Concentration, UV-spectroscopic characteristics and fractionation of DOC in stormflow from an urban stream, Southern California, USA
John A. Izbicki, Isabel Pimentel, Russell Johnson, George R. Aiken, Jerry Leenheer
2007, Environmental Chemistry (4) 35-48
The composition of dissolved organic carbon (DOC) in stormflow from urban areas has been greatly altered, both directly and indirectly, by human activities and there is concern that there may be public health issues associated with DOC, which has unknown composition from different sources within urban watersheds. This...
Role of hydrous iron oxide formation in attenuation and diel cycling of dissolved trace metals in a stream affected by acid rock drainage
Stephen R. Parker, Chris Gammons, Clain A. Jones, David A. Nimick
2007, Water, Air, & Soil Pollution (181) 247-263
Mining-impacted streams have been shown to undergo diel (24-h) fluctuations in concentrations of major and trace elements. Fisher Creek in south-central Montana, USA receives acid rock drainage (ARD) from natural and mining-related sources. A previous diel field study found substantial changes in dissolved metal concentrations at three sites with differing...
Nitrification in the euphotic zone as evidenced by nitrate dual isotopic composition: Observations from Monterey Bay, California
Scott D. Wankel, Carol Kendall, J.T. Pennington, Francisco P. Chavez, Adina Paytan
2007, Global Biogeochemical Cycles (21)
Coupled measurements of nitrate (NO3−), nitrogen (N), and oxygen (O) isotopic composition (δ15NNO3 and δ18ONO3) were made in surface waters of Monterey Bay to investigate multiple N cycling processes occurring within surface waters. Profiles collected throughout the year at three sites exhibit a wide range of values, suggesting simultaneous...
Recent climate trends and implications for water resources in the Catskill Mountain region, New York, USA
Douglas A. Burns, Julian Klaus, Michael R. McHale
2007, Journal of Hydrology (336) 155-170
Climate scientists have concluded that the earth’s surface air temperature warmed by 0.6 °C during the 20th century, and that warming induced by increasing concentrations of greenhouse gases is likely to continue in the 21st century, accompanied by changes in the hydrologic cycle. Climate change has important implications in the Catskill...
Isotopic characterization of three groundwater recharge sources and inferences for selected aquifers in the upper Klamath Basin of Oregon and California, USA
P.C. Palmer, M. W. Gannett, S.R. Hinkle
2007, Journal of Hydrology (336) 17-29
Stable isotope (??D and ??18O) signatures of three principal groundwater recharge areas in the 21,000-km2 upper Klamath Basin are used to infer recharge sources for aquifers in the interior parts of the basin. Two of the principal recharge areas, the Cascade Range on the western and southern margin of the...
Evidence for terrigenic SF6 in groundwater from basaltic aquifers, Jeju Island, Korea: Implications for groundwater dating
Dong-Chan Koh, Niel Plummer, Eurybiades Busenberg, Yongje Kim
2007, Journal of Hydrology (339) 93-104
Measurements of the concentrations of dichlorodifluoromethane (CFC-12), tritium (3H), and sulfur hexafluoride (SF6) in groundwater from basaltic aquifers in Jeju Island, Korea, demonstrate a terrigenic source of SF6. Using a lumped-parameter dispersion model, groundwater was identified as young water (<15 years), old water with negligible CFC-12 and 3H, and binary mixtures...
Nitrate dynamics within the Pajaro River, a nutrient-rich, losing stream
C.R. Ruehl, A.T. Fisher, Huertos M. Los, Scott D. Wankel, C.G. Wheat, Carol Kendall, C.E. Hatch, C. Shennan
2007, Journal of the North American Benthological Society (26) 191-206
The major ion chemistry of water from an 11.42-km reach of the Pajaro River, a losing stream in central coastal California, shows a consistent pattern of higher concentrations during the 2nd (dry) half of the water year. Most solutes are conserved during flow along the reach, but [NO3−] decreases by...
Correcting acoustic Doppler current profiler discharge measurement bias from moving-bed conditions without global positioning during the 2004 Glen Canyon Dam controlled flood on the Colorado River
J. W. Gartner, N. K. Ganju
2007, Limnology and Oceanography: Methods (5) 156-162
Discharge measurements were made by acoustic Doppler current profiler at two locations on the Colorado River during the 2004 controlled flood from Glen Canyon Dam, Arizona. Measurement hardware and software have constantly improved from the 1980s such that discharge measurements by acoustic profiling instruments are now routinely made over a...
Flux and age of dissolved organic carbon exported to the Arctic Ocean: A carbon isotopic study of the five largest arctic rivers
P.A. Raymond, J.W. McClelland, R.M. Holmes, A.V. Zhulidov, K. Mull, B. J. Peterson, Robert G. Striegl, G. R. Aiken, T.Y. Gurtovaya
2007, Global Biogeochemical Cycles (21)
The export and Δ14C-age of dissolved organic carbon (DOC) was determined for the Yenisey, Lena, Ob', Mackenzie, and Yukon rivers for 2004–2005. Concentrations of DOC elevate significantly with increasing discharge in these rivers, causing approximately 60% of the annual export to occur during a 2-month period following spring ice breakup....
Phosphorus budgets in Everglades wetland ecosystems: The effects of hydrology and nutrient enrichment
G.B. Noe, D.L. Childers
2007, Wetlands Ecology and Management (15) 189-205
The Florida Everglades is a naturally oligotrophic hydroscape that has experienced large changes in ecosystem structure and function as the result of increased anthropogenic phosphorus (P) loading and hydrologic changes. We present whole-ecosystem models of P cycling for Everglades wetlands with differing hydrology and P enrichment with the goal of...
Bedrock aquifers and population growth in the Denver Basin, Colorado, USA
J.E. Moore, R.G. Raynolds, M. Dechesne
2007, Episodes (30) 115-118
The Denver Basin bedrock aquifer system consists of Tertiary and Cretaceous age sedimentary rocks known as the Dawson, Denver, Arapahoe and Laramie-Fox Hills aquifers. The number of bedrock wells has increased from 12,000 in 1985 to over 33,700 in 2001 and the withdrawal of groundwater has caused water level declines...
Formation of mixed Al-Fe colloidal sorbent and dissolved-colloidal partitioning of Cu and Zn in the Cement Creek - Animas River Confluence, Silverton, Colorado
Laurence E. Schemel, Briant A. Kimball, Robert L. Runkel, Marisa H. Cox
2007, Applied Geochemistry (22) 1467-1484
Transport and chemical transformations of dissolved and colloidal Al, Fe, Cu and Zn were studied by detailed sampling in the mixing zone downstream from the confluence of Cement Creek (pH 4.1) with the Animas River (pH 7.6). Complete mixing resulted in...
Role of chemotaxis in the transport of bacteria through saturated porous media
R.M. Ford, Ronald W. Harvey
2007, Advances in Water Resources (30) 1608-1617
Populations of chemotactic bacteria are able to sense and respond to chemical gradients in their surroundings and direct their migration toward increasing concentrations of chemicals that they perceive to be beneficial to their survival. It has been suggested that this phenomenon may facilitate bioremediation processes by bringing bacteria into closer...
The science and practice of environmental flows and the role of hydrogeologists
M. Sophocleous
2007, Ground Water (45) 393-401
Conflicts between ecosystems and human needs for fresh water are increasing. The purpose of this paper is to raise awareness in the hydrogeologic community of environmental flows (EFs) and to address the major challenges involved in their protection. Ground water is a key component of EFs, and therefore hydrogeologists are...
Origin of halite brine in the Onondaga Trough near Syracuse, New York State, USA: Modeling geochemistry and variable-density flow
Richard M. Yager, William M. Kappel, Niel Plummer
2007, Hydrogeology Journal (15) 1321-1339
Halite brine (saturation ranging from 45 to 80%) lies within glacial sediments that fill the Onondaga Trough, a bedrock valley deepened by Pleistocene glaciation near Syracuse, New York State, USA. The most concentrated brine occupies the northern end of the trough, about 10 km downgradient of the northern limit of...
Altered stream-flow regimes and invasive plant species: The Tamarix case
J.C. Stromberg, S.J. Lite, R. Marler, C. Paradzick, P.B. Shafroth, D. Shorrock, J. M. White, M.S. White
2007, Global Ecology and Biogeography (16) 381-393
Aim: To test the hypothesis that anthropogenic alteration of stream-flow regimes is a key driver of compositional shifts from native to introduced riparian plant species. Location: The arid south-western United States; 24 river reaches in the Gila and Lower Colorado drainage basins of Arizona. Methods: We compared the abundance of...
Distributed energy-balance modeling of snow-cover evolution and melt in rugged terrain: Tobacco Root Mountains, Montana, USA
S.L. Letsinger, G.A. Olyphant
2007, Journal of Hydrology (336) 48-60
A distributed energy-balance model was developed for simulating snowpack evolution and melt in rugged terrain. The model, which was applied to a 43-km2 watershed in the Tobacco Root Mountains, Montana, USA, used measured ambient data from nearby weather stations to drive energy-balance calculations and to constrain the model of Liston...
Hydrologic significance of carbon monoxide concentrations in ground water
Francis H. Chapelle, Paul M. Bradley
2007, Ground Water (45) 272-280
Dissolved carbon monoxide (CO) is present in ground water produced from a variety of aquifer systems at concentrations ranging from 0.2 to 20 nanomoles per liter (0.0056 to 0.56 μg/L). In two shallow aquifers, one an unconsolidated coastal plain aquifer in Kings Bay, Georgia, and the other a fractured‐bedrock aquifer...
Oxygen and chlorine isotopic fractionation during perchlorate biodegradation: Laboratory results and implications for forensics and natural attenuation studies
Neil C. Sturchio, John Karl Bohlke, Abelardo D. Beloso Jr., S.H. Streger, Linnea J. Heraty, Paul B. Hatzinger
2007, Environmental Science & Technology (41) 2796-2802
Perchlorate is a widespread environmental contaminant having both anthropogenic and natural sources. Stable isotope ratios of O and Cl in a given sample of perchlorate may be used to distinguish its source(s). Isotopic ratios may also be useful for identifying the extent of biodegradation of perchlorate, which is critical for...
Freshwater-saltwater transition zone movement during aquifer storage and recovery cycles in Brooklyn and Queens, New York City, USA
Paul E. Misut, Clifford I. Voss
2007, Journal of Hydrology (337) 87-103
Freshwater storage in deep aquifers of Brooklyn and Queens, New York, USA, is under consideration as an emergency water supply for New York City. The purpose of a New York City storage and recovery system is to provide an emergency water supply during times of drought or other contingencies and...
Mercury speciation in piscivorous fish from mining-impacted reservoirs
James S. Kuwabara, Yuji Arai, Brent R. Topping, I.J. Pickering, G.N. George
2007, Environmental Science & Technology (41) 2745-2749
Guadalupe Reservoir (GUA), California, and Lahontan Reservoir (LAH), Nevada, U.S. are both affected either directly or indirectly by the legacy of gold and silver mining in the Sierra Nevada during the nineteenth century. Analysis of total mercury in fish from these lentic systems consistently indicate elevated concentrations (>1 μg·g-1 wet...
Enhancing water cycle measurements for future hydrologic research
H.W. Loescher, J.M. Jacobs, O. Wendroth, D.A. Robinson, G.S. Poulos, K. McGuire, P. Reed, B.P. Mohanty, J. B. Shanley, W. Krajewski
2007, Bulletin of the American Meteorological Society (88) 669-676
The Consortium of Universities for the Advancement of Hydrologic Sciences, Inc., established the Hydrologic Measurement Facility to transform watershed-scale hydrologic research by facilitating access to advanced instrumentation and expertise that would not otherwise be available to individual investigators. We outline a committee-based process that determined which suites of instrumentation best...
Assessment of contamination from arsenical pesticide use on orchards in the great valley region, Virginia and West Virginia, USA
Gilpin R. Robinson Jr., Peter Larkins, Carol J. Boughton, Bradley W. Reed, Philip L. Sibrell
2007, Journal of Environmental Quality (36) 654-663
Lead arsenate pesticides were widely used in apple orchards from 1925 to 1955. Soils from historic orchards in four counties in Virginia and West Virginia contained elevated concentrations of As and Pb, consistent with an arsenical pesticide source. Arsenic concentrations in approximately 50% of the orchard site soils and approximately...
Increased groundwater to stream discharge from permafrost thawing in the Yukon River basin: Potential impacts on lateral export of carbon and nitrogen
Michelle Ann Walvoord, Robert G. Striegl
2007, Geophysical Research Letters (34)
Arctic and subarctic watersheds are undergoing climate warming, permafrost thawing, and thermokarst formation resulting in quantitative shifts in surface water - groundwater interaction at the basin scale. Groundwater currently comprises almost one fourth of Yukon River water discharged to the Bering Sea and contributes 5-10% of the dissolved organic carbon...
Geoelectrical evidence of bicontinuum transport in groundwater
K. Singha, Frederick D. Day-Lewis, John W. Lane Jr.
2007, Geophysical Research Letters (34)
Bicontinuum models and rate-limited mass transfer (RLMT) explain complex transport behavior (e.g., long tailing and rebound) in heterogeneous geologic media, but experimental verification is problematic because geochemical samples represent the mobile component of the pore space. Here, we present geophysical evidence of RLMT at the field scale during an aquifer-storage...