Sea ice melting in the marginal ice zone
E.G. Josberger
1983, Journal of Geophysical Research - Oceans (88) 2841-2844
The heat and salt flux boundary conditions together with the freezing curve relationship are a necessary component of any ice-sea water thermodynamic model. A neutral two-layer oceanic planetary boundary layer model that incorporates these boundary conditions gives the following results: The interfacial salinity is within 10% of the far-field salinity...
Selective concentration of aromatic bases from water with a resin adsorbent
H. A. Stuber, Jerry A. Leenheer
1983, Analytical Chemistry (55) 111-115
Aromatic bases are concentrated from water on columns of a resin adsorbent and recovered by aqueous-acid elution. The degree of concentration attainable depends on the ratio of the capacity factor (k) of the neutral form of the amine to that of the ionized form. Capacity factors of ionic forms of...
Paleoceanographic implications of Miocene deep-sea hiatuses
G. Keller, J.A. Barron
1983, Geological Society of America Bulletin (94) 590-613
Miocene paleoceanographic evolution exhibits major changes resulting from the opening and closing of passages, the subsequent changes in oceanic circulation, and development of major Antarctic glaciation. The consequences and timing of these events can be observed in variations in the distribution of deep-sea...
Seasat synthetic aperture radar ( SAR) response to lowland vegetation types in eastern Maryland and Virginia
M. D. Krohn, N.M. Milton, D. B. Segal
1983, Journal of Geophysical Research - Oceans (88) 1937-1952
Examination of SEASAT SAR images of eastern Maryland and Virginia reveals botanical distinctions between vegetated lowland areas and adjacent upland areas. Radar returns from the lowland areas can be either brighter or darker than returns from the upland forests. Scattering models and scatterometer measurements predict an increase of 6 dB...
Comparison of analytical methods for the determination of silica in geothermal waters
J.C. Chemerys
1983, Journal of Volcanology and Geothermal Research (16) 57-63
The silica concentration of 26 Guatemalan geothermal waters were analyzed colorimetrically (spectrophotometrically) and by atomic absorption. Results by the atomic absorption method were less affected by polymerization and precipitation of silica from supersaturated solutions. Shaking the samples prior to analysis improves the accuracy of the atomic absorption results. The advantages...
Stability of streams and lakes on Mars
M. H. Carr
1983, Icarus (56) 476-495
Under present climatic conditions streams and lakes on Mars will freeze. Freezing is slow and would have a negligible effect in impeding flow of the large floods that are believed to have eroded the outflow channels. Valley networks are more difficult...
Origin of concretionary Mn-Fe-oxides in stream sediments of Maine, U.S.A.
G.A. Nowlan, J. B. McHugh, T. D. Hessin
1983, Chemical Geology (38) 141-156
Studies of stream and sediment-pore waters largely explain the genesis of concretionary Mn-Fe-oxides in Maine. Waters of two small streams near Jackman, Maine, were studied in terms of pH, Eh, dissolved oxygen, dissolved organic carbon, dissolved Mn, total dissolved Fe, and ferrous and ferric Fe. Pyrite Creek has profuse concretions...
Development of reaction models for ground-water systems
Niel Plummer, D.L. Parkhurst, D.C. Thorstenson
1983, Geochimica et Cosmochimica Acta (47) 665-685
Methods are described for developing geochemical reaction models from the observed chemical compositions of ground water along a hydrologic flow path. The roles of thermodynamic speciation programs, mass balance calculations, and reaction-path simulations in developing and testing reaction models are contrasted. Electron transfer is included in the mass balance equations...
River discharge controls phytoplankton dynamics in the northern San Francisco Bay estuary
J. E. Cloern, A.E. Alpine, B.E. Cole, R.L.J. Wong, J.F. Arthur, M.D. Ball
1983, Estuarine, Coastal and Shelf Science (16) 415-429
Phytoplankton dynamics in the upper reach of the northern San Francisco Bay estuary are usually characterized by low biomass dominated by microflagellates or freshwater diatoms in winter, and high biomass dominated by neritic diatoms in summer. During two successive years of very low river discharge (the drought of 1976-77), the...
Gas-film coefficients for streams
R. E. Rathbun, D. Y. Tai
1983, Journal of Environmental Engineering (109) 1111-1127
Equations for predicting the gas-film coefficient for the volatilization of organic solutes from streams are developed. The film coefficient is a function of windspeed and water temperature. The dependence of the coefficient on windspeed is determined from published information on the evaporation of water from a canal. The dependence of...
VLF electromagnetic investigations of the crater and central dome of Mount St. Helens, Washington
J.N. Towle
1983, Journal of Volcanology and Geothermal Research (19) 113-120
A very low frequency (VLF) electromagnetic induction survey in the crater of Mount St. Helens has identified several electrically conductive structures that appear to be associated with thermal anomalies and ground water within the crater. The most interesting of these conductive structures lies beneath the central dome. It is probably...
The contribution of humic substances to the acidity of colored natural waters
B.G. Oliver, E.M. Thurman, Ronald L. Malcolm
1983, Geochimica et Cosmochimica Acta (47) 2031-2035
An operationally defined carboxyl content of humic substances extracted from rivers, streams, lakes, wetlands, and groundwaters throughout the United States and Canada is reported. Despite the diversity of the samples, only small variations were observed in this humic carboxyl content. The dissociation behavior of two combined fulvic/humic acid extracts was...
Approximate sampling distribution of the serial correlation coefficient for small samples
Gary D. Tasker
1983, Water Resources Research (19) 579-582
The probability density function for the sample serial correlation coefficient r can be approximated byf(r) = (β(½, ½(T + 1)))−1(1 − r2)½(T− 1)(1+ c2 − 2cr)−½(T), whereβ is the Beta function, T= n− 2, c = ρ − [(1 + ρ)/(n − 3)], n is the number of observations, and ρ is the population lag one serial correlation. This distribution is derived from...
Calculation of amorphous silica solubilities at 25° to 300°C and apparent cation hydration numbers in aqueous salt solutions using the concept of effective density of water
Robert O. Fournier, Marshall L. Williams
1983, Geochimica et Cosmochimica Acta (47) 587-596
The solubility of amorphous silica in aqueous salt solutions at 25° to 300°C can be calculated using information on its solubility in pure water and a model in which the activity of water in the salt solution is defined to equal the effective density. pe, of “free” water in that solution....
Thermal decarboxylation of acetic acid: Implications for origin of natural gas
Y.K. Kharaka, W.W. Carothers, R.J. Rosenbauer
1983, Geochimica et Cosmochimica Acta (47) 397-402
Laboratory experiments on the thermal decarboxylation of solutions of acetic acid at 200°C and 300°C were carried out in hydrothermal equipment allowing for on-line sampling of both the gas and liquid phases for chemical and stable-carbon-isotope analyses. The solutions had ambient pH values between 2.5 and 7.1; pH values and...
Snow and ice in a changing hydrological world
M. F. Meier
1983, Hydrological Sciences Journal (28) 3-22
On the occasion of the 60th anniversary of the International Association of Hydrological Sciences, the 100th and 50th anniversaries of the First and Second International Polar Years, and the 25th anniversary of the International Geophysical Year, it seems appropriate to re-examine the world's water balance and the role of snow...
Characteristics of resuspended sediment from Georges Bank collected with a sediment trap
C.M. Parmenter, Michael H. Bothner, B. Butman
1983, Estuarine, Coastal and Shelf Science (17) 521-533
A sediment trap was deployed 3 m from the bottom at a water depth of 62 m on the southern flank of Georges Bank (41°02·2′N, 67°33·5′W) from 30 September 1978 to 10 March 1979 to qualitatively determine the size of sediments resuspended from the bottom by winter storms and to...
An interpretation of carbon and sulfur relationships in Black Sea sediments as indicators of environments of deposition
J.S. Leventhal
1983, Geochimica et Cosmochimica Acta (47) 133-137
Syngenetic iron sulfides in sediments are formed from dissolved sulfide resulting from sulfate reduction and catabolism of organic matter by anaerobic bacteria. It has been shown that in recent marine sediments deposited below oxygenated waters there is a constant relationship between reduced sulfur and organic carbon which is generally independent...
Isotopic and chemical composition of Parbati Valley geothermal discharges, north-west Himalaya, India
W.F. Giggenbach, R. Gonfiantini, B.L. Jangi, A.H. Truesdell
1983, Geothermics (12) 199-222
The isotopic compositions of the waters discharged from Parbati Valley geothermal areas indicate a higher altitude meteoric origin, with discharge temperatures reflecting variations in the depth of penetration of the waters to levels heated by the existence of a ‘normal’ geothermal gradient. On the basis of mixing models involving silica,...
On the reported optical activity of amino acids in the Murchison meteorite
J.L. Bada, J.R. Cronin, M.-S. Ho, K.A. Kvenvolden, J.G. Lawless, S.L. Miller, John Oro, S. Steinberg
1983, Nature (301) 494-496
In analyses of extracts from the Murchison meteorite (a carbonaceous chondrite), Engel and Nagy1 reported an excess of L-enantiomers for several protein amino acids but found that the non-protein amino acids were racemic. They suggested that the excess of L-isomers might have resulted from an asymmetric synthesis or decomposition. Their...
New evidence for the age of the Gubik Formation Alaskan North Slope
C.A. Repenning
1983, Quaternary Research (19) 356-372
At several Alaskan North Slope localities south of the shore of the Arctic Ocean the Gubik Formation, herein regarded as latest Pliocene and Pleistocene in age, contains a marine unit at its base. Near Ocean Point and near Teshekpuk Lake this basal unit, or the lowest exposed marine unit, of...
Requirements for modeling trace metal partitioning in oxidized estuarine sediments
Samuel N. Luoma, J.A. Davis
1983, Marine Chemistry (12) 159-181
The fate of particulate-bound metals is of particular importance in estuaries because major biological energy flows involve consumption of detrital particles. The biological impact of particulate-bound metals is strongly influenced by the partitioning of metals among sediment components at the oxidized sediment-water interface. Adequate methods for directly measuring this partitioning...
Nitrate concentrations under irrigated agriculture
A. Zaporozec
1983, Environmental Geology (5) 35-38
In recent years, considerable interest has been expressed in the nitrate content of water supplies. The most notable toxic effect of nitrate is infant methemoglobinemia. The risk of this disease increases significantly at nitrate-nitrogen levels exceeding 10 mg/l. For this reason, this concentration has been established as a limit for...
In situ capture gamma-ray analysis of coal in an oversize borehole
J.L. Mikesell, D.W. Dotson, F. E. Senftle, R.S. Zych, J. Koger, L. Goldman
1983, Nuclear Instruments and Methods In Physics Research (215) 561-566
In situ capture gamma-ray analysis in a coal seam using a high resolution gamma-ray spectrometer in a close-fitting borehole has been reported previously. In order to check the accuracy of the method under adverse conditions, similar measurements were made by means of a small-diameter sonde in an oversize borehole in...
Ground-water models for water resource planning
J.E. Moore
1983, GeoJournal (7) 453-458
In the past decade hydrogeologists have emphasized the development of computer-based mathematical models to aid in the understanding of flow, the transport of solutes, transport of heat, and deformation in the ground-water system. These models have been used to provide information and predictions for water managers. Too frequently, ground-water was...
