Phytoforensics: Trees as bioindicators of potential indoor exposure via vapor intrusion
Jordan L. Wilson, V.A. Samaranayake, Matthew A. Limmer, Joel G. Burken
2018, PLoS ONE (13) 1-17
Human exposure to volatile organic compounds (VOCs) via vapor intrusion (VI) is an emerging public health concern with notable detrimental impacts on public health. Phytoforensics, plant sampling to semi-quantitatively delineate subsurface contamination, provides a potential non-invasive screening approach to detect VI potential, and plant sampling is effective and also time-...
Regional variability of nitrate fluxes in the unsaturated zone and groundwater, Wisconsin, USA
Christopher T. Green, Lixia Liao, Bernard T. Nolan, Paul F. Juckem, Christopher L. Shope, Anthony J. Tesoriero, Bryant C. Jurgens
2018, Water Resources Research (54) 301-322
Process-based modeling of regional NO3− fluxes to groundwater is critical for understanding and managing water quality, but the complexity of NO3− reactive transport processes make implementation a challenge. This study introduces a regional vertical flux method (VFM) for efficient estimation of reactive transport of NO3− in the vadose zone and...
Morphological indicators of a mascon beneath Ceres' largest crater, Kerwan
Michael T. Bland, Anton Ermakov, Carol A. Raymond, David A. Williams, Tim J. Bowling, F. Preusker, Ryan S. Park, Simone Marchi, Julie C. Castillo-Rogez, R.R. Fu, Christopher T. Russell
2018, Geophysical Research Letters (45) 1297-1304
Gravity data of Ceres returned by the National Aeronautics and Space Administration's Dawn spacecraft is consistent with a lower density crust of variable thickness overlying a higher density mantle. Crustal thickness variations can affect the long‐term, postimpact modification of impact craters on Ceres. Here we show...
Global trends in mineral commodities for advanced technologies
Steven M. Fortier, Christine Lyn Thomas, Erin A. McCullough, Amy Tolcin
2018, Natural Resources Research (27) 191-200
The U.S. Geological Survey National Minerals Information Center (NMIC) is the U.S. Government agency tasked with the collection, analysis, and dissemination of information on the production, consumption, import, export, and other measures of the flows of non-fuel mineral commodities of importance to the U.S. economy and national security. The NMIC...
Quality of water from crystalline rock aquifers in New England, New Jersey, and New York, 1995-2007
Sarah M. Flanagan, Joseph D. Ayotte, Gilpin R. Robinson Jr.
2018, Scientific Investigations Report 2011-5220
Crystalline bedrock aquifers in New England and parts of New Jersey and New York (NECR aquifers) are a major source of drinking water. Because the quality of water in these aquifers is highly variable, the U.S. Geological Survey (USGS) statistically analyzed chemical data on samples of untreated groundwater collected from...
Effects of lava heating on volatile-rich slopes on Io
Colin M. Dundas
2017, Journal of Geophysical Research E: Planets (122) 546-559
The upper crust of Io may be very rich in volatile sulfur and SO2. The surface is also highly volcanically active, and slopes may be warmed by radiant heat from the lava. This is particularly the case in paterae, which commonly host volcanic eruptions and long-lived lava lakes. Paterae slopes...
Baseline assessment of groundwater quality in Pike County, Pennsylvania, 2015
Lisa A. Senior, Charles A. Cravotta III
2017, Scientific Investigations Report 2017-5110
The Devonian-age Marcellus Shale and the Ordovician-age Utica Shale, which have the potential for natural gas development, underlie Pike County and neighboring counties in northeastern Pennsylvania. In 2015, the U.S. Geological Survey, in cooperation with the Pike County Conservation District, conducted a study that expanded on a previous more limited...
An evaluation of the zooplankton community at the Sheboygan River Area of Concern and non-Area of Concern comparison sites in western Lake Michigan rivers and harbors in 2016
Hayley T. Olds, Barbara C. Scudder Eikenberry, Daniel J. Burns, Amanda H. Bell
2017, Scientific Investigations Report 2017-5131
The Great Lakes Areas of Concern (AOCs) are considered to be the most severely degraded areas within the Great Lakes basin, as defined in the Great Lakes Water Quality Agreement and amendments. Among the 43 designated AOCs are four Lake Michigan AOCs in the State of Wisconsin. The smallest of...
Determining quantity and quality of retained oil in mature marly chalk and marlstone of the Cretaceous Niobrara Formation by low-temperature hydrous pyrolysis
Michael Lewan, Mark D. Sonnenfeld
2017, Conference Paper, Unconventional Resources Technology Conference
Low-temperature hydrous pyrolysis (LTHP) at 300°C (572°F) for 24 h released retained oils from 12- to 20-meshsize samples of mature Niobrara marly chalk and marlstone cores. The released oil accumulated on the water surface of the reactor, and is compositionally similar to oil produced from the same well. The quantities...
A new sulfur and carbon degassing inventory for the Southern Central American Volcanic Arc: The importance of accurate time-series datasets and possible tectonic processes responsible for temporal variations in arc-scale volatile emissions
Maarten de Moor, Christoph Kern, Geoffroy Avard, Cyril Muller, Sandro Aiuppa, Armando Saballos, Martha Ibarra, Peter LaFemina, Mario Protti, Tobias Fischer
2017, Geochemistry, Geophysics, Geosystems (18) 4437-4468
This work presents a new database of SO2 and CO2 fluxes from the Southern Central American Volcanic Arc (SCAVA) for the period 2015–2016. We report ∼300 SO2 flux measurements from 10 volcanoes and gas ratios from 11 volcanoes in Costa Rica and Nicaragua representing the most extensive available assessment of this ∼500 km...
Constraining the magmatic system at Mount St. Helens (2004–2008) using Bayesian inversion with physics-based models including gas escape and crystallization
Ying-Qi Wong, Paul Segall, Andrew Bradley, Kyle R. Anderson
2017, Journal of Geophysical Research B: Solid Earth (122) 7789-7812
Physics-based models of volcanic eruptions track conduit processes as functions of depth and time. When used in inversions, these models permit integration of diverse geological and geophysical data sets to constrain important parameters of magmatic systems. We develop a 1-D steady state conduit model for effusive eruptions including equilibrium crystallization...
Magnetotelluric imaging of lower crustal melt and lithospheric hydration in the Rocky Mountain Front transition zone, Colorado, USA
D. W. Feucht, Anne F Sheehan, Paul A. Bedrosian
2017, Journal of Geophysical Research B: Solid Earth (122) 9489-9510
We present an electrical resistivity model of the crust and upper mantle from two‐dimensional (2‐D) anisotropic inversion of magnetotelluric data collected along a 450 km transect of the Rio Grande rift, southern Rocky Mountains, and High Plains in Colorado, USA. Our model provides a window into the modern‐day lithosphere beneath the...
Organic chemical characterization and mass balance of a hydraulically fractured well: From fracturing fluid to produced water over 405 days
James Rosenblum, E. Michael Thurman, Imma Ferrer, George R. Aiken, Karl G. Linden
2017, Environmental Science & Technology (51) 14006-14015
A long-term field study (405 days) of a hydraulically fractured well from the Niobrara Formation in the Denver-Julesburg Basin was completed. Characterization of organic chemicals used in hydraulic fracturing and their changes through time, from the preinjected fracturing fluid to the produced water, was conducted. The characterization consisted of a...
Tree sampling as a method to assess vapor intrusion potential at a site characterized by VOC-contaminated groundwater and soil
Jordan L. Wilson, Matthew A. Limmer, V.A. Samaranayake, John G. Schumacher, Joel G. Burken
2017, Environmental Science & Technology (51) 10369-10378
Vapor intrusion (VI) by volatile organic compounds (VOCs) in the built environment presents a threat to human health. Traditional VI assessments are often time-, cost-, and labor-intensive; whereas traditional subsurface methods sample a relatively small volume in the subsurface and are difficult to collect within and near structures. Trees could...
Updated polychlorinated biphenyl mass budget for Lake Michigan
Jiehong Guo, Kevin Romanak, Stephen M. Westenbroek, An Li, Russell Kreis, Ronald A. Hites, Marta Venier
2017, Environmental Science & Technology (51) 12455-12465
This study revisits and updates the Lake Michigan Mass Balance Project (LMMBP) for polychlorinated biphenyls (PCBs) that was conducted in 1994–1995. This work uses recent concentrations of PCBs in tributary and open lake water, air, and sediment to calculate an updated mass budget. Five of the 11 LMMBP tributaries were...
Hydrogeology and water quality of sand and gravel aquifers in McHenry County, Illinois, 2009–14, and comparison to conditions in 1979
Amy M. Gahala
2017, Scientific Investigations Report 2017-5112
Baseline conditions for the sand and gravel aquifers (groundwater) in McHenry County, Illinois, were assessed using data from a countywide network of 44 monitoring wells collecting continuous water-level data from 2009–14. In 2010, water-quality data were collected from 41 of the monitoring wells, along with five additional monitoring wells...
Fractional crystallization-induced variations in sulfides from the Noril’sk-Talnakh mining district (polar Siberia, Russia)
C.J. Duran, S-J. Barnes, P. Plese, M. Kudrna Prasek, Michael L. Zientek, P. Page
2017, Ore Geology Reviews (90) 326-351
The distribution of platinum-group elements (PGE) within zoned magmatic ore bodies has been extensively studied and appears to be controlled by the partitioning behavior of the PGE during fractional crystallization of magmatic sulfide liquids. However, other chalcophile elements, especially TABS (Te, As, Bi, Sb, and Sn) have been neglected despite...
A comparison of four porewater sampling methods for metal mixtures and dissolved organic carbon and the implications for sediment toxicity evaluations
Danielle M. Cleveland, William G. Brumbaugh, Donald D. MacDonald
2017, Environmental Toxicology and Chemistry (36) 2906-2915
Evaluations of sediment quality conditions are commonly conducted using whole-sediment chemistry analyses but can be enhanced by evaluating multiple lines of evidence, including measures of the bioavailable forms of contaminants. In particular, porewater chemistry data provide information that is directly relevant for interpreting sediment toxicity data. Various methods for sampling...
Groundwater-quality data from the National Water-Quality Assessment Project, January through December 2014 and select quality-control data from May 2012 through December 2014
Terri Arnold, Laura M. Bexfield, MaryLynn Musgrove, Bruce D. Lindsey, Paul E. Stackelberg, Jeannie R. B. Barlow, Leslie A. DeSimone, Justin T. Kulongoski, James A. Kingsbury, Joseph D. Ayotte, Brandon J. Fleming, Kenneth Belitz
2017, Data Series 1063
Groundwater-quality data were collected from 559 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program from January through December 2014. The data were collected from four types of well networks: principal aquifer study networks, which are used to assess the quality of...
Water-quality data from an earthen dam site in southern Westchester County, New York, 2015
Anthony Chu, Michael L. Noll
2017, Data Series 1057
The U.S. Geological Survey, in cooperation with the New York City Department of Environmental Protection, sampled 37 sites in the reservoir area for nutrients, major ions, metals, pesticides and their degradates, volatile organic compounds, temperature, pH, and specific conductance during fall 2015. Data collection was done to characterize the local...
The interior structure of Ceres as revealed by surface topography
Roger R. Fu, Anton Ermakov, Simone Marchi, Julie C. Castillo-Rogez, Carol A. Raymond, Bradford Hager, Maria Zuber, Scott D. King, Michael T. Bland, Maria Cristina De Sanctis, Frank Preusker, Ryan S. Park, Christopher T. Russell
2017, Earth and Planetary Science Letters (476) 153-164
Ceres, the largest body in the asteroid belt (940 km diameter), provides a unique opportunity to study the interior structure of a volatile-rich dwarf planet. Variations in a planetary body's subsurface rheology and density affect the rate of topographic relaxation. Preferential attenuation of long...
Concentration and trend of 1,4-dioxane in wells sampled during 2002–2017 in the vicinity of the Tucson International Airport Area Superfund Site, Arizona
Fred D. Tillman
2017, Scientific Investigations Map 3385
Industrial activities causing extensive groundwater contamination led to the listing of the Tucson International Airport Area (TIAA) as a Superfund Site in 1983. Early groundwater investigations identified volatile organic compounds (VOCs), including the chlorinated solvents trichloroethylene (TCE) and perchloroethylene (PCE), in wells in the area. Several responsible parties were identified...
Assessment of critical minerals: Updated application of an early-warning screening methodology
Erin A. McCullough, Nedal Nassar
2017, Mineral Economics (30) 257-272
Increasing reliance on non-renewable mineral resources reinforces the need for identifying potential supply constraints before they occur. The US National Science and Technology Council recently released a report that outlines a methodology for screening potentially critical minerals based on three indicators: supply risk (R), production growth (<i class="EmphasisTypeItalic...
Pitted terrains on (1) Ceres and implications for shallow subsurface volatile distribution
H.G. Sizemore, Thomas Platz, Norbert Schorghofer, Thomas Prettyman, Maria Christina De Sanctis, David A. Crown, Nico Schmedemann, Andeas Nessemann, Thomas Kneissl, Simone Marchi, Paul M. Schenk, Michael T. Bland, B.E. Schmidt, Kynan H.G. Hughson, F. Tosi, F Zambon, S.C. Mest, R.A. Yingst, D.A. Williams, C.T. Russell, C.A. Raymond
2017, Geophysical Research Letters (44) 6570-6578
Prior to the arrival of the Dawn spacecraft at Ceres, the dwarf planet was anticipated to be ice-rich. Searches for morphological features related to ice have been ongoing during Dawn's mission at Ceres. Here we report the identification of pitted terrains associated with fresh Cerean impact craters. The Cerean pitted...
Holistic assessment of occurrence and fate of metolachlor within environmental compartments of agricultural watersheds
Claire E. Rose, Richard H. Coupe, Paul D. Capel, Richard M. Webb
2017, Science of the Total Environment (612) 708-719
Background: Metolachlor [(RS)-2-Chloro-N-(2-ethyl-6-methyl-phenyl)-N-(1-methoxypropan-2-yl)acetamide] and two degradates (metolachlor ethane-sulfonic acid and metolachlor oxanilic acid) are commonly observed in surface and groundwater. The behavior and fate of these compounds were examined over a 12-year period in seven agricultural watersheds in the United States. They were quantified in air, rain, streams, overland flow,...