome indicates that it lacks a conventional arsenite oxidase (Aox), but instead possesses two operons that each encode a putative...
Development of regression models to estimate flow duration statistics at ungaged streams in Oklahoma using a regional approach
R.A. Esralew
2009, Conference Paper, Proceedings of World Environmental and Water Resources Congress 2009 - World Environmental and Water Resources Congress 2009: Great Rivers
Multiple-regression analysis was used to develop equations for estimating annual and seasonal flow-duration statistics at ungaged streams in and near Oklahoma that are not substantially affected by human alteration. Ordinary least-squares and left-censored (Tobit) multiple-regression techniques were used to develop equations that relate these statistics, from continuous streamflow data at...
Complete and draft genome sequences of six members of the aquificales
A.-L. Reysenbach, N. Hamamura, M. Podar, E. Griffiths, S. Ferreira, R. Hochstein, J. Heidelberg, J. Johnson, D. Mead, A. Pohorille, M. Sarmiento, K. Sehweighofer, R. Seshadri, M.A. Voytek
2009, Journal of Bacteriology (191) 1992-1993
The Aquificales are widespread in marine and terrestrial hydrothermal environments. Here, we report the complete and draft genome sequences of six new members of the Aquificales: two marine species, Persephonella marina strain EX-H1 and Hydrogenivirga strain 128-5-R1 (from the East Pacific Rise, 9°50.3′N, 104°17.5′W, and the Eastern Lau Spreading Center, 176°11.5′W, 20°45.8′S, respectively), and four terrestrial isolates, Sulfurihydrogenibium...
Benthic nutrient sources to hypereutrophic Upper Klamath Lake, Oregon, USA
J.S. Kuwabara, B.R. Topping, D. D. Lynch, J.L. Carter, H.I. Essaid
2009, Environmental Toxicology and Chemistry (28) 516-524
Three collecting trips were coordinated in April, May, and August 2006 to sample the water column and benthos of hypereutrophic Upper Klamath Lake (OR, USA) through the annual cyanophyte bloom of Aphanizomenon flos‐aquae. A pore‐water profiler was designed and fabricated to obtain the first high‐resolution (centimeter‐scale) estimates of the vertical concentration...
Ultraviolet absorbance as a proxy for total dissolved mercury in streams
J.A. Dittman, J. B. Shanley, C. T. Driscoll, G. R. Aiken, A.T. Chalmers, J.E. Towse
2009, Environmental Pollution (157) 1953-1956
Stream water samples were collected over a range of hydrologic and seasonal conditions at three forested watersheds in the northeastern USA. Samples were analyzed for dissolved total mercury (THgd), DOC concentration and DOC composition, and UV254 absorbance across the three sites over different seasons and flow conditions. Pooling data from...
Reproductive health of bass in the potomac, USA, drainage: Part 1. exploring the effects of proximity to wastewater treatment plant discharge
L. R. Iwanowicz, V. S. Blazer, C.P. Guy, A.E. Pinkney, J.E. Mullcan, D.A. Alvarezw
2009, Environmental Toxicology and Chemistry (28) 1072-1083
Intersex (specifically, testicular oocytes) has been observed in male smallmouth bass (SMB; Micropterus dolomieu) and other centrarchids in the South Branch of the Potomac River, USA, and forks of the Shenandoah River, USA, during the past five years. This condition often is associated with exposure to estrogenic endocrine‐disrupting chemicals in some...
'Natural background' soil water repellency in conifer forests of the north-western USA: Its prediction and relationship to wildfire occurrence
S.H. Doerr, S.W. Woods, D.A. Martin, M. Casimiro
2009, Journal of Hydrology (371) 12-21
Soils under a wide range of vegetation types exhibit water repellency following the passage of a fire. This is viewed by many as one of the main causes for accelerated post-fire runoff and soil erosion and it has often been assumed that strong soil water repellency present after wildfire is...
How does landscape structure influence catchment transit time across different geomorphic provinces?
D. Tetzlaff, J. Seibert, K.J. McGuire, H. Laudon, Douglas A. Burns, S.M. Dunn, C. Soulsby
2009, Hydrological Processes (23) 945-953
Despite an increasing number of empirical investigations of catchment transit times (TTs), virtually all are based on individual catchments and there are few attempts to synthesize understanding across different geographical regions. Uniquely, this paper examines data from 55 catchments in five geomorphic provinces in northern temperate regions (Scotland, United States...
N-15 NMR spectra of naturally abundant nitrogen in soil and aquatic natural organic matter samples of the International Humic Substances Society
K. A. Thorn, L.G. Cox
2009, Organic Geochemistry (40) 484-499
The naturally abundant nitrogen in soil and aquatic NOM samples from the International Humic Substances Society has been characterized by solid state CP/MAS 15N NMR. Soil samples include humic and fulvic acids from the Elliot soil, Minnesota Waskish peat and Florida Pahokee peat, as well as the Summit Hill soil...
Feather mercury concentrations and physiological condition of great egret and white ibis nestlings in the Florida Everglades
G. Herring, D.E. Gawlik, D.G. Rumbold
2009, Science of the Total Environment (407) 2641-2649
Mercury contamination in the Florida Everglades has reportedly played a role in the recent decline of wading birds, although no studies have identified a mechanism leading to population-level effects. We assessed feather mercury levels in great egret (Ardea alba; n = 91) and white ibis (Eudocimus albus; n = 46)...
The occurrence of glyphosate, atrazine, and other pesticides in vernal pools and adjacent streams in Washington, DC, Maryland, Iowa, and Wyoming, 2005-2006
William A. Battaglin, Karen C. Rice, Michael J. Focazio, Sue Salmons, Robert X. Barry
2009, Environmental Monitoring and Assessment (155) 281-307
Vernal pools are sensitive environments that provide critical habitat for many species, including amphibians. These small water bodies are not always protected by pesticide label requirements for no-spray buffer zones, and the occurrence of pesticides in them is poorly documented. In this study, we investigated the occurrence of glyphosate, its...
Waste-indicator and pharmaceutical compounds in landfill-leachate-affected ground water near Elkhart, Indiana, 2000-2002
P.M. Buszka, D.J. Yeskis, D.W. Kolpin, E. T. Furlong, S.D. Zaugg, M. T. Meyer
2009, Bulletin of Environmental Contamination and Toxicology (82) 653-659
Four wells downgradient from a landfill near Elkhart, Indiana were sampled during 2000–2002 to evaluate the presence of waste-indicator and pharmaceutical compounds in landfill-leachate-affected ground water. Compounds detected in leachate-affected ground water included detergent metabolites (p-nonylphenol, nonylphenol monoethoxylate, nonylphenol diethoxylate, and octylphenol monoethoxylate), plasticizers (ethanol-2-butoxy-phosphate and diethylphthalate),...
Reproductive health of bass in the potomac, USA, drainage: Part 2. Seasonal occurrence of persistent and emerging organic contaminants
D.A. Alvarez, W.L. Cranor, S.D. Perkins, V.L. Schroeder, L. R. Iwanowicz, R.C. Clark, C.P. Guy, A.E. Pinkney, V. S. Blazer, J.E. Mullican
2009, Environmental Toxicology and Chemistry (28) 1084-1095
The seasonal occurrence of organic contaminants, many of which are potential endocrine disruptors, entering the Potomac River, USA, watershed was investigated using a two-pronged approach during the fall of 2005 and spring of 2006. Passive samplers (semipermeable membrane device and polar organic chemical integrative sampler [POCIS]) were deployed in tandem...
Utilizing chromophoric dissolved organic matter measurements to derive export and reactivity of dissolved organic carbon exported to the Arctic Ocean: A case study of the Yukon River, Alaska
R.G.M. Spencer, G. R. Aiken, K.D. Butler, M.M. Dornblaser, Robert G. Striegl, P.J. Hernes
2009, Geophysical Research Letters (36)
[1] The quality and quantity of dissolved organic matter (DOM) exported by Arctic rivers is known to vary with hydrology and this exported material plays a fundamental role in the biogeochemical cycling of carbon at high latitudes. We highlight the potential of optical measurements to examine DOM...
Mercury cycling in stream ecosystems. 2. Benthic methylmercury production and bed sediment - Pore water partitioning
Mark Marvin-DiPasquale, Michelle A. Lutz, Mark E. Brigham, David P. Krabbenhoft, George R. Aiken, William H. Orem, Britt D. Hall
2009, Environmental Science & Technology (43) 2726-2732
Mercury speciation, controls on methylmercury (MeHg) production, and bed sediment−pore water partitioning of total Hg (THg) and MeHg were examined in bed sediment from eight geochemically diverse streams where atmospheric deposition was the predominant Hg input. Across all streams, sediment THg concentrations were best described as a combined function of...
Biogeochemistry at a wetland sediment-alluvial aquifer interface in a landfill leachate plume
M.M. Lorah, I.M. Cozzarelli, J.K. Böhlke
2009, Journal of Contaminant Hydrology (105) 99-117
The biogeochemistry at the interface between sediments in a seasonally ponded wetland (slough) and an alluvial aquifer contaminated with landfill leachate was investigated to evaluate factors that can effect natural attenuation of landfill leachate contaminants in areas of groundwater/surface-water interaction. The biogeochemistry at the wetland-alluvial aquifer interface differed greatly between...
Evaluation of irrigation canal networks to assess stream connectivity in a watershed
M.E. Colvin, C.M. Moffitt
2009, River Research and Applications (25) 486-496
We used digital data sets, aerial photos and direct field observations in a geographical information system to evaluate the stream habitat in an Idaho watershed affected by agriculture. We found that the scale of the digital data sets affected the outcome of the assessment due to the presence of dewatered...
Sources and transformations of nitrate from streams draining varying land uses: Evidence from dual isotope analysis
Douglas A. Burns, E.W. Boyer, E.M. Elliott, C. Kendall
2009, Journal of Environmental Quality (38) 1149-1159
Knowledge of key sources and biogeochemical processes that affect the transport of nitrate (NO3-) in streams can inform watershed management strategies for controlling downstream eutrophication. We applied dual isotope analysis of NO3- to determine the dominant sources and processes that affect NO3- concentrations in six stream/river watersheds of different land...
Interbasin flow in the Great Basin with special reference to the southern Funeral Mountains and the source of Furnace Creek springs, Death Valley, California, U.S.
W.R. Belcher, M. S. Bedinger, J.T. Back, D. S. Sweetkind
2009, Journal of Hydrology (369) 30-43
Interbasin flow in the Great Basin has been established by scientific studies during the past century. While not occurring uniformly between all basins, its occurrence is common and is a function of the hydraulic gradient between basins and hydraulic conductivity of the intervening rocks. The Furnace Creek springs in Death...
The use of fluoride as a natural tracer in water and the relationship to geological features: Examples from the Animas River Watershed, San Juan Mountains, Silverton, Colorado
Dana J. Bove, Katherine Walton-Day, Briant A. Kimball
2009, Geochemistry: Exploration, Environment, Analysis (9) 125-138
Investigations within the Silverton caldera, in southwestern Colorado, used a combination of traditional geological mapping, alteration-assemblage mapping, and aqueous geochemical sampling that showed a relationship between geological and hydrologic features that may be used to better understand the provenance and evolution of the water. Veins containing fluorite, huebnerite, and elevated...
Simulating hydrologic and hydraulic processes throughout the Amazon River Basin
R.E. Beighley, K.G. Eggert, T. Dunne, Y. He, V. Gummadi, K.L. Verdin
2009, Hydrological Processes (23) 1221-1235
Presented here is a model framework based on a land surface topography that can be represented with various degrees of resolution and capable of providing representative channel/floodplain hydraulic characteristics on a daily to hourly scale. The framework integrates two models: (1) a water balance model (WBM) for the vertical fluxes...