The distribution of nitrogen species and adsorption of ammonium in sediments from the tidal Potomac River and estuary
N.S. Simon, M.M. Kennedy
1987, Estuarine, Coastal and Shelf Science (25) 11-26
The distribution of dissolved ammonium, adsorbed ammonium and residual, organic and total nitrogen was measured in Potomac River tidal, transition zone and lower estuary sediments to a depth of 66 cm. For these sediments, exchangeable ammonium, and thereby adsorbed ammonium concentrations, were determined directly using an ammonia electrode in alkaline...
Kinetics and mechanisms of iron sulfide reductions in hydrogen and in carbon monoxide
T. Wiltowski, C.C. Hinckley, Gerard V. Smith, T. Nishizawa, Mykola Saporoschenko, R.H. Shiley, J.R. Webster
1987, Journal of Solid State Chemistry (71) 95-102
The reduction of iron sulfides by hydrogen and by carbon monoxide has been studied using plug flow and thermogravimetric methods. The reactions were studied in the 523–723°K temperature range and were found to be first-order processes. Plug flow studies were used to correlate reaction rates between pyrite and the gases...
Structural analysis of geochemical samples by solid-state nuclear magnetic resonance spectrometry. Role of paramagnetic material
A. M. Vassallo, M. A. Wilson, P. J. Collin, J. M. Oades, A. G. Waters, Ronald L. Malcolm
1987, Analytical Chemistry (59) 558-562
An examination of coals, coal tars, a fulvic acid, and soil fractions by solid-state 13C NMR spectrometry has demonstrated widely differing behavior regarding quantitative representation in the spectrum. Spin counting experiments on coal tars and the fulvic acid show that almost all the sample carbon is observed in both solution...
Valles Marineris, Mars: Wet debris flows and ground ice
Baerbel K. Lucchitta
1987, Icarus (72) 411-429
Detailed study of the Valles Marineris equatorial troughs suggests that the landslides in that area contained water and probably were gigantic wet debris flows: one landslide complex generated a channel that has several bends and extends for 250 km. Further support for water or ice in debris masses includes rounded...
Archean inheritance in zircon from late Paleozoic granites from the Avalon zone of southeastern New England: An African connection
R. E. Zartman, Hermes O. Don
1987, Earth and Planetary Science Letters (82) 305-315
In southeastern New England the Narragansett Pier Granite locally intrudes Carboniferous metasedimentary rocks of the Narragansett basin, and yields a monazite UPb Permian emplacement age of 273 ± 2Ma. Zircon from the Narragansett Pier Granite contains a...
Coastal lava flows from Mauna Loa and Hualalai volcanoes, Kona, Hawaii
James G. Moore, D. Clague
1987, Bulletin of Volcanology (49) 752-764
A major carbonate reef which drowned 13 ka is now submerged 150 m below sea level on the west coast of the island of Hawaii. A 25-km span of this reef was investigated using the submersible Makali'i. The reef occurs on the flanks of two active volcanoes, Mauna Loa and...
Analysis of the U.S. geological survey streamgaging network
A. G. Scott
1987, Water Science and Technology (19) 31-42
This paper summarizes the results from the first 3 years of a 5-year cost-effectiveness study of the U.S. Geological Survey streamgaging network. The objective of the study is to define and document the most cost-effective means of furnishing streamflow information. In the first step of this study, data uses were...
Estimating threshold values for the land disposal of organic solvent-contaminated wastes
William R. Roy, R. A. Griffin
1987, Journal of Hazardous Materials (15) 365-376
This paper describes conceptual and mathematical modeling approaches to evaluate environmentally suitable waste management practices that prevent ground water pollution from landfill disposal of solid wastes contaminated with organic solvents. Threshold values for disposal of solid wastes contaminated with acetone, nitrobenzene, chlorobenzene, and carbon tetrachloride were estimated using a disposal...
The crustal structure of the axis of the Great Valley, California, from seismic refraction measurements
W.S. Holbrook, Walter D. Mooney
1987, Tectonophysics (140) 49-63
In 1982 the U.S. Geological Survey collected six seismic refraction profiles in the Great Valley of California: three axial profiles with a maximum shot-to-receiver offset of 160 km, and three shorter profiles perpendicular to the valley axis. This paper presents the results of two-dimensional raytracing and synthetic seismogram modeling of...
Analysis of broadband seismograms from selected IASPEI events
G. L. Choy, E.R. Engdahl
1987, Physics of the Earth and Planetary Interiors (47) 80-92
Broadband seismograms of body waves that are flat to displacement and velocity in the frequency range from 0.01 to 5.0 Hz can now be routinely obtained for most earthquakes of magnitude greater than about 5.5. These records are obtained either directly or through multichannel deconvolution of waveforms from digitally recording...
Role of pressure in smectite dehydration: Effects on geopressure and smectite-to-illite transformation
Virginia Colten-Bradley
1987, American Association of Petroleum Geologists Bulletin (71) 1414-1427
Evaluation of the effect of pressure on the temperature of interlayer water loss (dehydration) by smectites under diagenetic conditions indicates that smectites are stable as hydrated phases in the deep subsurface. Hydraulic and differential pressure conditions affect dehydration differently. Smectites under hydraulic pressure conditions, such as in the pores of...
Evaluating evaporation from field crops using airborne radiometry and ground-based meteorological data
R. D. Jackson, M. S. Moran, L. W. Gay, L.H. Raymond
1987, Irrigation Science (8) 81-90
Airborne measurements of reflected solar and emitted thermal radiation were combined with ground-based measurements of incoming solar radiation, air temperature, windspeed, and vapor pressure to calculate instantaneous evaporation (LE) rates using a form of the Penman equation. Estimates of evaporation over cotton, wheat, and alfalfa fields were obtained on 5...
The solubilities of some major and minor element minerals in ground waters associated with a sandstone-hosted uranium deposit
Richard B. Wanty, J. R. Chatcham, D. Langmuir
1987, Bulletin de Mineralogie (110) 209-226
Ground-water samples from 41 wells penetrating basal Oakville sandstone (Miocene) in S Texas were chemically analysed to identify chemical changes related to nearby U orebodies. The coverage included a 240 km2 area which contains several fault-related U deposits. Factors affecting the hydrochemistry include: 1) relatively high permeabilities of buried fluvial-channel...
Sources and flux of natural gases from Mono Lake, California
Ronald S. Oremland, L.G. Miller, Michael J. Whiticar
1987, Geochimica et Cosmochimica Acta (51) 2915-2929
The ability to identify a formation mechanism for natural gas in a particular environment requires consideration of several geochemical factors when there are multiple sources present. Four primary sources of methane have been identified in Mono Lake. Two of these sources were associated with numerous natural gas seeps which...
Modes of development of slope canyons and their relation to channel and levee features on the Ebro sediment apron, off-shore northeastern Spain
S. O'Connell, William B. F. Ryan, W. R. Normark
1987, Marine and Petroleum Geology (4)
Six submarine slope canyons in an area of the northwestern Mediterranean, offshore from the Ebro River and Delta, were surveyed with bathymetric swathmapping (SeaBeam) and mid-range side-looking sonar (SeaMARC I). All of the canyons have slightly winding paths with concave-upwards gradients that are relatively steep shallower than 1,200 m. Two...
An automated technique for flow measurements from mariotte reservoirs
Jim Constantz, Fred Murphy
1987, Soil Science Society of America Journal (51) 252-254
The mariotte reservoir supplies water at a constant hydraulic pressure by self-regulation of its internal gas pressure. Automated outflow measurements from mariotte reservoirs are generally difficult because of the reservoir's self-regulation mechanism. This paper describes an automated flow meter specifically designed for use with mariotte reservoirs. The flow meter monitors...
Molecular orbital (SCF-Xα-SW) theory of metal-metal charge transfer processes in minerals - II. Application to Fe2+ --> Ti4+ charge transfer transitions in oxides and silicates
David M. Sherman
1987, Physics and Chemistry of Minerals (14) 364-367
A molecular orbital description, based on Xα-Scattered wave calculations on a (FeTiO10)14− cluster, is given for Fe2+ → Ti4+ charge transfer transitions in minerals. The calculated energy for the lowest Fe2+ → Ti4+ metal-metal charge transfer transition is 18040 cm−1 in reasonable agreement with energies observed in the optical spectra of Fe-Ti oxides and silicates. As...
Crustal and upper mantle structure of stable continental regions in North America and northern Europe
R.P. Masse
1987, Pure and Applied Geophysics PAGEOPH (125) 205-239
From an analysis of many seismic profiles across the stable continental regions of North America and northern Europe, the crustal and upper mantle velocity structure is determined. Analysis procedures include ray theory calculations and synthetic seismograms computed using reflectivity techniques. The P wave velocity structure beneath the Canadian Shield is...
Dynamics of Mojave Desert shrub assemblages in the Panamint Mountains, California.
Robert Webb, John W. Steiger, Raymond M. Turner
1987, Ecology (68) 478-490
We studied shrub communities in the Panamint Mountains of the Mojave Desert to determine whether vegetational changes after disturbance can be characterized as succession according to modern successional theory. We found, on a variety of disturbed and undisturbed sites, that the rate of change was a function of the type...
PHYSICAL MODELING OF CONTRACTED FLOW.
Jonathan K. Lee
1987, Conference Paper
Experiments on steady flow over uniform grass roughness through centered single-opening contractions were conducted in the Flood Plain Simulation Facility at the U. S. Geological Survey's Gulf Coast Hydroscience Center near Bay St. Louis, Miss. The experimental series was designed to provide data for calibrating and verifying two-dimensional, vertically averaged...
Critical behavior of dilute NaCl in H2O
Kenneth S. Pitzer, James L. Bischoff, Robert J. Rosenbauer
1987, Chemical Physics Letters (134) 60-63
The compositions of the saturated vapor and liquid phases are measured for the system NaCl-H2O at 380°C, which is close to the critical point of pure water. The shape of the phase equilibrium curve is classical, which confirms a conclusion reached earlier on the basis of less accurate data. This...
Radiocarbon and cation-radio ages for rock varnish on Tioga and Tahoe marainal boulders of Pine Creek, eastern Sierra Nevada, California, and their paleoclimatic implications
R.I. Dorn, B. D. Turrin, A.J.T. Jull, T.W. Linick, D.J. Donahue
1987, Quaternary Research (28) 36-49
Accelerator mass spectrometry 14C analyses of organic matter extracted from rock varnishes on morainal boulders yield limiting minimum ages for three crests of the Tioga glaciation. At Pine Creek in the eastern Sierra Nevada, varnish started to form on boulders of the outermost Tioga moraine before 19,000 yr B.P., and...
The vertical attenuation of light in Charlotte Harbor, a shallow, subtropical estuary, south-western Florida
B. F. McPherson, R. L. Miller
1987, Estuarine, Coastal and Shelf Science (25) 721-737
The relative contribution of different components to the attenuation of photosynthetically active radiation was determined in the Charlotte Harbor estuarine system based on laboratory and in situ measurements. Agreement between laboratory and in situ measurements of the attenuation coefficient (kt) was good (r2 = 0·92). For all in situ measurements (n = 100), suspended, non-chlorophyll matter accounted...
Source of lead and mineralizing brines for rossie-type Pb-Zn veins in the Frontenac axis area, New York ( USA).
Robert Ayuso, Nora K. Foley, C. Erwin Brown
1987, Economic Geology (82) 489-491
Veins composed mainly of calcite and some galena, sphalerite, fluorite, and other minerals are widespread in the Frontenac axis area of New York and Ontario. In New York, the veins (Fig. 1) occur mainly west and northwest of Gouverneur (Brown, 1983). The veins, mined in the 1800s for lead,...
Mineralogical basis for the interpretation of multi-element (ICP-AES), oxalic acid, and aqua regia partial digestions of stream sediments for reconnaissance exploration geochemistry
S. E. Church, E. L. Mosier, J. M. Motooka
1987, Journal of Geochemical Exploration (29) 207-233
We have applied partial digestion procedures, primarily oxalic acid and aqua regia leaches, to several regional geochemical reconnaissance studies carried out using Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) analytical methods. We have chosen to use these two acids because the oxalic...