National, holistic, watershed-scale approach to understand the sources, transport, and fate of agricultural chemicals
P. D. Capel, K. A. McCarthy, J.E. Barbash
2008, Journal of Environmental Quality (37) 983-993
This paper is an introduction to the following series of papers that report on in-depth investigations that have been conducted at five agricultural study areas across the United States in order to gain insights into how environmental processes and agricultural practices interact to determine the transport and fate of agricultural...
Bioaccumulation of pharmaceuticals and other anthropogenic waste indicators in earthworms from agricultural soil amended with biosolid or swine manure
C.A. Kinney, E. T. Furlong, D.W. Kolpin, M.R. Burkhardt, S.D. Zaugg, S.L. Werner, J.P. Bossio, M.J. Benotti
2008, Environmental Science & Technology (42) 1863-1870
Analysis of earthworms offers potential for assessing the transfer of organic anthropogenic waste indicators (AWIs) derived from land-applied biosolid or manure to biota. Earthworms and soil samples were collected from three Midwest agricultural fields to measure the presence and potential for transfer of 77 AWIs from land-applied...
Using heat to characterize streambed water flux variability in four stream reaches
H.I. Essaid, C.M. Zamora, K. A. McCarthy, J. R. Vogel, J.T. Wilson
2008, Journal of Environmental Quality (37) 1010-1023
Estimates of streambed water flux are needed for the interpretation of streambed chemistry and reactions. Continuous temperature and head monitoring in stream reaches within four agricultural watersheds (Leary Weber Ditch, IN; Maple Creek, NE; DR2 Drain, WA; and Merced River, CA) allowed heat to be used as a tracer to...
Effect of hydrological conditions on nitrous oxide, methane, and carbon dioxide dynamics in a bottomland hardwood forest and its implication for soil carbon sequestration
K. Yu, S.P. Faulkner, M.J. Baldwin
2008, Global Change Biology (14) 798-812
This study was conducted at three locations in a bottomland hardwood forest with a distinct elevation and hydrological gradient: ridge (high, dry), transition, and swamp (low, wet). At each location, concentrations of soil greenhouse gases (N2O, CH4, and CO2), their fluxes to the atmosphere, and soil redox potential (Eh) were...
Climatic and anthropogenic factors affecting river discharge to the global ocean, 1951-2000
John D. Milliman, K.L. Farnsworth, P. D. Jones, K.H. Xu, L.C. Smith
2008, Global and Planetary Change (62) 187-194
During the last half of the 20th century, cumulative annual discharge from 137 representative rivers (watershed areas ranging from 0.3 to 6300 ?? 103??km2) to the global ocean remained constant, although annual discharge from about one-third of these rivers changed by more than 30%. Discharge trends for many rivers reflected...
Spatial patterns of ecohydrologic properties on a hillslope-alluvial fan transect, central New Mexico
D. R. Bedford, E.E. Small
2008, Catena (73) 34-48
Spatial patterns of soil properties are linked to patchy vegetation in arid and semi-arid landscapes. The patterns of soil properties are generally assumed to be linked to the ecohydrological functioning of patchy dryland vegetation ecosystems. We studied the effects of vegetation canopy, its spatial pattern, and landforms on soil properties...
Utilizing geochemical, hydrologic, and boron isotopic data to assess the success of a salinity and selenium remediation project, Upper Colorado River Basin, Utah
D. L. Naftz, T.D. Bullen, Bernard J. Stolp, C.D. Wilkowske
2008, Science of the Total Environment (392) 1-11
Stream discharge and geochemical data were collected at two sites along lower Ashley Creek, Utah, from 1999 to 2003, to assess the success of a site specific salinity and Se remediation project. The remediation project involved the replacement of a leaking sewage lagoon system that was interacting with Mancos Shale...
Characterization of the shallow groundwater system in an alpine watershed: Handcart Gulch, Colorado, USA
Katherine G. Kahn, Shemin Ge, Jonathan S. Caine, A. Manning
2008, Hydrogeology Journal (16) 103-121
Water-table elevation measurements and aquifer parameter estimates are rare in alpine settings because few wells exist in these environments. Alpine groundwater systems may be a primary source of recharge to regional groundwater flow systems. Handcart Gulch is an alpine watershed in Colorado, USA comprised of highly fractured Proterozoic metamorphic and...
Flood trends and river engineering on the Mississippi River system
N. Pinter, A.A. Jemberie, J.W.F. Remo, R.A. Heine, B.S. Ickes
2008, Geophysical Research Letters (35)
Along >4000 km of the Mississippi River system, we document that climate, land-use change, and river engineering have contributed to statistically significant increases in flooding over the past 100-150 years. Trends were tested using a database of >8 million hydrological measurements. A geospatial database of historical engineering construction was used...
Nitrogen fluxes through unsaturated zones in five agricultural settings across the United States
C.T. Green, L.H. Fisher, B.A. Bekins
2008, Journal of Environmental Quality (37) 1073-1085
The main physical and chemical controls on nitrogen (N) fluxes between the root zone and the water table were determined for agricultural sites in California, Indiana, Maryland, Nebraska, and Washington from 2004 to 2005. Sites included irrigated and nonirrigated fields; soil textures ranging from clay to sand; crops including corn,...
Trace analysis of antidepressant pharmaceuticals and their select degradates in aquatic matrixes by LC/ESI/MS/MS
M.M. Schultz, E. T. Furlong
2008, Analytical Chemistry (80) 1756-1762
Treated wastewater effluent is a potential environmental point source for antidepressant pharmaceuticals. A quantitative method was developed for the determination of trace levels of antidepressants in environmental aquatic matrixes using solid-phase extraction coupled with liquid chromatography-electrospray ionization tandem mass spectrometry. Recoveries of parent antidepressants from matrix spiking...
Monitoring urban impacts on suspended sediment, trace element, and nutrient fluxes within the City of Atlanta, Georgia, USA: Program design, methodological considerations, and initial results
A. J. Horowitz, K. A. Elrick, J.J. Smith
2008, Hydrological Processes (22) 1473-1496
Atlanta, Georgia (City of Atlanta, COA), is one of the most rapidly growing urban areas in the US. Beginning in 2003, the US Geological Survey established a long-term water-quantity/quality monitoring network for the COA. The results obtained during the first 2 years have provided insights into the requirements needed to...
Acetylene as fast food: Implications for development of life on anoxic primordial earth and in the outer solar system
R.S. Oremland, M.A. Voytek
2008, Astrobiology (8) 45-58
Acetylene occurs, by photolysis of methane, in the atmospheres of jovian planets and Titan. In contrast, acetylene is only a trace component of Earth's current atmosphere. Nonetheless, a methane-rich atmosphere has been hypothesized for early Earth; this atmosphere would also have been...
Inverse geochemical modeling of groundwater evolution with emphasis on arsenic in the Mississippi River Valley alluvial aquifer, Arkansas (USA)
M.U. Sharif, R.K. Davis, K.F. Steele, B. Kim, T.M. Kresse, J.A. Fazio
2008, Journal of Hydrology (350) 41-55
Inverse geochemical modeling (PHREEQC) was used to identify the evolution of groundwater with emphasis on arsenic (As) release under reducing conditions in the shallow (25-30 m) Mississippi River Valley Alluvial aquifer, Arkansas, USA. The modeling was based on flow paths defined by high-precision (??2 cm) water level contour map; X-ray...
Ground-based thermography of fluvial systems at low and high discharge reveals potential complex thermal heterogeneity driven by flow variation and bioroughness
M.B. Cardenas, J. W. Harvey, A.I. Packman, D.T. Scott
2008, Hydrological Processes (22) 980-986
Temperature is a primary physical and biogeochemical variable in aquatic systems. Field‐based measurement of temperature at discrete sampling points has revealed temperature variability in fluvial systems, but traditional techniques do not readily allow for synoptic sampling schemes that can address temperature‐related questions with broad, yet detailed,...
A comparison of winter mercury accumulation at forested and no-canopy sites measured with different snow sampling techniques
S.J. Nelson, K.B. Johnson, K.C. Weathers, C.S. Loftin, I.J. Fernandez, J. S. Kahl, D. P. Krabbenhoft
2008, Applied Geochemistry (23) 384-398
Atmospheric mercury (Hg) is delivered to ecosystems via rain, snow, cloud/fog, and dry deposition. The importance of snow, especially snow that has passed through the forest canopy (throughfall), in delivering Hg to terrestrial ecosystems has received little attention in the literature. The snowpack...
Evaluation of statistical treatments of left-censored environmental data using coincident uncensored data sets: I. Summary statistics
Ronald C. Antweiler, Howard E. Taylor
2008, Environmental Science & Technology (42) 3732-3738
The main classes of statistical treatment of below-detection limit (left-censored) environmental data for the determination of basic statistics that have been used in the literature are substitution methods, maximum likelihood, regression on order statistics (ROS), and nonparametric techniques. These treatments, along with using all instrument-generated data (even those below detection),...
Evapotranspiration rates and crop coefficients for a restored marsh in the Sacramento-San Joaquin Delta, California, USA
Judith Z. Drexler, Frank E. Anderson, Richard L. Snyder
2008, Hydrological Processes (22) 725-735
The surface renewal method was used to estimate evapotranspiration (ET) for a restored marsh on Twitchell Island in the Sacramento–San Joaquin Delta, California, USA. ET estimates for the marsh, together with reference ET measurements from a nearby climate station, were used to determine crop coefficients over a 3‐year period during...
Anthropogenic influences on the input and biogeochemical cycling of nutrients and mercury in Great Salt Lake, Utah, USA
D. Naftz, C. Angeroth, T. Kenney, B. Waddell, N. Darnall, S. Silva, C. Perschon, J. Whitehead
2008, Applied Geochemistry (23) 1731-1744
Despite the ecological and economic importance of Great Salt Lake (GSL), little is known about the input and biogeochemical cycling of nutrients and trace elements in the lake. In response to increasing public concern regarding anthropogenic inputs to the GSL ecosystem, the US Geological Survey (USGS) and US Fish and...
Analysis of chlorothalonil and three degradates in sediment and soil
M.L. Hladik, K.M. Kuivila
2008, Journal of Agricultural and Food Chemistry (56) 2310-2314
A method has been developed for the simultaneous extraction of chlorothalonil and three of its degradates (4-hydroxy-2,5,6-trichloroisophthalonitrile, 1-carbamoyl-3-cyano-4-hydroxy-2,5,6-trichlorobenzene, and 1,3-dicarbamoyl-2,4,5,6-tetrachlorobenzene) from soils and sediments; the compounds were extracted using sonication with acetone and isolation of the parent compound and matrix interferences from the degradates by solid phase extraction (SPE)....
Mercury, trace elements and organic constituents in atmospheric fine particulate matter, Shenandoah National Park, Virginia, USA: A combined approach to sampling and analysis
A. Kolker, M.A. Engle, W. H. Orem, J.E. Bunnell, H.E. Lerch, D. P. Krabbenhoft, M.L. Olson, J.D. McCord
2008, Geostandards and Geoanalytical Research (32) 279-293
Compliance with U.S. air quality regulatory standards for atmospheric fine particulate matter (PM2.5) is based on meeting average 24 hour (35 μ m−3) and yearly (15 μg m−3) mass‐per‐unit‐volume limits, regardless of PM2.5 composition. Whereas this presents a workable regulatory framework, information on particle composition is needed...
Probable flood predictions in ungauged coastal basins of El Salvador
M.J. Friedel, M.E. Smith, A.M.E. Chica, D. Litke
2008, Conference Paper, Journal of Hydrologic Engineering
A regionalization procedure is presented and used to predict probable flooding in four ungauged coastal river basins of El Salvador: Paz, Jiboa, Grande de San Miguel, and Goascoran. The flood-prediction problem is sequentially solved for two regions: upstream mountains and downstream alluvial plains. In the upstream mountains, a set of...
Coupled effect of chemotaxis and growth on microbial distributions in organic-amended aquifer sediments: Observations from laboratory and field studies
M. Wang, R.M. Ford, R.W. Harvey
2008, Environmental Science & Technology (42) 3556-3562
The inter-relationship of growth and chemotactic response exhibited by two common soil-inhabiting bacteria was investigated to determine its impact on bacterial migration. Filter-chambers were used to simulate aquifer sediments characterized by vertical gradients of organic contaminants in both artificial groundwater flow systems in the laboratory and within...
The role of hydrologic regimes on dissolved organic carbon composition in an agricultural watershed
P.J. Hernes, R.G.M. Spencer, R.Y. Dyda, B.A. Pellerin, P.A.M. Bachand, B.A. Bergamaschi
2008, Geochimica et Cosmochimica Acta (72) 5266-5277
Willow Slough, a seasonally irrigated agricultural watershed in the Sacramento River valley, California, was sampled weekly in 2006 in order to investigate seasonal concentrations and compositions of dissolved organic carbon (DOC). Average DOC concentrations nearly doubled from winter baseflow (2.75 mg L-1) to summer irrigation (5.14 mg L-1), while a...
Assessment of crop growth and soil water modules in SWAT2000 using extensive field experiment data in an irrigation district of the Yellow River Basin
Y. Luo, C. He, M. Sophocleous, Z. Yin, R. Hongrui, Z. Ouyang
2008, Journal of Hydrology (352) 139-156
SWAT, a physically-based, hydrological model simulates crop growth, soil water and groundwater movement, and transport of sediment and nutrients at both the process and watershed scales. While the different versions of SWAT have been widely used throughout the world for agricultural and water resources applications, little has been done to...